Non-steady-state living polymerization: a new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

2005 ◽  
pp. 3870 ◽  
Author(s):  
Hassen Bouchékif ◽  
Marcia I. Philbin ◽  
Eamon Colclough ◽  
Allan J. Amass
Keyword(s):  
Steady State ◽  
Ambient Temperature ◽  
Ring Opening ◽  
Living Polymerization ◽  
Ring Opening Polymerization ◽  
Cationic Ring Opening Polymerization

A squaramide and tertiary amine: an excellent hydrogen-bonding pair organocatalyst for living polymerization

2015 ◽  
Vol 6 (20) ◽  
pp. 3754-3757 ◽  
Author(s):  
Jingjing Liu ◽  
Cheng Chen ◽  
Zhenjiang Li ◽  
Wenzhuo Wu ◽  
Xu Zhi ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Ambient Temperature ◽  
Tertiary Amine ◽  
Ring Opening ◽  
Living Polymerization ◽  
Ring Opening Polymerization

A hydrogen-bond motif based on a squaramide and sparteine efficiently promoted the ring-opening polymerization of l-lactide at ambient temperature.

scholarly journals Synthesis of Poly(2-ethyl-2-oxazoline)-b-poly(styrene) Copolymers via a Dual Initiator Route Combining Cationic Ring-Opening Polymerization and Atom Transfer Radical Polymerization

2008 ◽  
Vol 41 (14) ◽  
pp. 5210-5215 ◽  
Author(s):  
C. Remzi Becer ◽  
Renzo M. Paulus ◽  
Stephanie Höppener ◽  
Richard Hoogenboom ◽  
Charles-André Fustin ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Styrene Copolymers ◽  
Cationic Ring Opening Polymerization

Effect of ring size on the cationic ring-opening polymerization of cyclic sulfites

1998 ◽  
Vol 199 (9) ◽  
pp. 1785-1789 ◽  
Author(s):  
Natsuhiro Azuma ◽  
Fumio Sanda ◽  
Toshikazu Takata ◽  
Takeshi Endo
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Ring Size ◽  
Cyclic Sulfites ◽  
Cationic Ring Opening Polymerization

Formation of polyoxazoline-silica nanoparticles via the surface-initiated cationic polymerization of 2-methyl-2-oxazoline

2016 ◽  
Vol 7 (32) ◽  
pp. 5157-5168 ◽  
Author(s):  
G. Bissadi ◽  
R. Weberskirch
Keyword(s):  
Silica Nanoparticles ◽  
Cationic Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Hybrid Nanoparticles ◽  
Cationic Ring Opening Polymerization ◽  
Silica Hybrid

The fabrication of silica hybrid nanoparticles by a surface-initiated cationic ring-opening polymerization of poly(2-methyl-2-oxazoline)s has been described.

Accelerated living cationic ring-opening polymerization of a methyl ester functionalized 2-oxazoline monomer

2015 ◽  
Vol 6 (4) ◽  
pp. 514-518 ◽  
Author(s):  
Petra J. M. Bouten ◽  
Dietmar Hertsen ◽  
Maarten Vergaelen ◽  
Bryn D. Monnery ◽  
Marcel A. Boerman ◽  
...  
Keyword(s):  
Methyl Ester ◽  
Ring Opening ◽  
Kinetic Studies ◽  
Ring Opening Polymerization ◽  
Cationic Ring Opening Polymerization

Kinetic studies on the homo- and copolymerization of 2-methoxycarboxyethyl-2-oxazoline with 2-methyl-2-oxazoline and 2-ethyl-2-oxazoline is discussed.

Cationic ring-opening polymerization of spirophosphorane, 5-phenyl-1,4,6,9-tetraoxa-5-phosphaspiro[4,4]nonane

1981 ◽  
Vol 5 (6) ◽  
Author(s):  
Shiro Kobayashi ◽  
Mureo Kaku ◽  
Takeo Saegusa
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cationic Ring Opening Polymerization
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