ChemInform Abstract: QUANTITATIVE DETERMINATION OF CYANOACETIC ACID IN THE PRESENCE OF MALONIC ACID, HYDROCHLORIC ACID AND SODIUM CHLORIDE

1977 ◽  
Vol 8 (2) ◽  
pp. no-no
Author(s):  
R. PIEKOS ◽  
K. OSMIALOWSKI ◽  
K. KOBYLCZYK ◽  
J. GRZYBOWSKI
Keyword(s):  
Sodium Chloride ◽  
Hydrochloric Acid ◽  
Quantitative Determination ◽  
Malonic Acid ◽  
Cyanoacetic Acid

DETERMINATION OF TRACE AMOUNTS OF SILVER IN GALENA ORES

1960 ◽  
Vol 38 (9) ◽  
pp. 1488-1494 ◽  
Author(s):  
E. J. Bounsall ◽  
W. A. E. McBryde
Keyword(s):  
Aqueous Solution ◽  
Nitric Acid ◽  
Sodium Chloride ◽  
Hydrochloric Acid ◽  
Chloride Solution ◽  
Sodium Chloride Solution ◽  
Silver Content ◽  
Aqueous Sodium Chloride Solution ◽  
Aqueous Sodium

An analytical method is described for the determination of microgram amounts of silver in galena ores, based on the "reversion" of silver dithizonate. Silver is separated from relatively large amounts of lead by extraction as dithizonate into chloroform from an aqueous 1:99 nitric acid solution. Separation from mercury, which is also extracted under these conditions and would, if present, interfere in the analysis, is achieved by reverting the dithizonate solution with a 5% aqueous sodium chloride solution which is also 0.015 molar in hydrochloric acid. Following dilution of this aqueous solution and adjustment of pH, silver is again extracted into chloroform as the dithizonate, and determined absorptiometrically. Analyses of a number of galena ore samples showed a precision of within 3% for a silver content ranging from 0.03 to 0.4%.Some other methods for isolating silver from these samples, which were tried but found unsatisfactory, are discussed.

THE DETERMINATION OF ZIRCONIUM WITH BENZOYLPHENYLHYDROXYLAMINE

1960 ◽  
Vol 38 (12) ◽  
pp. 2488-2492 ◽  
Author(s):  
D. E. Ryan
Keyword(s):  
Hydrochloric Acid ◽  
Quantitative Determination ◽  
Sulphuric Acid ◽  
Rare Earths ◽  
Acid Solutions ◽  
Constant Composition ◽  
Hydrochloric Acid Solutions

Zirconium is completely precipitated by benzoylphenylhydroxylamine from 0.5 N acid solutions. The complex formed in sulphuric acid solutions has a constant composition, Zr(C13H10O2N)4, and is used for the direct weighing of zirconium; the factor is 0.0970. The product precipitated from hydrochloric acid solutions must be ignited to the oxide. The reaction is sensitive, 1 p.p.m. of zirconium being detectable, and quantitative determination of 0.2 mg is possible. Thorium and the rare earths do not interfere.

scholarly journals The Oxidative Derivatization Method For The Spectrofluorimetric Determination Of Periciazine In Pharmaceutical Preparations

2020 ◽  
Vol 15 (1) ◽  
pp. 21-26
Author(s):  
M.Ye. Blazheyevskiy ◽  
Yu.V. Scrypynets ◽  
A.V. Yegorova ◽  
V.P. Antonovich
Keyword(s):  
Hydrochloric Acid ◽  
Acid Solution ◽  
Quantitative Determination ◽  
Pharmaceutical Preparations ◽  
Oral Solution ◽  
Calibration Plot ◽  
Highly Sensitive ◽  
Spectrofluorimetric Determination ◽  
Derivatizing Agent

The oxidative derivatization method for the indirect spectrofluorimetric determination of Periciazine has been presented. Potassium hydrogenperoxymonosulfate (Oxone ®) is proposed as a derivatizing agent for Periciazine, yielding the strongly fluorescent Periciazine sulfoxide. A highly sensitive, simple and rapid method for determination of the Periciazine by fluorescence of its oxidation product with Oxone ® solution in 0.02 M hydrochloric acid solution (λex = 364 nm; λem = 444 nm) has been developed. The calibration plot is linear in concentration range of 0.05 – 4.00 µg mL -1 . LOQ (10S) is 0.05 µg mL -1 . The possibility of quantitative determination of Periciazine in pharmaceutical preparations (Neuleptil ®, 10 mg capsules and Neuleptil ®, a 30 mL 4 % oral (solution) drops) has been shown RSD < 2.2 % (δ < RSD).

scholarly journals The Chemistry of Dicarboxylic Acids. I. A New Method for Quantitative Determination of Malonic Acid.

