Significant Melting Point Depression of Two-Dimensional Folded-Chain Crystals of Isotactic Poly(methyl methacrylate)s Observed by High-Resolution In Situ Atomic Force Microscopy

2013 ◽  
Vol 117 (18) ◽  
pp. 5594-5605 ◽  
Author(s):  
Yuma Takanashi ◽  
Jiro Kumaki
2008 ◽  
Vol 72 (1) ◽  
pp. 141-144 ◽  
Author(s):  
A. I. Vavouraki ◽  
C. V. Putnis ◽  
A. Putnis ◽  
E. H. Oelkers ◽  
P. G. Koutsoukos

AbstractCalcite growth rates were measured in the presence of sulphate using mixed-flow reactors and in situ Atomic Force Microscopy. Preliminary observations reveal that the kinetics and mechanism of the calcite growth was altered by the presence of sulphate. Calcite growth rates in the presence of sulphate (≥ mM) were decreased and two-dimensional nuclei tend to grow on top of existing nuclei, rather than spreading. The height of new nuclei was ~4 Å, 1 Å greater than that of pure calcite growth. This difference reflects the incorporation of tetrahedral SO2-4 anions into the calcite lattice.


2008 ◽  
Vol 72 (1) ◽  
pp. 419-424
Author(s):  
B. Goritschnig ◽  
K. R. Hallam ◽  
T. McMaster ◽  
V. Ragnarsdottir

AbstractAtomic force microscopy (AFM) has been used to monitor the appearance and behaviour of the hormone progesterone on mineral surfaces, including mica and highly oriented pyrolytic graphite (HOPG). Different solvents have been used resulting in various features on the two substrates. After the application of 254 nm ultra-violet (UV) light, changes in structure of the adsorbed hormone have been observed. To understand the reactions at the progesterone-mica interface in aqueous solution, adsorption has been studied in situ with AFM.


RSC Advances ◽  
2013 ◽  
Vol 3 (3) ◽  
pp. 708-712 ◽  
Author(s):  
Yongmei Tian ◽  
Jiahan Li ◽  
Mingjun Cai ◽  
Weidong Zhao ◽  
Haijiao Xu ◽  
...  

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