Vibrationally Excited Nitric Oxide Produced in the Flash Photolysis of Nitrosyl Chloride

Nature ◽  
1961 ◽  
Vol 189 (4763) ◽  
pp. 455-456 ◽  
Author(s):  
N. BASCO ◽  
R. G. W. NORRISH
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis ◽  
Nitrosyl Chloride ◽  
Vibrationally Excited

Energy disequilibrium in the flash photolysis of NO 2

1973 ◽  
Vol 334 (1599) ◽  
pp. 553-568 ◽  
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis ◽  
Vibrational Energy ◽  
Dissociation Limit ◽  
Primary Process ◽  
Transfer Energy ◽  
Vibrationally Excited ◽  
Absolute Concentrations ◽  
The Absolute ◽  
Excited Oxygen

From measurements of the absolute concentrations of vibrationally excited oxygen produced in levels v" = 4 to v" = 13, it is concluded that ca . 20 % of the exothermicity of the reaction O( 3 P) + NO 2 → NO + O + 2 ( v" ≤11) (1) appears initially as vibrational energy in oxygen. Vibrationally excited nitric oxide ( v" = 1, 2) is also observed and may be produced in this reaction or in the primary process NO 2 + hv → NO ( v" ≤ 2) + O( 3 P). More highly excited oxygen ( v" ≤ 15), with energy exceeding the exothermicity of the reaction, is produced in reaction (1) when the NO 2 is first excited by radiation above the dissociation limit near 400 nm. The excited NO 2 thus produced can also transfer energy to nitric oxide. NO 2 * + NO( v" = 0) → NO 2 + NO( v" = 1).

Vibrationally excited nitric oxide produced in the flash photolysis of nitrosyl halides

1962 ◽  
Vol 268 (1334) ◽  
pp. 291-303 ◽  
Keyword(s):  
Nitric Oxide ◽  
Energy Transfer ◽  
Ground State ◽  
Vibrational Relaxation ◽  
Direct Evidence ◽  
Flash Photolysis ◽  
Vibrational Energy ◽  
Electronic States ◽  
Vibrationally Excited ◽  
Direct Production

The flash photolysis of nitrosyl chloride and nitrosyl bromide has been studied under isothermal conditions. Vibrationally excited nitric oxide molecules were produced and all levels from v " = 0 to v " = 11 were observed in absorption from the ground electronic states in the β, γ, δ and Є systems. Some of these bands have not previously been reported. The mechanism of the production is either directly NO R + hv → NO ( X 2 II , v ≤ 11) + R ( 2 P ), or by the sequence which includes the reactions NO R + hv → NO( 4 II ) + R , NO. 4 II + M → NO ( X 2 II , v > 0) + M In the latter case, the 4 II state of NO lies not more than 3·5 eV above the ground state. Other possible mechanisms and models accounting for the direct production of vibrationally excited NO in its ground electronic states are discussed. By flashing chlorine in the presence of NOCl it was shown that the reaction Cl + NOCl → Cl 2 + NO ( v > 0) does not occur, thus providing direct evidence that in reactions of the type A + BCD → AB + CD only the AB molecule containing the newly formed bond can be vibrationally excited. Vibrational relaxation is very rapid and probably occurs by step-wise degradation involving resonance vibrational energy transfer. NOCl and NOBr are very efficient and with NO itself the reaction NO ( v = n ) + NO ( v = 0) → NO ( v = n -1) + NO ( v = 1) can be followed.

The β and γ bands of nitric oxide observed during the flash photolysis of nitrosyl chloride

1971 ◽  
Vol 37 (2) ◽  
pp. 240-251 ◽  
Author(s):  
R. Engleman ◽  
P.E. Rouse
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis ◽  
Nitrosyl Chloride

The absorption spectrum of SO and the flash photolysis of sulphur dioxide and sulphur trioxide

1959 ◽  
Vol 249 (1259) ◽  
pp. 498-512 ◽  
Keyword(s):  
Absorption Spectrum ◽  
Dissociation Energy ◽  
Sulphur Dioxide ◽  
Flash Photolysis ◽  
Ultra Violet ◽  
Vibrationally Excited ◽  
A Value ◽  
Continuous Absorption ◽  
Sulphur Trioxide ◽  
Normal Spectrum

