scholarly journals Ceramic-like stable CsPbBr3 nanocrystals encapsulated in silica derived from molecular sieve templates

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Qinggang Zhang ◽  
Bo Wang ◽  
Weilin Zheng ◽  
Long Kong ◽  
Qun Wan ◽  
...  

AbstractAchieving good stability while maintaining excellent properties is one of the main challenges for enhancing the competitiveness of luminescent perovskite CsPbX3 (X=Cl, Br, I) nanocrystals (NCs). Here, we propose a facile strategy to synthesize ceramic-like stable and highly luminescent CsPbBr3 NCs by encapsulating them into silica derived from molecular sieve templates at high temperature (600–900 oC). The obtained CsPbBr3-SiO2 powders not only show high photoluminescence quantum yield (~71%), but also show an exceptional stability comparable to the ceramic Sr2SiO4:Eu2+ green phosphor. They can maintain 100% of their photoluminescence value under illumination on blue light-emitting diodes (LEDs) chips (20 mA, 2.7 V) for 1000 h, and can also survive in a harsh hydrochloric acid aqueous solution (1 M) for 50 days. We believe that the above robust stabilities will significantly enhance the potential of perovskite CsPbX3 NCs to be practically applied in LEDs and backlight displays.

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Yan ◽  
Qionghua Mo ◽  
Shuangyi Zhao ◽  
Wensi Cai ◽  
Zhigang Zang

With a high photoluminescence quantum yield (PLQY) being able to exceed 90% for those prepared by hot injection method, CsPbBr3 quantum dots (QDs) have attracted intensive attentions for white light-emitting...


RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26415-26420
Author(s):  
Yue Yao ◽  
Si-Wei Zhang ◽  
Zijian Liu ◽  
Chun-Yun Wang ◽  
Ping Liu ◽  
...  

A Bi3+-doped Cs2SnCl6 exhibits photoluminescence at around 456 nm and a photoluminescence quantum yield of 31%. The blue LED based on the Bi3+-doped Cs2SnCl6 phosphor exhibits a long life of 120 hours and a CIE color coordinates of (0.14, 0.11).


2018 ◽  
Vol 53 ◽  
pp. 01035
Author(s):  
Shulv Zhang ◽  
Yuhang Yin ◽  
Weiling Luan ◽  
Mengke Liu

Inorganic perovskite light-emitting diodes (PeLEDs) with full coverage and compact films were realized by doping a certain amount of PEO into perovskite emitting layer. The additive PEO (Polyethylene oxide) can not only improve the coverage of films by physically filling the pin-holes of crystal boundaries but also act as a protective layer to passivate the films, which successfully reduce the rate of non-radiative recombination, and enhance photoluminescence quantum yield (PLQY) of the CsPbBr3 films. In addition, PEO can also decrease the surface roughness of the perovskite films. As a result, the addition of PEO can improve the transport capability of carriers in PeLEDs. By optimizing the concentration of PEO, a maximum external quantum efficiency (EQE) of 0.26% and brightness of 1432 cd/m2 were achieved, which is significantly improved compared with previous work. The results presented in this paper shows that the additive PEO in perovskite precursor solution paves a new way for the application in PeLEDs.


Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15791-15799 ◽  
Author(s):  
Hao-Hua Deng ◽  
Qiong-Qiong Zhuang ◽  
Kai-Yuan Huang ◽  
Paramasivam Balasubramanian ◽  
Zhen Lin ◽  
...  

White-light-emitting devices are successfully fabricated by using solid-state copper nanoclusters as the sole phosphors with aggregation-induced emission properties.


2015 ◽  
Vol 754-755 ◽  
pp. 567-570
Author(s):  
Syarifah Aminah Ismail ◽  
Noorina Hidayu Jamil ◽  
Kamarudin Hussin ◽  
Mohd Arif Anuar Mohd Salleh

This project deals with the experimental results of leaching of Sn from solder dross by means of leaching using different concentration of hydrochloric acid (HCl). Solder dross was sieved to obtain a mean particle size of 75 μm. The solder dross powder obtained was leached by using HCl acid aqueous solution. To optimize the parameter required for recovery of Sn from solder dross, initially the bench scale studies were carried out using varying acid concentration, stirring time and temperature. The experimental indicate that 98.7% of Sn was leached out from solder dross using 0.1M of HCl, 24 hours of stirring time at60°C solution temperature.


2014 ◽  
Vol 513-517 ◽  
pp. 165-168
Author(s):  
Hao Li ◽  
Si Rong Yu

A novel method for preparing oleophobic surface is presented. In this article, an oleophobic surface on X70 pipeline steel was prepared successfully by the combination of shot blasting, hydrochloric acid aqueous solution etching, and modified with low-energy material. The influences of the concentration of hydrochloric acid and chemical etching time on the oleophobicity were analyzed. And the optimal experimental parameters were determined. The surface morphology and chemical composition were observed by the field emission scanning electron microscopy (FESEM) and energy dispersive spectrometer (EDS), and the contact angle was measured by contact angle meter. The results showed that micro-nanocomposite structure on the substrate was formed after shot blasting and chemical etching of hydrochloric acid aqueous solution. After low-energy modified, the specimen obtained the better oleophobicity, and the maximum contact angle between the surface and peanut oil was 140°.


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