Energy Transfer and Activated Chemiluminescence during Thermal Oxidation of Polypropylene:  Evidence for Chemically Induced Electron Exchange Luminescence

2001 ◽  
Vol 34 (26) ◽  
pp. 9130-9138 ◽  
Author(s):  
Idriss Blakey ◽  
Graeme A. George ◽  
Norman C. Billingham







1994 ◽  
Vol 1189 (2) ◽  
pp. 175-180 ◽  
Author(s):  
M. Aránzazu Partearroyo ◽  
Elena Cabezón ◽  
José-Luis Nieva ◽  
Alicia Alonso ◽  
Félix M. Goñi




2000 ◽  
Vol 122 (36) ◽  
pp. 8631-8634 ◽  
Author(s):  
Waldemar Adam ◽  
Masakatsu Matsumoto ◽  
Alexei V. Trofimov


2015 ◽  
Vol 19 (01-03) ◽  
pp. 427-441 ◽  
Author(s):  
Adam Langlois ◽  
Hai-Jun Xu ◽  
Paul-Ludovic Karsenti ◽  
Claude P. Gros ◽  
Pierre D. Harvey

A trichromophoric dyad composed of an octa-β-alkyl-palladium(II)porphyrin (donor) and two tri-meso-aryl-zinc(II)porphyrins (acceptors) held by a truxene spacer exhibits very fast rates for triplet energy transfers at 77 (kET(T1) = 1.63 × 108 s-1) and 298 K (kET(T1) = 3.44 × 108 s-1), whereas the corresponding singlet energy transfer rates, kET(S1) = 3.9 × 1010 s-1 (77 K) and kET(S1) = 6.0 × 1010 s-1 (298 K), are also considered fast. The interpretation for these results is that the energy transfer processes proceed via a through bond Dexter mechanism (i.e. double electron exchange) supported by comparison with literature data and evidence for a moderate MO coupling between the donor and acceptor chromophores in the frontier MOs.





1971 ◽  
Vol 27 (19) ◽  
pp. 1253-1256 ◽  
Author(s):  
K. E. Maher ◽  
J. J. Leventhal


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