Deuterium isotope effect upon a bimolecular dehydrochlorination of tert-butyl chloride in acetonitrile

1969 ◽  
Vol 34 (6) ◽  
pp. 1985-1987 ◽  
Author(s):  
Dennis N. Kevill ◽  
James E. Dorsey
Keyword(s):  
Isotope Effect ◽  
Butyl Chloride ◽  
Deuterium Isotope Effect ◽  
Tert Butyl ◽  
Tert Butyl Chloride

CHLORINE ISOTOPE EFFECT IN REACTIONS OF TERT-BUTYL CHLORIDE

1954 ◽  
Vol 32 (10) ◽  
pp. 979-983 ◽  
Author(s):  
Rosalie M. Bartholomew ◽  
F. Brown ◽  
M. Lounsbury
Keyword(s):  
Silver Nitrate ◽  
Sodium Hydroxide ◽  
Isotope Effect ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Chlorine Isotope ◽  
Tert Butyl Chloride

When tert-butyl chloride reacts with either alcoholic silver nitrate or aqueous alcoholic sodium hydroxide the Cl35 compound reacts faster than the Cl37 compound. The ratio of the rates of reaction is[Formula: see text]

Orientational dependence of the translational energy transfer in the scattering of oriented fluoroform and tert‐butyl chloride molecules by a graphite(0001) surface

1990 ◽  
Vol 93 (10) ◽  
pp. 7416-7426 ◽  
Author(s):  
Stanislav I. Ionov ◽  
Michael E. LaVilla ◽  
Richard B. Bernstein
Keyword(s):  
Energy Transfer ◽  
Translational Energy ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Chloride

Surface temperature dependence of the steric effect in the scattering of oriented tert‐butyl chloride and fluoroform molecules by graphite(0001)

1990 ◽  
Vol 93 (10) ◽  
pp. 7406-7415 ◽  
Author(s):  
Stanislav I. Ionov ◽  
Michael E. LaVilla ◽  
R. Scott Mackay ◽  
Richard B. Bernstein
Keyword(s):  
Surface Temperature ◽  
Temperature Dependence ◽  
Steric Effect ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Chloride

scholarly journals tert-Butylation of 1-Naphthol with tert-Butyl Alcohol or tert-Butyl Chloride in the Presence of Sulfuric Acid or Zinc Chloride

1973 ◽  
Vol 31 (10) ◽  
pp. 831-834 ◽  
Author(s):  
Toshiyuki MIYATA ◽  
Takahiro HAMADA ◽  
Tsuneaki HIRASHIMA ◽  
Osamu MANABE ◽  
Hachiro HIYAMA
Keyword(s):  
Sulfuric Acid ◽  
Zinc Chloride ◽  
Butyl Alcohol ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Tert Butyl Chloride

Thermodynamic studies in solution. Part IV. Solvent effect on the solvolysis of tert-butyl chloride. A new treatment of the experimental data

1979 ◽  
Vol 57 (5) ◽  
pp. 500-502 ◽  
Author(s):  
Joaquim Jose Moura Ramos ◽  
Jacques Reisse ◽  
M. H. Abraham
Keyword(s):  
Free Energy ◽  
Solvent Effect ◽  
Free Energies ◽  
Butyl Chloride ◽  
Activation Free Energy ◽  
Tert Butyl ◽  
New Treatment ◽  
The One ◽  
Activated Complex ◽  
Tert Butyl Chloride

A new treatment of the solvent effect on the solvolysis of tert-butyl chloride is proposed. This treatment is based on activation free energy measurements and on transfer free energy measurements of the reactant (R) on the one hand and of a model (M) of the activated complex (AC) on the other hand. Solute–solvent interaction free energies for the reactant, the activated complex and the model compound are estimated. This estimation involves the calculation of the free energy of cavity formation of these various solutes (R, AC, and M) in all the solvents. These cavity terms, which are a function of the cohesive properties of the solvent and of the surface of the cavity do not reflect the electronic structure of the solute whereas the interaction free energy term does. The method we propose can be described as a new 'experimental' approach for the study of the charge separation in an activated complex.

ChemInform Abstract: EVALUATION OF THE FORCE CONSTANT FOR THE CARBON-CHLORIDE STRETCHING VIBRATION FOR TERT-BUTYL CHLORIDE USING MINDO 3

1976 ◽  
Vol 7 (9) ◽  
pp. no-no
Author(s):  
DONALD G. GRACZYK ◽  
ROBERT L. JULIAN ◽  
JAMES W. TAYLOR ◽  
S. D. WORLEY
Keyword(s):  
Force Constant ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Stretching Vibration ◽  
Tert Butyl Chloride
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