The flash photolysis of sulphur dioxide under adiabatic conditions results in the complete temporary disappearance of its spectrum , which then slowly regains its original intensity over a period of several milliseconds. Simultaneously with the disappearance of the sulphur dioxide spectrum a continuous absorption appears in the far ultra-violet and fades slowly as the sulphur dioxide reappears. It is shown that the effect of the flash is thermal rather than photochemical, and the possibility of the existence of an isomer of sulphur dioxide at high temperatures is discussed; the disappearance of the normal spectrum on flashing is explained in this way. Several previously unrecorded bands of SO observed in the photolysis indicate that the vibrational numbering of its spectrum should be revised by the addition of 2 to the present values of v' . This leads to a value of the dissociation energy of 123.5 kcal. In formation about the levels v' = 4, 5 and 6 has also been obtained. The isothermal flash photolysis of sulphur trioxide results in the appearance of vibrationally excited SO, and the primary photochemical step in this reaction is discussed.

Towards Vibrationally Excited Nitric Oxide Monitoring (VENOM) in a Laminar, Hypersonic Boundary Layer

2020 ◽  
Author(s):  
Zachary D. Buen ◽  
Casey Broslawski ◽  
Madeline Smotzer ◽  
Jason E. Kuszynski ◽  
Simon North ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Boundary Layer ◽  
Hypersonic Boundary Layer ◽  
Vibrationally Excited

Direct Measurement by Laser Flash Photolysis of Intramolecular Electron Transfer in a Two-Domain Construct of Murine Inducible Nitric Oxide Synthase

2006 ◽  
Vol 128 (11) ◽  
pp. 3808-3811 ◽  
Author(s):  
Changjian Feng ◽  
Clayton Thomas ◽  
Michael A. Holliday ◽  
Gordon Tollin ◽  
John C. Salerno ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Electron Transfer ◽  
Nitric Oxide Synthase ◽  
Inducible Nitric Oxide Synthase ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Intramolecular Electron Transfer ◽  
Oxide Synthase ◽  
Inducible Nitric Oxide

Direct Measurement by Laser Flash Photolysis of Intraprotein Electron Transfer in a Rat Neuronal Nitric Oxide Synthase

2007 ◽  
Vol 129 (17) ◽  
pp. 5621-5629 ◽  
Author(s):  
Changjian Feng ◽  
Gordon Tollin ◽  
James T. Hazzard ◽  
Nickolas J. Nahm ◽  
J. Guy Guillemette ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Electron Transfer ◽  
Nitric Oxide Synthase ◽  
Direct Measurement ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Neuronal Nitric Oxide Synthase ◽  
Laser Flash ◽  
Oxide Synthase

THE ISOTOPE EXCHANGE REACTION BETWEEN LABELLED NITRIC OXIDE,15NO AND NITROSYL CHLORIDE,14NOCl1

1961 ◽  
Vol 65 (6) ◽  
pp. 1084-1085
Author(s):  
Lester P. Kuhn ◽  
Chester Butkiewicz
Keyword(s):  
Nitric Oxide ◽  
Exchange Reaction ◽  
Isotope Exchange ◽  
Nitrosyl Chloride ◽  
Isotope Exchange Reaction

ChemInform Abstract: MECHANISM OF THE PHOTOOXIDATION OF FORMALDEHYDE STUDIED BY FLASH PHOTOLYSIS OF FORMALDEHYDE-OXYGEN-NITRIC OXIDE MIXTURES

1982 ◽  
Vol 13 (47) ◽  
Author(s):  
B. VEYRET ◽  
J.-C. RAYEZ ◽  
R. LESCLAUX
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis

Dual Effects of the Substrate and Pterins on the Kinetics of CO Binding to Neuronal Nitric Oxide Synthase: A Laser Flash Photolysis Study

2005 ◽  
Vol 34 (6) ◽  
pp. 752-753
Author(s):  
Simona N. Bengea ◽  
Yasuyuki Araki ◽  
Osamu Ito ◽  
Jotaro Igarashi ◽  
Hirofumi Kurokawa ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Nitric Oxide Synthase ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Neuronal Nitric Oxide Synthase ◽  
Laser Flash ◽  
Oxide Synthase ◽  
Kinetics Of
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