Noncovalent Interactions under Extreme Conditions: High-Pressure and Low-Temperature Diffraction Studies of the Isostructural Metal−Organic Networks (4-Chloropyridinium)2[CoX4] (X = Cl, Br)

2008 ◽  
Vol 130 (28) ◽  
pp. 9058-9071 ◽  
Author(s):  
Guillermo Mínguez Espallargas ◽  
Lee Brammer ◽  
David R. Allan ◽  
Colin R. Pulham ◽  
Neil Robertson ◽  
...  
2005 ◽  
Vol 5 (3) ◽  
pp. 1055-1071 ◽  
Author(s):  
Iain D. H. Oswald ◽  
David R. Allan ◽  
Graeme M. Day ◽  
W. D. Samuel Motherwell ◽  
Simon Parsons

1999 ◽  
Vol 38 (7) ◽  
pp. 1411-1415 ◽  
Author(s):  
Hartmut Yersin ◽  
Dietrich Trümbach ◽  
Harald Wiedenhofer

2020 ◽  
Author(s):  
Pia Vervoorts ◽  
Stefan Burger ◽  
Karina Hemmer ◽  
Gregor Kieslich

The zeolitic imidazolate frameworks ZIF-8 and ZIF-67 harbour a series of fascinating stimuli responsive properties. Looking at their responsitivity to hydrostatic pressure as stimulus, open questions exist regarding the isotropic compression with non-penetrating pressure transmitting media. By applying a state-of-the-art high-pressure powder X-ray diffraction setup, we revisit the high-pressure behaviour of ZIF-8 and ZIF-67 up to <i>p</i> = 0.4 GPa in small pressure increments. We observe a drastic, reversible change of high-pressure powder X-ray diffraction data at <i>p</i> = 0.3 GPa, discovering large volume structural flexibility in ZIF-8 and ZIF-67. Our results imply a shallow underlying energy landscape in ZIF-8 and ZIF-67, an observation that might point at rich polymorphism of ZIF-8 and ZIF-67, similar to ZIF-4(Zn).<br>


2020 ◽  
Author(s):  
Pia Vervoorts ◽  
Stefan Burger ◽  
Karina Hemmer ◽  
Gregor Kieslich

The zeolitic imidazolate frameworks ZIF-8 and ZIF-67 harbour a series of fascinating stimuli responsive properties. Looking at their responsitivity to hydrostatic pressure as stimulus, open questions exist regarding the isotropic compression with non-penetrating pressure transmitting media. By applying a state-of-the-art high-pressure powder X-ray diffraction setup, we revisit the high-pressure behaviour of ZIF-8 and ZIF-67 up to <i>p</i> = 0.4 GPa in small pressure increments. We observe a drastic, reversible change of high-pressure powder X-ray diffraction data at <i>p</i> = 0.3 GPa, discovering large volume structural flexibility in ZIF-8 and ZIF-67. Our results imply a shallow underlying energy landscape in ZIF-8 and ZIF-67, an observation that might point at rich polymorphism of ZIF-8 and ZIF-67, similar to ZIF-4(Zn).<br>


2021 ◽  
pp. 160309
Author(s):  
M. Osorio-García ◽  
K. Suárez-Alcántara ◽  
Y. Todaka ◽  
A. Tejeda-Ochoa ◽  
M. Herrera Ramírez ◽  
...  

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