Near-IR Spectroscopic Monitoring of Analytes during Microbially Catalysed Baeyer−Villiger Bioconversions

2002 ◽  
Vol 6 (4) ◽  
pp. 569-576 ◽  
Author(s):  
Paul A. Bird ◽  
David C. A. Sharp ◽  
John M. Woodley
1995 ◽  
Vol 10 ◽  
pp. 629-630 ◽  
Author(s):  
R. Schulz ◽  
Th. Encrenaz ◽  
J.A. Stüwe ◽  
G. Wiedemann

2003 ◽  
Vol 212 ◽  
pp. 253-254
Author(s):  
Watson P. Varricatt ◽  
Peredur M. Williams ◽  
Nagarhalli M. Ashok

The near-IR spectrum of the periodic dust making WCpd+O4-5 binary WR 140 was monitored to cover the 2001 periastron passage and maximum colliding-wind activity. The He i λ1.083μm emission-line profile showed the appearence of a subpeak on epochs close to periastron passage. The evolution of the subpeak was consistent with the motion of the stars and the colliding wind region. The appearance and evolution of the emission subpeak suggests that the theoretical 1/r dependence of X-ray flux does not hold, so that there is no need to change the values of eccentricity and epoch of periastron passage derived from the RV orbit. JHK spectra show variations of the continuum and and dilution of the emission lines, in agreement with the production and cooling of dust.


2020 ◽  
Vol 500 (2) ◽  
pp. 2063-2075
Author(s):  
Conor Wildy ◽  
Hermine Landt ◽  
Martin J Ward ◽  
Bożena Czerny ◽  
Daniel Kynoch

ABSTRACT The nucleus of the active galaxy NGC 5548 was the target of two intensive spectroscopic monitoring campaigns at X-ray, ultraviolet (UV), and optical frequencies in 2013/2014. These campaigns detected the presence of a massive obscuration event. In 2016/2017, Landt et al. conducted a near-IR spectroscopic monitoring campaign on NGC 5548 and discovered He i  1.08-μm absorption. Here, we decompose this absorption into its components and study its time variability. We attribute the narrow He  i absorption lines to the warm absorber (WA) and, as for the newly appeared low-ionization WA lines in the UV, their presence is most likely due to a reduction in ionization parameter caused by the obscurer. The observed variability of the narrow He i absorption is consistent with what is expected for the WA. Most importantly, we also detect fast, broad He i absorption, which we attribute to the obscurer. This He i broad absorption, which is indicative of a high column density gas, is unsaturated and variable on time-scales of a few months. The observed variability of the obscurer is mainly due to changes in ionization, although density changes also play a role. We test the physical cycle model of Dehghanian et al. which proposes that helium recombination can account for how the obscurer influences the physics of the WA gas. Our results support their model, but also indicate that the reality might be more complex.


1992 ◽  
Vol 46 (12) ◽  
pp. 1809-1815 ◽  
Author(s):  
Jie Lin ◽  
Chris W. Brown

The concentrations of NaCl in aqueous solutions have been determined with the use of near-IR spectra between 1100 and 1900 nm. Models expressing the concentration of NaCl are developed with linear and nonlinear regression with the use of the absorbances at selected wavelengths and with principal component regression (PCR) using entire spectra. Temperature perturbations on water bands interfere with the measurement of NaCl but can be removed by linear or nonlinear regressions using the absorbances at the wavelengths where the temperature effects are zero, or they can be accounted for by PCR. Standard errors of 5 mM and a detection limit of IS mM are obtained for NaCl. This technique can be applied for quantitative analysis of NaCl in the laboratory or can be readily adapted for continuous monitoring in process control.


1999 ◽  
Vol 08 (04) ◽  
pp. 519-525
Author(s):  
SHEN YUQUAN ◽  
LI ZHAO ◽  
ZHAO YUXIA ◽  
ZHAI JIANFENG ◽  
ZHOU JIAYUN ◽  
...  

An UV-VIS-Near-IR spectroscopic method for determination of optical loss in organic/polymeric films has been suggested. The optical losses of two polyimide polymers with push-pull azobenzene chromophore attached were examined by this method and the data were calibrated by conventional optical method.


2015 ◽  
Vol 119 (36) ◽  
pp. 9534-9540 ◽  
Author(s):  
Wei-Wei Yang ◽  
Zong-Jun Li ◽  
Shu-Hui Li ◽  
Xiang Gao

1996 ◽  
Vol 158 ◽  
pp. 325-326
Author(s):  
A. Evans ◽  
T.R. Geballe ◽  
J.M.C. Rawlings ◽  
A.D. Scott

Nova V705 Cas was discovered on 1993 December 7, several days before maximum light. The light curve indicates that t2 ≃ 40 d (see e.g. [4]), characteristic of dust-forming novae. The light curve went into decline on day 58, indicating the formation of an optically thick dust shell. IR spectra have been obtained regularly since outburst using the cooled grating spectrometer CGS4 on the United Kingdom InfraRed Telescope (UKIRT). We present here the results of ongoing IR spectroscopic monitoring of this nova.


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