Equilibrium Data of Hydrogen, Methane, Nitrogen, Carbon Dioxide, and Natural Gas in Semi-Clathrate Hydrates of Tetrabutyl Ammonium Bromide

2007 ◽  
Vol 52 (6) ◽  
pp. 2153-2158 ◽  
Author(s):  
Mosayyeb Arjmandi ◽  
Antonin Chapoy ◽  
Bahman Tohidi
2016 ◽  
Vol 830 ◽  
pp. 134-138 ◽  
Author(s):  
Camila Senna Figueiredo ◽  
Jailton Ferreira do Nascimento ◽  
Rony Oliveira de Sant'ana ◽  
Deborah Cordeiro de Andrade ◽  
Zaniel Souto Dantas Procópio ◽  
...  

Monoethylene glycol (MEG) is being widely applied as thermodynamic inhibitor to avoid formation of natural gas hydrates. High hydrophilicity, low toxicity, low viscosity, low solubility in liquid hydrocarbons and high capacity of dissolving salts are advantageous for the use of MEG in the natural gas production. In addition, MEG recovery can be easily achieved considering its low volatility in relation to water, which makes the process economical and environmentally feasible. The reuse of MEG is being theme of research and phase equilibrium data for the involved species are required. In this work, a experimental procedure to synthetize iron carbonate and, afterwards, determine its solubility in aqueous mixtures of MEG in the presence of carbon dioxide atmosphere have been developed. Furthermore, a series of solubility data has been measured. This work presents a worthy contribution to the description of iron carbonate aqueous solubilities in the presence of MEG and carbon dioxide, regarding the instability of the salt to respect of oxidation. Subsequently, the knowledge of the behavior of the iron carbonate solubilities is useful for the industrial unities of production of natural gas and recovery of MEG.


Tetrahedron ◽  
2014 ◽  
Vol 70 (16) ◽  
pp. 2669-2673 ◽  
Author(s):  
Hailei Wang ◽  
Yuping Ma ◽  
Heng Tian ◽  
Ajuan Yu ◽  
Junbiao Chang ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 539 ◽  
Author(s):  
Zhang-Qin Liu ◽  
Peng-Sheng You ◽  
Liang-Dong Zhang ◽  
Da-Qing Liu ◽  
Sheng-Shu Liu ◽  
...  

A highly efficient sulfonylation of para-quinone methides with sulfonyl hydrazines in water has been developed on the basis of the mode involving a tetrabutyl ammonium bromide (TBAB)-promoted sulfa-1,6-conjugated addition pathway. This reaction provides a green and sustainable method to synthesize various unsymmetrical diarylmethyl sulfones, showing good functional group tolerance, scalability, and regioselectivity. Further transformation of the resulting diarylmethyl sulfones provides an efficient route to some functionalized molecules.


2013 ◽  
Vol 404 ◽  
pp. 132-136
Author(s):  
Jing Han

To explore environmentally benign method for preparing TiO2, composite photocatalysts TiO2 immobilized on activated carbon fibers (TiO2/ACF) were prepared in caprolactam tetrabutyl ammonium bromide ionic liquid (CPL-TBAB ILs). The TiO2/ACF composites were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).The effects of different preparation condition were discussed by degradation of methyl orange (MO). The results showed that nanoTiO2 particles of mixed grain phase were well deposited on the activated carbon fiber surface. 96% of MO was removed under optimal preparation conditions.


2011 ◽  
Vol 25 (1) ◽  
pp. 159-161 ◽  
Author(s):  
Bin Guo ◽  
Erhong Duan ◽  
Yongfei Zhong ◽  
Liang Gao ◽  
Xuesong Zhang ◽  
...  

2019 ◽  
Vol 16 (11) ◽  
pp. 906-910
Author(s):  
Arman Shokooh Saljooghi ◽  
Hojatollah Khabazzadeh ◽  
Moj Khaleghi

A new series of benzamido alkyl naphthols were synthesized from the multi-component reaction of 4-(3′-methylthioureido)benzamide, aromatic aldehydes and 2-naphthol. Molten tetrabutyl ammonium bromide was used as a very efficient medium for this reaction while the use of common organic solvents gave no or poor yields. This method is an interesting instance of using molten salt as a medium in multicomponent reactions.


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