Molecular transition-metal phosphonates

2011 ◽  
Vol 40 (20) ◽  
pp. 5394 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Tapas Senapati ◽  
Atanu Dey ◽  
Sakiat Hossain
Keyword(s):  
Transition Metal ◽  
Metal Phosphonates ◽  
Molecular Transition

ChemInform Abstract: Molecular Transition-Metal Phosphonates

ChemInform ◽  
2011 ◽  
Vol 42 (43) ◽  
pp. no-no
Author(s):  
Vadapalli Chandrasekhar ◽  
Tapas Senapati ◽  
Atanu Dey ◽  
Sakiat Hossain
Keyword(s):  
Transition Metal ◽  
Metal Phosphonates ◽  
Molecular Transition

Introduction of Organic Moieties into Transition-Metal Oxide Matrices via Phosphonate Groups

1998 ◽  
Vol 519 ◽  
Author(s):  
P.H. Mutin ◽  
C. Delenne ◽  
D. Medoukali ◽  
R. Corriu ◽  
A. Vioux
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Phosphonic Acid ◽  
Sol Gel ◽  
Transition Metal Oxide ◽  
Metal Alkoxide ◽  
Hydrolytic Condensation ◽  
Metal Phosphonates ◽  
Or Groups ◽  
Sol Gel Process

AbstractTransition metal oxide / phenylphosphonate hybrids with M/P ratios ranging from 1 to 5, (M= Ti, Zr) and metal phosphonates (M/P = 0.5) have been prepared by a sol-gel process involving in a first step the non-hydrolytic condensation between metal alkoxide and phosphonic acid leading to M-O-P bonds, followed by the hydrolysis-condensation of the remaining M-OR groups. The composition, texture and structure of the materials were investigated using EDX, TGA, XRD, IR and 31P NMR.

scholarly journals Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes

2020 ◽  
Vol 11 (36) ◽  
pp. 9836-9851
Author(s):  
Katherine J. Lee ◽  
Kunal M. Lodaya ◽  
Cole T. Gruninger ◽  
Eric S. Rountree ◽  
Jillian L. Dempsey
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Transition Metal Complex ◽  
Redox Mediators ◽  
Insoluble Material ◽  
Molecular Transition ◽  
Novel Strategy

We present an example of electrochemically-driven solubility cycling of a molecular transition metal complex and report a novel strategy for catalytically enhancing the oxidation of an insoluble material using homogeneous redox mediators.

Hybrid Organic-Inorganic Transition-Metal Phosphonates as Precursors for Water Oxidation Electrocatalysts

2017 ◽  
Vol 27 (40) ◽  
pp. 1703158 ◽  
Author(s):  
Rui Zhang ◽  
Patrícia A. Russo ◽  
Ana G. Buzanich ◽  
Taeyeol Jeon ◽  
Nicola Pinna
Keyword(s):  
Transition Metal ◽  
Water Oxidation ◽  
Metal Phosphonates
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