Kinetico-Mechanistic Studies on Intramolecular C–X Bond Activation (X = Br, Cl) of Amino-Imino Ligands on Pt(II) Compounds. Prevalence of a Concerted Mechanism in Nonpolar, Polar, and Ionic Liquid Media

2012 ◽  
Vol 31 (11) ◽  
pp. 4367-4373 ◽  
Author(s):  
Teresa Calvet ◽  
Margarita Crespo ◽  
Mercè Font-Bardía ◽  
Susanna Jansat ◽  
Manuel Martínez
Keyword(s):  
Ionic Liquid ◽  
Bond Activation ◽  
Mechanistic Studies ◽  
Liquid Media ◽  
Concerted Mechanism

Electrochemical Determination of pKaof N-Bases in Ionic Liquid Media

2011 ◽  
Vol 116 (1) ◽  
pp. 277-282 ◽  
Author(s):  
Rachid Barhdadi ◽  
Michel Troupel ◽  
Clément Comminges ◽  
Michel Laurent ◽  
Andrew Doherty
Keyword(s):  
Ionic Liquid ◽  
Electrochemical Determination ◽  
Liquid Media

Amine basicity: measurements of ion pair stability in ionic liquid media

Tetrahedron ◽  
2007 ◽  
Vol 63 (47) ◽  
pp. 11681-11685 ◽  
Author(s):  
Francesca D'Anna ◽  
Renato Noto
Keyword(s):  
Ionic Liquid ◽  
Ion Pair ◽  
Liquid Media

Preparation of cellulosic soft and composite materials using ionic liquid media and ion gels

Cellulose ◽  
2021 ◽  
Author(s):  
Akihiko Takada ◽  
Jun-ichi Kadokawa
Keyword(s):  
Ionic Liquid ◽  
Composite Materials ◽  
Liquid Media ◽  
Ion Gels

Electrochemical and electronic properties of flower-like MoS2 nanostructures in aqueous and ionic liquid media

RSC Advances ◽  
2015 ◽  
Vol 5 (71) ◽  
pp. 57943-57949 ◽  
Author(s):  
Kavita Pandey ◽  
Pankaj Yadav ◽  
Indrajit Mukhopadhyay
Keyword(s):  
Ionic Liquid ◽  
Electronic Properties ◽  
Hydrothermal Method ◽  
Liquid Media ◽  
One Pot

In the present work, we report a facile strategy to synthesize uniform 3D flower-like MoS2 nanostructures prepared by a one-pot hydrothermal method and investigate their supercapacitive behavior.

Preparation of Substituted Allyl Acetates and Sulfones from Baylis—Hillman Adducts in Ionic Liquid Media.

ChemInform ◽  
2003 ◽  
Vol 34 (38) ◽  
Author(s):  
George W. Kabalka ◽  
Bollu Venkataiah ◽  
Gang Dong
Keyword(s):  
Ionic Liquid ◽  
Liquid Media

Nickel-Catalyzed Hydroalkenylation of Alkynes through C–F Bond Activation: Synthesis of 2-Fluoro-1,3-dienes

Synthesis ◽  
2017 ◽  
Vol 49 (16) ◽  
pp. 3569-3575 ◽  
Author(s):  
Junji Ichikawa ◽  
Yota Watabe ◽  
Kohei Kanazawa ◽  
Takeshi Fujita
Keyword(s):  
Bond Activation ◽  
Oxidative Cyclization ◽  
Coupling Reactions ◽  
Mechanistic Studies ◽  
Co Catalyst

2-Fluoro-1,3-dienes were synthesized through nickel-catalyzed coupling reactions between β,β-difluorostyrenes and alkynes in the presence of ZrF4 as co-catalyst and a hydride source derived from triethylborane and lithium isopropoxide. Mechanistic studies revealed that the carbon–fluorine bond was cleaved by β-fluorine elimination from intermediary nickelacyclopentenes generated through oxidative cyclization of the two substrates.

scholarly journals Recovery of Metals from Secondary Raw Materials by Coupled Electroleaching and Electrodeposition in Aqueous or Ionic Liquid Media

Metals ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 556 ◽  
Author(s):  
Nathalie Leclerc ◽  
Sophie Legeai ◽  
Maxime Balva ◽  
Claire Hazotte ◽  
Julien Comel ◽  
...  
Keyword(s):  
Physical Chemistry ◽  
Ionic Liquid ◽  
Chemical Engineering ◽  
Electrode Materials ◽  
Raw Materials ◽  
Aqueous Media ◽  
Hybrid Technique ◽  
Liquid Media ◽  
Secondary Raw Materials ◽  
Strategic Resources

This paper presents recent views on a hybrid process for beneficiation of secondary raw materials by combined electroleaching of targeted metals and electrodeposition. On the basis of several case studies with aqueous solutions or in ionic liquid media, the paper describes the potential and the limits of the novel, hybrid technique, together with the methodology employed, combining determination of speciation, physical chemistry, electrochemistry, and chemical engineering. On one hand, the case of electroleaching/electrodeposition (E/E) process in aqueous media, although often investigated at the bench scale, appears nevertheless relatively mature, because of the developed methodology, and the appreciable current density allowed, and so it can be used to successfully treat electrode materials of spent Zn/MnO2 batteries or Ni/Cd accumulators and Waelz oxide. On the other hand, the use of ionic liquids as promising media for the recovery of various metals can be considered for other types of wastes, as shown here for the case of electrodes of aged fuel cells. The combined (E/E) technique could be successfully used for the above waste, in particular by the tricky selection of ionic liquid media. Nevertheless, further investigations in physical chemistry and chemical engineering appear necessary for possible developments of larger-scale processes for the recovery of these strategic resources.

Shifting the equilibrium of methanol synthesis from CO2 by in situ absorption using ionic liquid media

2019 ◽  
Vol 3 (12) ◽  
pp. 3399-3405
Author(s):  
Jenny Reichert ◽  
Stephanie Maerten ◽  
Katharina Meltzer ◽  
Alexander Tremel ◽  
Manfred Baldauf ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Methanol Synthesis ◽  
Liquid Media ◽  
Alkali Salt ◽  
In Situ Absorption

A promising way to increase the methanol yields in CO2 hydrogenation significantly up to 60% by in situ sorption of methanol and water in alkali salt-doped ionic liquids (ILs) is demonstrated.

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