The evolution of multicomponent systems at high pressures Part II.The Alder–Wainwright, high-density, gas–solid phase transition of the hard-sphere fluid

1999 ◽  
Vol 1 (14) ◽  
pp. 3277-3285 ◽  
Author(s):  
J F. Kenney
2006 ◽  
Vol 124 (4) ◽  
pp. 044508 ◽  
Author(s):  
V. G. Baonza ◽  
M. Taravillo ◽  
A. Cazorla ◽  
S. Casado ◽  
M. Cáceres

2013 ◽  
Vol 4 (1) ◽  
Author(s):  
Jinjin Li ◽  
Olaseni Sode ◽  
Gregory A. Voth ◽  
So Hirata

1971 ◽  
Vol 3 (2) ◽  
pp. 776-780 ◽  
Author(s):  
Jean-Pierre Hansen ◽  
Dominique Levesque ◽  
Daniel Schiff

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1575
Author(s):  
Kseniya D. Skakunova ◽  
Denis A. Rychkov

The polymorphism of molecular crystals is a well-known phenomenon, resulting in modifications of physicochemical properties of solid phases. Low temperatures and high pressures are widely used to find phase transitions and quench new solid forms. In this study, L-Leucinium hydrogen maleate (LLHM), the first molecular crystal that preserves its anomalous plasticity at cryogenic temperatures, is studied at extreme conditions using Raman spectroscopy and optical microscopy. LLHM was cooled down to 11 K without any phase transition, while high pressure impact leads to perceptible changes in crystal structure in the interval of 0.0–1.35 GPa using pentane-isopentane media. Surprisingly, pressure transmitting media (PTM) play a significant role in the behavior of the LLHM system at extreme conditions—we did not find any phase change up to 3.05 GPa using paraffin as PTM. A phase transition of LLHM to amorphous form or solid–solid phase transition(s) that results in crystal fracture is reported at high pressures. LLHM stability at low temperatures suggests an alluring idea to prove LLHM preserves plasticity below 77 K.


2014 ◽  
Vol 140 (18) ◽  
pp. 184507 ◽  
Author(s):  
Toshihiro Kaneko ◽  
Jaeil Bai ◽  
Kenji Yasuoka ◽  
Ayori Mitsutake ◽  
Xiao Cheng Zeng

1987 ◽  
Vol 42 (3) ◽  
pp. 231-235
Author(s):  
Hyearn-Maw Koo ◽  
Siegfried Hess

Solution of the Kirkwood-Smoluchowski equation for a hard sphere fluid yields an expression for the viscosity which shows a dramatic pretransitional increase and a divergence at a number density close to that one observed in computer simulations and in colloidal dispersions. The value for the transition density stems from a boundary condition at the surface of the hard sphere in the configurational relative pair-space and makes use of the density dependence of the pair-correlation function and of its derivative at the point of contact.


2019 ◽  
Vol 21 (24) ◽  
pp. 13070-13077 ◽  
Author(s):  
Jianxiang Tian ◽  
Hua Jiang ◽  
A. Mulero

A review on the numerical virial coefficients, compressibility factor, fluid–solid phase transition point and equations of the state of hard sphere fluids.


1972 ◽  
Vol 47 (4) ◽  
pp. 1069-1086 ◽  
Author(s):  
Yoshiki Kuramoto ◽  
Hiroshi Furukawa

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