An empirical equation of state for pure water in the oceanographic region of temperature and pressure determined from direct measurements

1986 ◽  
Vol 31 (2) ◽  
pp. 189-194 ◽  
Author(s):  
Alvin Bradshaw ◽  
Karl E. Schleicher
SINERGI ◽  
2018 ◽  
Vol 22 (2) ◽  
pp. 107
Author(s):  
Supriatno Supriatno

Utilization of hydrogen as an alternative fuel is promising because it is environmentally friendly. Hydrogen system design requires accurate hydrogen densities. The density of hydrogen is determined based on experimental data. For gases that have a low density such as hydrogen, the effective measurement method is required. An apparatus has been designed to measure PVT properties of hydrogen at pressures up to 1 MPa and temperatures up to 500ºC. The apparatus uses a combination of isochoric and expansion methods. The method doesn’t need a measurement of pressures and temperatures along the isochoric line as required usually in the isochoric conventional method. Moreover, it doesn't need direct measurements of gas mass and gas volume. The volume was determined by measuring nitrogen at a pressure of 0.5 MPa and at temperatures up to 500ºC and by using Span’s equation of state. Measurements of hydrogen have been performed at a pressure up to 0.7 MPa and temperatures up to 498.217ºC. Densities of hydrogen obtained from the present measurement are compared with that obtained from calculation of Leachman's equation of state. Maximum deviation is 1.42% at a temperature of 498.217ºC and at a pressure of 0.2947 MPa and minimum deviation is 0.11% at temperature and pressure of 399.461ºC and 0.6981 MPa respectively.


1980 ◽  
Vol 45 (4) ◽  
pp. 977-983 ◽  
Author(s):  
Jan Sýs ◽  
Anatol Malijevský

An empirical equation of state was proposed, which is based on pseudoexperimental data on the state behaviour. The equation can be used at reduced temperatures from the range 0.7-100.0 and reduced densities up to 2. Calculated compressibility factors and critical properties agree well with available literature data.


2010 ◽  
Vol 14 (3) ◽  
pp. 859-863
Author(s):  
Marko Popovic

Most people would face a problem if there is a need to calculate the mole fraction of a substance A in a gaseous solution (a thermodynamic system containing two or more ideal gases) knowing its molarity at a given temperature and pressure. For most it would take a lot of time and calculations to find the answer, especially because the quantities of other substances in the system aren?t given. An even greater problem arises when we try to understand how special relativity affects gaseous systems, especially solutions and systems in equilibrium. In this paper formulas are suggested that greatly shorten the process of conversion from molarity to mole fraction and give us a better insight into the relativistic effects on a gaseous system.


1977 ◽  
Vol 66 (5) ◽  
pp. 2142-2144 ◽  
Author(s):  
Chen‐Tung Chen ◽  
Rana A. Fine ◽  
Frank J. Millero

1985 ◽  
Vol 285 (8) ◽  
pp. 725-763 ◽  
Author(s):  
J. L. Bischoff ◽  
R. J. Rosenbauer

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