Solid-State Reaction Mechanisms in Monomer−Dimer Interconversions ofp-Bromonitrosobenzene. Single-Crystal-to-Single-Crystal Photodissociation and Formation of New Non-van der Waals Close Contacts

Vapours of p-benzoquinone (BQ) have been found to react with solid 2,4,5-trichlorophenol (TCP). The reaction product (BQ-TCP) separated in the form of monoclinic single crystals, the structure of which was determined by X-ray diffraction to reveal that the two molecules are linked by a single hydrogen bond between the carbonyl oxygen of BQ and the phenolic hydrogen of TCP.

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Synthesis of perovskite-type manganites Yb1−xDyxMnO3 (0.1 ≤ x ≤ 0.5) via solid-state reaction and high-pressure flux methods followed by structural characterization and magnetic property studies

New Journal of Chemistry ◽

10.1039/c4nj01876a ◽

2015 ◽

Vol 39 (4) ◽

pp. 2596-2601 ◽

Cited By ~ 5

Author(s):

Yingnan Zhang ◽

Fuyang Liu ◽

Tong Zheng ◽

Ziqing Zhang ◽

Wei Liu ◽

...

Keyword(s):

High Pressure ◽

Magnetic Property ◽

Solid State ◽

Single Crystal ◽

Structural Characterization ◽

Solid State Reaction ◽

Structural Difference ◽

Paramagnetic Property ◽

Perovskite Type

h-Yb1−xDyxMnO3 (0.1 ≤ x ≤ 0.5) and single crystal o-Yb0.5Dy0.5MnO3 were firstly synthesized, and o-Yb0.5Dy0.5MnO3 has the paramagnetic property due to slight structural difference.

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The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5

Zeitschrift für Naturforschung B ◽

10.1515/znb-1999-1202 ◽

1999 ◽

Vol 54 (12) ◽

pp. 1489-1494 ◽

Cited By ~ 1

Author(s):

Thomas J. Mormann ◽

Wolfgang Jeitschko

Keyword(s):

Crystal Structure ◽

Solid State ◽

Single Crystal ◽

Solid State Reaction ◽

Title Compound ◽

Empirical Formula ◽

Variable Parameters ◽

Structure Factors ◽

Linear Coordination ◽

Oxygen Atoms

The title compound was prepared by solid state reaction of Ag2O with Hg(NO3)2· H2O in air at 350 °C. Its crystal structure was determined from single-crystal diffractometer data: Pnma, a = 620.1(1) pm, b = 670.1(1) pm, c = 1267.5(2) pm, Z = 4, R = 0.026 for 586 structure factors and 33 variable parameters. The compound may be represented by the formula Ag(HgO)2NO3 . The mercury(II) together with the oxygen atoms form zig-zag chains with linear coordination of the mercury atoms. The oxygen atoms of these chains are linked via silver(I) atoms, thus forming two-dimensionally infinite nets, which contain the trigonal planar nitrate groups in interstices. Thus, only secondary Hg-O and Ag-O bond are formed between the nets.

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Interpenetrierende Clusterstränge in der Kristallstruktur von K0,77Nb6Cl15 / Interpenetrating Cluster Chains in the Structure of K0.77Nb6Cl15

Zeitschrift für Naturforschung B ◽

10.1515/znb-2001-1121 ◽

2001 ◽

Vol 56 (11) ◽

pp. 1238-1240 ◽

Cited By ~ 5

Author(s):

Andreas Nägele ◽

Cynthia Day ◽

Abdessadek Lachgar ◽

H.-Jürgen Meyer

Keyword(s):

