The Solubility of Lead Chloride in Sodium Chloride, Perchloric Acid and Hydrochloric Acid Solutions1

1953 ◽  
Vol 75 (11) ◽  
pp. 2768-2768 ◽  
Author(s):  
S. Z. Lewin ◽  
John E. Vance ◽  
Lawrence B. Nelson
1960 ◽  
Vol 38 (9) ◽  
pp. 1488-1494 ◽  
Author(s):  
E. J. Bounsall ◽  
W. A. E. McBryde

An analytical method is described for the determination of microgram amounts of silver in galena ores, based on the "reversion" of silver dithizonate. Silver is separated from relatively large amounts of lead by extraction as dithizonate into chloroform from an aqueous 1:99 nitric acid solution. Separation from mercury, which is also extracted under these conditions and would, if present, interfere in the analysis, is achieved by reverting the dithizonate solution with a 5% aqueous sodium chloride solution which is also 0.015 molar in hydrochloric acid. Following dilution of this aqueous solution and adjustment of pH, silver is again extracted into chloroform as the dithizonate, and determined absorptiometrically. Analyses of a number of galena ore samples showed a precision of within 3% for a silver content ranging from 0.03 to 0.4%.Some other methods for isolating silver from these samples, which were tried but found unsatisfactory, are discussed.


2017 ◽  
Vol 52 (16) ◽  
pp. 2611-2621 ◽  
Author(s):  
Zdeněk Palatý ◽  
Helena Bendová

2020 ◽  
Vol 1001 ◽  
pp. 139-144
Author(s):  
Ying Li ◽  
Ben Tao Li ◽  
Guang Yu Sun ◽  
Hui Huang ◽  
Chen Gong ◽  
...  

The influence of different acidic medium, including hydrochloric acid, nitric acid and perchloric acid on the absorbance of sodium by flame atomic absorption spectrometry was studied. The results showed that the effects of acidic medium and water on the determination of sodium were as follows: hydrochloric acid > perchloric acid > nitric acid > water. Acid effect changed with the increase of acid concentration, however, the absorbance value of sodium element decreased when the concentration of acid was higher than 1%~2%. This effect was more obvious for high content of sodium. The detection limits, repeatability and recovery of the samples under the three acidic medium were compared. The optimum acid conditions were determined and the sensitivity of the method was improved.


2010 ◽  
Vol 61 (9) ◽  
pp. 783-789 ◽  
Author(s):  
G. S Peng ◽  
K. H. Chen ◽  
H. C. Fang ◽  
H. Chao ◽  
S. Y. Chen

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