1958 ◽  
Vol 12 ◽  
pp. 1437-1443 ◽  
Author(s):  
Aage Jart ◽  
P. Sørensen ◽  
Einar Stenhagen ◽  
K. Hartiala ◽  
S. Veige ◽  
...  
Keyword(s):  
Quantitative Determination ◽  
Malonic Acid ◽  
Dicarboxylic Acids ◽  
New Method

scholarly journals Development of methods for standardization of the active substance, namely the model mixture based on decamethoxine and thiotriazoline

2021 ◽  
Vol 23 (5) ◽  
pp. 703-707
Author(s):  
L. I. Kucherenko ◽  
O. O. Chonka ◽  
O. O. Portna
Keyword(s):  
Hydrochloric Acid ◽  
Polyvinyl Alcohol ◽  
Quantitative Determination ◽  
Active Substance ◽  
Model Mixture ◽  
State Enterprise ◽  
Chemical Reagents ◽  
The Creation ◽  
Active Substances

Today, the important problem is the creation of new decamethoxine and thiotriazoline based drugs for the treatment of stomatitis. The aim of the work is to develop a method for quantitative determination of decamethoxine and thiotriazoline in the model mixture (1:25) by spectrophotometry. Materials and methods. Series 6 model mixtures were made at the ratio of decamethoxine and thiotriazoline 1:25. We used certified substances: thiotriazoline series GTT 3460911 (manufacturer: State Enterprise Chemical Reagents Plant, Kharkiv), decamethoxine series № 010915 (manufacturer: LLC “PHARMCHIM”). Optizen POP spectrophotometer, polyvinyl alcohol, hydrochloric acid, and eosin were used. Results. A method for quantitative determination of decamethoxine and thiotriazoline in MS was developed. It was established that the content of active substances in MS is thiotriazoline from 0.5021 to 0.5096, decamethoxine from 0.0207 to 0.0211. Conclusions. A method for quantitative determination of decamethoxine and thiotriazoline in MS has been developed. The method of quantitative determination of decamethoxine and thiotriazoline in MS is reproducible.

THE APPLICATION OF 8-HYDROXYQUINOLINE TO THE ANALYSIS OF ALUMINIUM ALLOYS: DETERMINATION OF MAGNESIUM IN THE PRESENCE OF MANGANESE AND NICKEL

1945 ◽  
Vol 23b (5) ◽  
pp. 183-193
Author(s):  
Paul E. Gagnon ◽  
Henri Shehyn
Keyword(s):  
Sodium Chloride ◽  
Hydrochloric Acid ◽  
Aluminium Alloys ◽  
Accurate Method ◽  
Salting Out ◽  
Co Precipitation ◽  
Short Method

The application of the precipitation of magnesium with oxine in tartro–sodic medium to the analysis of aluminium alloys has been studied from the standpoint of possible interference from other constituents of the alloys and especially manganese and nickel. In the presence of manganese in amounts not exceeding 8.0 mgm. per 100 ml. of solution, magnesium can be successfully determined provided sodium chloride is not present. With amounts of sodium chloride exceeding 6 gm. and manganese over 6 mgm. per 100 ml. of solution, a salting-out of manganese oxinate definitely takes place which leads to high results for magnesium. This interference can be eliminated by preventing the formation of appreciable amounts of sodium chloride by evaporating off hydrochloric acid before adjusting the pH for the precipitation of magnesium oxinate. Nickel in amounts exceeding 2.5 mgm. per 100 ml. of solution interferes by co-precipitation of nickel oxinate, which is adsorbed on the magnesium oxinate and finally leads to high values for magnesium. For this reason, nickel must be removed by means of an ammonium sulphide separation for which a short method is described. With these modifications the precipitation of magnesium with oxine in tartro–sodic medium provides a rapid and accurate method of determining this element in aluminium alloys.

scholarly journals A METHOD FOR THE QUANTITATIVE DETERMINATION OF FECAL BACTERIA

1911 ◽  
Vol 14 (4) ◽  
pp. 433-444 ◽  
Author(s):  
H. A. Mattill ◽  
P. B. Hawk
Keyword(s):  
Hydrochloric Acid ◽  
Quantitative Determination ◽  
Bacterial Suspension ◽  
Average Amount ◽  
Daily Amount ◽  
True Value ◽  
Ether Extraction ◽  
Fresh Feces ◽  
Average Daily Amount

From results of which the foregoing data form a part, it appears that the amount of bacterial nitrogen in the feces is a valuable index to intestinal conditions, and the method herein described is a simple and satisfactory one for making this determination. It involves three serial centrifugalizations of a two gram sample of the fresh feces brought into suspension in 0.2 per cent. hydrochloric acid. The bacterial suspension finally obtained is concentrated and extracted by alcohol, and nitrogen is determined in the precipitated material. The complete data on a given stool can be obtained in about five days, and one operator can take care of three or four stools in duplicate in one day. On an absolutely uniform diet of simple and easily digested food during a period of three to four weeks, the average amount of bacterial nitrogen in two subjects was found to be 53.9 per cent. of the total fecal nitrogen, and this percentage, though higher than that obtained by workers heretofore, is probably more nearly a true value for bacterial nitrogen, because no ether extraction was employed. The average daily amount of dry bacteria, calculated on the basis of the nitrogen values, is 8.27 grams.

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