Solid State ◽

Single Crystal ◽

Solid State Reaction ◽

Three Dimensional ◽

Orthorhombic Space Group ◽

X Ray ◽

Lattice Constants ◽

A Value ◽

Dimensional Network ◽

Ray Methods

The solid state reaction of KCl, NbCl5 and Nb powder at 760 °C yielded black crystals of KNb6Cl15. The structure of the compound has been determined using single-crystal X-ray methods. KNb6Cl15 crystallizes in the orthorhombic space group Pmma (no. 51) with lattice constants a = 1780.1(2), b = 1341.4(1), and c = 925.5(1) pm, Z = 4, and R1 = 0.039 for all 2727 observed reflections.[(Nb6Cl12i)Cl6/2a-a]- anions in the structure are linked via two Cla-a bridges to form one set of linear and one set of kinked chains along the crystallographic c and a directions. Four remaining Cla-a bridges interconnect both sets of chains to a three-dimensional network. The potassium occupancy on a 4k site was refined to a value of 0.384(3) consistent with the formula K0.77Nb6Cl15-. Ternäre Niobchloride des Formeltyps ANb6Cl15 wurden bereits verschiedentlich beschrieben. Verbindungen mit A = Li [1] und Na [2] kristallisieren kubisch (Ia3̅d) mit identischen Schweratomstrukturen. Die Alkalimetall-Ionen Li (KZ = 4) und Na (KZ = 6 ) besetzen in den Strukturen ANb6Cl15 aber unterschiedliche Splitlagen und sind dynamisch fehlgeordnet. Die Vertreter mit A = In und TI [3] kristallisieren orthorhombisch (Pmma). Ihre Kationen befinden sich in zweifach überdachten, würfelförmigen Cl-Umgebungen (KZ = 10). Die Kenntnis des Formeltyps ANb6Cl15 mit schweren Alkalimetallen ist noch unvollständig. Einkristallstrukturuntersuchungen für A = Rb, Cs ergaben Kationenfehlordnungen [4, 5]. Für die Verbindung KNb6Cl15 wurde eine Einkristallstrukturbestimmung durchgeführt (Tab. 1). Die Verbindung kristallisiert orthorhombisch in der Raumgruppe Pmma (Nr. 51) mit den Gitterkonstanten a = 1780,1(2), b = 1341,4(1) und c = 925,5(1) pm mit Z = 4 und ist isotyp zu den Inund TI-Verbindungen. Die Besetzung der K-Position (4k-Lage, mx-Punktsymmetrie) wurde zu 0,384(3) verfeinert, was der Zusammensetzung K0.77Nb6Cl15 entspricht (Tab. 2)#. Die Nb-Nb-Abstände in KNb6Cl15 liegen zwischen 291,47(6) und 296,45(7) pm, die Bindungslängen Nb-ClI betragen 243,3(1) - 247,18(9) und die Nb-Cla-Abstände 258,7(2) - 271,40(9) pm.

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Synthesis and Crystal Structure of K6Mo10O33

Zeitschrift für Naturforschung B ◽

10.1515/znb-2007-0101 ◽

2007 ◽

Vol 62 (1) ◽

pp. 1-4 ◽

Cited By ~ 2

Author(s):

Nachiappan Arumugam ◽

Eva-Maria Peters ◽

Martin Jansen

Keyword(s):

Crystal Structure ◽

Solid State ◽

Single Crystal ◽

Molybdenum Oxide ◽

Solid State Reaction ◽

X Ray Diffraction ◽

Synthesis And Crystal Structure ◽

Space Group ◽

X Ray ◽

Lattice Constants

A new potassium molybdenum oxide, K6Mo10O33, was synthesized by solid state reaction from the appropriate quantities of pre-dried MoO3 and K2MoO4, fired at around 650 °C for 2 d. The structure has been solved by using single crystal X-ray diffraction. The compound adopts the space group P1, with the lattice constants a = 7.7100(5), b = 11.9659(8), c = 17.1321(12) A° , α = 86.42 (10), β = 77.18(10), γ = 74.14(10)°. The structure is built up of infinite chains of edge-sharing MoO6 octahedra and groups of four MoO6 octahedra forming Mo4O17 units. These sub-units are connected together by common vertices.

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