scholarly journals Time-Resolved Detection of Surface Oxide Formation at Individual Gold Nanoparticles: Role in Electrocatalysis and New Approach for Sizing by Electrochemical Impacts

2016 ◽  
Vol 138 (39) ◽  
pp. 12755-12758 ◽  
Author(s):  
Cameron L. Bentley ◽  
Minkyung Kang ◽  
Patrick R. Unwin
Keyword(s):  
Gold Nanoparticles ◽  
Surface Oxide ◽  
Oxide Formation ◽  
Time Resolved ◽  
New Approach ◽  
Surface Oxide Formation

Direct observation of surface oxide formation and reduction on platinum clusters by time-resolved X-ray absorption spectroscopy

1995 ◽  
Vol 384 (1-2) ◽  
pp. 99-103 ◽  
Author(s):  
P.G. Allen ◽  
S.D. Conradson ◽  
M.S. Wilson ◽  
S. Gottesfeld ◽  
I.D. Raistrick ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Direct Observation ◽  
Surface Oxide ◽  
Oxide Formation ◽  
Time Resolved ◽  
X Ray ◽  
Platinum Clusters ◽  
Surface Oxide Formation ◽  
X Ray Absorption

scholarly journals How the anisotropy of surface oxide formation influences the transient activity of a surface reaction

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
P. Winkler ◽  
J. Zeininger ◽  
Y. Suchorski ◽  
M. Stöger-Pollach ◽  
P. Zeller ◽  
...  
Keyword(s):  
Hydrogen Oxidation ◽  
Surface Oxidation ◽  
Surface Reactivity ◽  
Surface Oxide ◽  
Surface Structures ◽  
Oxide Formation ◽  
Reaction Fronts ◽  
Transient Activity ◽  
Surface Oxide Formation ◽  
Stepped Surface

AbstractScanning photoelectron microscopy (SPEM) and photoemission electron microscopy (PEEM) allow local surface analysis and visualising ongoing reactions on a µm-scale. These two spatio-temporal imaging methods are applied to polycrystalline Rh, representing a library of well-defined high-Miller-index surface structures. The combination of these techniques enables revealing the anisotropy of surface oxidation, as well as its effect on catalytic hydrogen oxidation. In the present work we observe, using locally-resolved SPEM, structure-sensitive surface oxide formation, which is summarised in an oxidation map and quantitatively explained by the novel step density (SDP) and step edge (SEP) parameters. In situ PEEM imaging of ongoing H2 oxidation allows a direct comparison of the local reactivity of metallic and oxidised Rh surfaces for the very same different stepped surface structures, demonstrating the effect of Rh surface oxides. Employing the velocity of propagating reaction fronts as indicator of surface reactivity, we observe a high transient activity of Rh surface oxide in H2 oxidation. The corresponding velocity map reveals the structure-dependence of such activity, representing a direct imaging of a structure-activity relation for plenty of well-defined surface structures within one sample.

Control of surface oxide formation in plasma-enhanced quasiatomic layer etching of tantalum nitride

2020 ◽  
Vol 38 (2) ◽  
pp. 022609 ◽  
Author(s):  
Nathan Marchack ◽  
Jon-l Innocent-Dolor ◽  
Marinus Hopstaken ◽  
Sebastian Engelmann
Keyword(s):  
Surface Oxide ◽  
Tantalum Nitride ◽  
Oxide Formation ◽  
Surface Oxide Formation

In SituInfrared Study of Surface Oxide Formation on Gas-Evaporated Si Microcrystals

1993 ◽  
Vol 32 (Part 1, No. 11A) ◽  
pp. 4870-4877 ◽  
Author(s):  
Shinji Hayashi ◽  
Satoshi Kawata ◽  
Han Min Kim ◽  
Keiichi Yamamoto
Keyword(s):  
Surface Oxide ◽  
Oxide Formation ◽  
Surface Oxide Formation

Surface oxide formation on IN625 and plasma sprayed NiCrAlY after high density and low density supercritical water testing

2012 ◽  
Vol 65 (8) ◽  
pp. 768-777 ◽  
Author(s):  
A. Selvig ◽  
X. Huang ◽  
D. J. Kim ◽  
D. Guzonas
Keyword(s):  
Supercritical Water ◽  
High Density ◽  
Surface Oxide ◽  
Low Density ◽  
Oxide Formation ◽  
Water Testing ◽  
Surface Oxide Formation ◽  
Plasma Sprayed

scholarly journals Quantitative surface structure determination using in situ high-energy SXRD: Surface oxide formation on Pd(100) during catalytic CO oxidation

2014 ◽  
Vol 630 ◽  
pp. 229-235 ◽  
Author(s):  
Mikhail Shipilin ◽  
Uta Hejral ◽  
Edvin Lundgren ◽  
Lindsay R. Merte ◽  
Chu Zhang ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Surface Structure ◽  
Structure Determination ◽  
High Energy ◽  
Surface Oxide ◽  
Oxide Formation ◽  
Catalytic Co Oxidation ◽  
Surface Oxide Formation

The influence of test frequency on fatigue crack growth in air, and crack surface oxide formation

1982 ◽  
Vol 16 (7) ◽  
pp. 795-798 ◽  
Author(s):  
A. Bignonnet ◽  
R. Namdar-Irani ◽  
M. Truchon
Keyword(s):  
Fatigue Crack ◽  
Fatigue Crack Growth ◽  
Crack Growth ◽  
Crack Surface ◽  
Surface Oxide ◽  
Test Frequency ◽  
Oxide Formation ◽  
Surface Oxide Formation
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