Precursor π-Complex in the Addition of Vinyl Bromide on Si(100)

2007 ◽  
Vol 111 (17) ◽  
pp. 6365-6371 ◽  
Author(s):  
Q. J. Zhang ◽  
J. L. Wang ◽  
Z. F. Liu
Keyword(s):  
Vinyl Bromide ◽  
Π Complex

C–Br bond rupture in 193 nm photodissociation of vinyl bromide

1998 ◽  
Vol 231 (2-3) ◽  
pp. 345-353 ◽  
Author(s):  
Hideki Katayanagi ◽  
Nobuaki Yonekuira ◽  
Toshinori Suzuki
Keyword(s):  
Bond Rupture ◽  
Vinyl Bromide ◽  
193 Nm

ChemInform Abstract: π-Complex Formation and Collapse in Electrophilic Halogenation of Aromatic Substrates.

ChemInform ◽  
1987 ◽  
Vol 18 (47) ◽  
Author(s):  
O. M. E. EL-DUSOUQUI ◽  
K. A. M. MAHMUD ◽  
Y. SULFAB
Keyword(s):  
Complex Formation ◽  
Aromatic Substrates ◽  
Π Complex

ÉTARD REACTION: III. NATURE OF THE COMPLEX

1960 ◽  
Vol 38 (11) ◽  
pp. 2136-2142 ◽  
Author(s):  
Owen H. Wheeler
Keyword(s):  
Magnetic Susceptibility ◽  
Reaction Mechanism ◽  
Chloride Complex ◽  
Initial Formation ◽  
Spectroscopic Evidence ◽  
Chromyl Chloride ◽  
Π Complex ◽  
Products Of Reaction

Magnetic susceptibility measurements have shown that the chromium atoms in the toluene–chromyl chloride complex are tetravalent. The structure of the complex and the reaction mechanism are discussed. Spectroscopic evidence has been found of the initial formation of a π-complex. The products of reaction of chromyl chloride and ethylbenzene, isopropylbenzene, tetralin, and indane have been determined.

Catalytic deuterium exchange reactions with organics. XIII. Characteristic reactions of the Group VIII transition metals

1965 ◽  
Vol 18 (7) ◽  
pp. 1003 ◽  
Author(s):  
JL Garnett ◽  
WA Sollich
Keyword(s):  
Transition Metal ◽  
Hydrogen Exchange ◽  
Deuterium Oxide ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Group Viii ◽  
Exchange Reactions ◽  
Substitution Mechanism ◽  
Π Complex ◽  
Complex Adsorption

Activation procedures and hydrogen exchange reactions with six Group VIII transition metal catalysts (Pt, Pd, Ru, Rh, Ir, Ni) are reported for three characteristic reaction systems: (i) deuterium oxide/benzene, (ii) deuterium oxide/naphthalene, and (iii) deuterium oxide/n-octane. Results of these exchange reactions indicate that both π-complex adsorption and the dissociative π-complex substitution mechanism previously established for platinum are applicable to other Group VIII transition metal catalysts. For general catalytic labelling with isotopic hydrogen, platinum was found to be the most efficient of the catalysts investigated.

A Glimpse at the Chemistry of GeH2in Solution. Direct Detection of an Intramolecular Germylene–Alkene π-Complex

2011 ◽  
Vol 133 (27) ◽  
pp. 10523-10534 ◽  
Author(s):  
Paul S. Billone ◽  
Katie Beleznay ◽  
Cameron R. Harrington ◽  
Lawrence A. Huck ◽  
William J. Leigh
Keyword(s):  
Direct Detection ◽  
Π Complex

Synthesis and molecular structure of niobocene trimethylacetate and its π-complex with diphenylacetylene

1979 ◽  
Vol 165 (1) ◽  
pp. 39-47 ◽  
Author(s):  
A.A. Pasynskii ◽  
Yu.V. Skripkin ◽  
I.L. Eremenko ◽  
V.T. Kalinnikov ◽  
G.G. Aleksandrov ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Π Complex
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