scholarly journals Site-Selective Cross-Coupling of Remote Chlorides Enabled by Electrostatically Directed Palladium Catalysis

2018 ◽  
Vol 140 (42) ◽  
pp. 13570-13574 ◽  
Author(s):  
William A. Golding ◽  
Robert Pearce-Higgins ◽  
Robert J. Phipps
Keyword(s):  
Palladium Catalysis ◽  
Cross Coupling ◽  
Site Selective

The Merger of CF3SO2Na and Palladium Catalysis to Enable Decarboxylative Cross-Coupling for the Synthesis of Aromatic Ketones under Room Temperature

2021 ◽  
Author(s):  
Pan Xie ◽  
Cheng Xue ◽  
Cancan Wang ◽  
Dongdong Du ◽  
Sanshan Shi
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Palladium Catalysis ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Aromatic Ketones ◽  
Aryl Ketones ◽  
Oxocarboxylic Acids

A CF3SO2Na/Pd(OAc)2 co-catalyzed strategy is developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of α-oxocarboxylic acids and aryl boronic acids. This process was perfomed under air at room temperature,...

Recent Advances in C–Br Bond Formation

Synlett ◽  
2021 ◽  
Author(s):  
Ying-Yeung Yeung ◽  
Jonathan Wong
Keyword(s):  
Organic Synthesis ◽  
Aromatic Compounds ◽  
Bond Formation ◽  
Cross Coupling ◽  
Catalytic Site ◽  
Atom Transfer ◽  
Bond Forming ◽  
Recent Advances ◽  
Catalytic Asymmetric ◽  
Site Selective

AbstractOrganobromine compounds are extremely useful in organic synthesis. In this perspective, a focused discussion on some recent advancements in C–Br bond-forming reactions is presented.1 Introduction2 Selected Recent Advances2.1 Catalytic Asymmetric Bromopolycyclization of Olefinic Substrates2.2 Catalytic Asymmetric Intermolecular Bromination2.3 Some New Catalysts and Reagents for Bromination2.4 Catalytic Site-Selective Bromination of Aromatic Compounds2.5 sp3 C–H Bromination via Atom Transfer/Cross-Coupling3 Outlook

Site-Selective Aerobic C–H Monoacylation of Carbazoles Using Palladium Catalysis

2020 ◽  
Author(s):  
Subhadip Maiti ◽  
Tirtha Mandal ◽  
Barada Prasanna Dash ◽  
Jyotirmayee Dash
Keyword(s):  
Palladium Catalysis ◽  
Site Selective

scholarly journals Synthesis of Functionalized p-Terphenyls Based on Site-Selective Suzuki Cross-Coupling Reactions of Bis(triflates) of 2,5-Dihydroxybenzoate

Synlett ◽  
2009 ◽  
Vol 2010 (01) ◽  
pp. e1-e1
Author(s):  
Peter Langer ◽  
Muhammad Nawaz ◽  
Muhammad Ibad ◽  
Obaid-Ur-Rahman Abid ◽  
Rasheed Khera ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Site Selective

Direct Site-Selective Arylation of Enamides via a Decarboxylative Cross-Coupling Reaction

2013 ◽  
Vol 15 (4) ◽  
pp. 816-819 ◽  
Author(s):  
Nicolas Gigant ◽  
Laëtitia Chausset-Boissarie ◽  
Isabelle Gillaizeau
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Cross Coupling Reaction ◽  
Site Selective

Comparison of the Suzuki cross-coupling reactions of 4,7-dichloroquinoline and 7-chloro-4-iodoquinoline with arylboronic acids using phosphine-free palladium catalysis in water

2004 ◽  
Vol 82 (2) ◽  
pp. 206-214 ◽  
Author(s):  
Richard W Friesen ◽  
Laird A Trimble
Keyword(s):  
Phenylboronic Acid ◽  
Palladium Catalysis ◽  
Suzuki Reaction ◽  
Tetrabutylammonium Bromide ◽  
Cross Coupling ◽  
Palladium Acetate ◽  
Coupling Reactions ◽  
Reaction Conditions ◽  
Arylboronic Acids ◽  
Cross Coupling Reactions

4,7-Dichloroquinoline (1a) and 7-chloro-4-iodoquinoline (1b) undergo Suzuki cross-coupling reactions with arylboronic acids catalyzed by phosphine-free palladium acetate in boiling water. Using phenylboronic acid (2), the reaction of 1a provides 7-chloro-4-phenylquinoline (3) (78%) together with diphenylquinoline (4) (12%), while 1b reacts in a much more regioselective fashion and provides 3 in 98% isolated yield. Although 1b undergoes a more regioselective Suzuki reaction than 1a, additional important observations are that the overall reaction of 1b with 2 is three times slower than 1a and that the reaction occurs in the absence of tetrabutylammonium bromide. Using optimized reaction conditions, a variety of aryl and vinylboronic acids undergo regioselective Suzuki cross-coupling with 1b to provide the products 7, 10, and 11 in good to excellent yield.Key words: palladium, cross-coupling, regioselectivity, quinolines, boronic acids.

Site Selective Synthesis of PentaarylpyridinesviaMultiple Suzuki-Miyaura Cross-Coupling Reactions

2014 ◽  
Vol 356 (9) ◽  
pp. 1987-2008 ◽  
Author(s):  
Sebastian Reimann ◽  
Peter Ehlers ◽  
Andranik Petrosyan ◽  
Stefanie Kohse ◽  
Anke Spannenberg ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Selective Synthesis ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Site Selective

ChemInform Abstract: Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of the Bis(triflate) of Methyl 3,7-Dihydroxy-2-naphthoate.

ChemInform ◽  
2014 ◽  
Vol 45 (8) ◽  
pp. no-no
Author(s):  
Zien Khaddour ◽  
Nadi Eleya ◽  
Omer A. Akrawi ◽  
Aws M. Hamdy ◽  
Tamas Patonay ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Site Selective

ChemInform Abstract: Programmed Synthesis of Tetraarylthieno[3,2-b]thiophene by Site-Selective Suzuki Cross-Coupling Reactions of Tetrabromothieno[3,2-b]thiophene.

ChemInform ◽  
2014 ◽  
Vol 45 (24) ◽  
pp. no-no
Author(s):  
Hien Nguyen ◽  
Dung Xuan Nguyen ◽  
Thinh Quang Tran ◽  
Binh Ngoc Vo ◽  
Thao Huong Nguyen ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Site Selective
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