Ionic Liquid-Based Gels for Applications in Electrochemical Energy Storage and Conversion Devices: A Review of Recent Progress and Future Prospects

Ionic liquids (ILs) are molten salts that are entirely composed of ions and have melting temperatures below 100 °C. When immobilized in polymeric matrices by sol–gel or chemical polymerization, they generate gels known as ion gels, ionogels, ionic gels, and so on, which may be used for a variety of electrochemical applications. One of the most significant research domains for IL-based gels is the energy industry, notably for energy storage and conversion devices, due to rising demand for clean, sustainable, and greener energy. Due to characteristics such as nonvolatility, high thermal stability, and strong ionic conductivity, IL-based gels appear to meet the stringent demands/criteria of these diverse application domains. This article focuses on the synthesis pathways of IL-based gel polymer electrolytes/organic gel electrolytes and their applications in batteries (Li-ion and beyond), fuel cells, and supercapacitors. Furthermore, the limitations and future possibilities of IL-based gels in the aforementioned application domains are discussed to support the speedy evolution of these materials in the appropriate applicable sectors.

Graphene-based dual-functional chiral metamirror composed of complementary 90° rotated U-shaped resonator arrays and its equivalent circuit model

An equivalent circuit model (ECM) using a MATLAB code to analyze a tunable two-layered graphene-based chiral dual-function metamirror, is proposed in this work. The investigated metastructure is composed of complementary U-shaped graphene resonator arrays in the terahertz (THz) region. The ECM analysis could be used for any two-layered chiral metastructure for any frequencies, containing resonators with a thickness less than λ/50. The characteristics of the proposed tunable metamirror were analyzed numerically using the finite element method (FEM) in CST Software to verify the ECM analysis. The proposed metamirror can be used in polarization-sensitive devices in the THz region with simpler biasing without a need for ion gels or similar. It works as a broadband TE and multiband (four bands) TM mirror in the 0.3–4.5 THz bandwidth with a strong linear dichroism (LD) response (up to 96%). The designed mirror is a dynamically tunable, dual-functional structure, requiring only 90° rotation of the incident electromagnetic fields to switch between broadband and multiband spectral behavior making it a promising candidate for future THz intelligent systems. The proposed ECM is in agreement with the FEM results. The ECM analysis provides a simple, fast, and effective way to understand the metamirror’s behavior and guides for the design and analysis of graphene-based chiral metastructures in the THz region.

Polymerizable Choline- and Imidazolium-Based Ionic Liquids Reinforced with Bacterial Cellulose for 3D-Printing

In this work, a novel approach is demonstrated for 3D-printing of bacterial cellulose (BC) reinforced UV-curable ion gels using two-component solvents based on 1-butyl-3-methylimidazolium chloride or choline chloride combined with acrylic acid. Preservation of cellulose’s crystalline and nanofibrous structure is demonstrated using wide-angle X-ray diffraction (WAXD) and atomic force microscopy (AFM). Rheological measurements reveal that cholinium-based systems, in comparison with imidazolium-based ones, are characterised with lower viscosity at low shear rates and improved stability against phase separation at high shear rates. Grafting of poly(acrylic acid) onto the surfaces of cellulose nanofibers during UV-induced polymerization of acrylic acid results in higher elongation at break for choline chloride-based compositions: 175% in comparison with 94% for imidazolium-based systems as well as enhanced mechanical properties in compression mode. As a result, cholinium-based BC ion gels containing acrylic acid can be considered as more suitable for 3D-printing of objects with improved mechanical properties due to increased dispersion stability and filler/matrix interaction.

A Review on Ionic Liquid Gas Separation Membranes

Ionic liquids have attracted the attention of the industry and research community as versatile solvents with unique properties, such as ionic conductivity, low volatility, high solubility of gases and vapors, thermal stability, and the possibility to combine anions and cations to yield an almost endless list of different structures. These features open perspectives for numerous applications, such as the reaction medium for chemical synthesis, electrolytes for batteries, solvent for gas sorption processes, and also membranes for gas separation. In the search for better-performing membrane materials and membranes for gas and vapor separation, ionic liquids have been investigated extensively in the last decade and a half. This review gives a complete overview of the main developments in the field of ionic liquid membranes since their first introduction. It covers all different materials, membrane types, their preparation, pure and mixed gas transport properties, and examples of potential gas separation applications. Special systems will also be discussed, including facilitated transport membranes and mixed matrix membranes. The main strengths and weaknesses of the different membrane types will be discussed, subdividing them into supported ionic liquid membranes (SILMs), poly(ionic liquids) or polymerized ionic liquids (PILs), polymer/ionic liquid blends (physically or chemically cross-linked ‘ion-gels’), and PIL/IL blends. Since membrane processes are advancing as an energy-efficient alternative to traditional separation processes, having shown promising results for complex new separation challenges like carbon capture as well, they may be the key to developing a more sustainable future society. In this light, this review presents the state-of-the-art of ionic liquid membranes, to analyze their potential in the gas separation processes of the future.