Stereochemical analysis of molecular transition metal "hetero-layered sandwich" complex, [Fe(CO)3(CH3C2CH3)2]Ni[C4(CH3)4], containing a nickel-iron bond: steric equivalence of the Ni(cyclobutadiene) fragment with iron tricarbonyl and Fe(CO)(cyclobutadiene) fragments

1970 ◽  
Vol 92 (3) ◽  
pp. 502-507 ◽  
Author(s):  
Earl F. Epstein ◽  
Lawrence F. Dahl
Keyword(s):  
Transition Metal ◽  
Sandwich Complex ◽  
Nickel Iron ◽  
Stereochemical Analysis ◽  
Molecular Transition ◽  
Iron Tricarbonyl

Molecular transition-metal phosphonates

2011 ◽  
Vol 40 (20) ◽  
pp. 5394 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Tapas Senapati ◽  
Atanu Dey ◽  
Sakiat Hossain
Keyword(s):  
Transition Metal ◽  
Metal Phosphonates ◽  
Molecular Transition

scholarly journals Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes

2020 ◽  
Vol 11 (36) ◽  
pp. 9836-9851
Author(s):  
Katherine J. Lee ◽  
Kunal M. Lodaya ◽  
Cole T. Gruninger ◽  
Eric S. Rountree ◽  
Jillian L. Dempsey
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Transition Metal Complex ◽  
Redox Mediators ◽  
Insoluble Material ◽  
Molecular Transition ◽  
Novel Strategy

We present an example of electrochemically-driven solubility cycling of a molecular transition metal complex and report a novel strategy for catalytically enhancing the oxidation of an insoluble material using homogeneous redox mediators.

NOVEL MANY-BODY EFFECTS IN PHOTOEMISSION AND INVERSE PHOTOEMISSION SPECTRA OF ULTRATHIN TRANSITION-METAL FILMS

1991 ◽  
Vol 05 (08) ◽  
pp. 1147-1178 ◽  
Author(s):  
CHANGFENG CHEN
Keyword(s):  
Transition Metal ◽  
Local Density ◽  
Many Body ◽  
Strongly Correlated Electron ◽  
Correlated Electron Systems ◽  
Nickel Iron ◽  
Correlated Electron ◽  
Inverse Photoemission ◽  
Recent Developments ◽  
Many Body Effects

We present an overview of some recent developments in the theoretical modeling of transition-metal systems, particularly the ultrathin-film structures, focusing on the effects of electron-electron interactions. We describe the progress in the understanding of how to model realistic strongly correlated electron systems using and going beyond the local-density-approximation single-particle electronic structures. Results of exact many-body calculations of photoemission and inverse photoemission spectra of ultrathin nickel, iron and cobalt films are shown to illustrate the application of our approach. Interesting new features induced by many-body effects are found and discussed. Comparison with available experimental results is presented and further work, both experimental and theoretical, is suggested.

Thiepine-iron tricarbonyl: stabilization of thermally labile parent thiepine by transition metal complexation

1991 ◽  
Vol 113 (13) ◽  
pp. 5059-5060 ◽  
Author(s):  
Keitaro Nishino ◽  
Masanobu Takagi ◽  
Teruhisa Kawata ◽  
Ichiro Murata ◽  
Junji Inanaga ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexation ◽  
Iron Tricarbonyl
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