The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay

2012 ◽  
Vol 14 (40) ◽  
pp. 13731 ◽  
Author(s):  
Akitaka Ito ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Golden Rule ◽  
Transfer Energy ◽  
State Decay ◽  
Rule Application

scholarly journals Sensitization of ultra-long-range excited-state electron transfer by energy transfer in a polymerized film

2012 ◽  
Vol 109 (38) ◽  
pp. 15132-15135 ◽  
Author(s):  
Akitaka Ito ◽  
David J. Stewart ◽  
Zhen Fang ◽  
M. Kyle Brennaman ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Long Range ◽  
Methyl Viologen ◽  
Polymer Network ◽  
Triplet Energy ◽  
Ligand Charge Transfer ◽  
Triplet Energy Transfer

Distance-dependent energy transfer occurs from the Metal-to-Ligand Charge Transfer (MLCT) excited state to an anthracene-acrylate derivative (Acr-An) incorporated into the polymer network of a semirigid poly(ethyleneglycol)dimethacrylate monolith. Following excitation, to Acr-An triplet energy transfer occurs followed by long-range, Acr-3An—Acr-An → Acr-An—Acr-3An, energy migration. With methyl viologen dication (MV2+) added as a trap, Acr-3An + MV2+ → Acr-An+ + MV+ electron transfer results in sensitized electron transfer quenching over a distance of approximately 90 Å.

Antenna Excited State Decay Kinetics Establish Primary Electron Transfer in Reaction Centers as Heterogeneous†

Biochemistry ◽  
1997 ◽  
Vol 36 (29) ◽  
pp. 8677-8685 ◽  
Author(s):  
Philip D. Laible ◽  
Scott R. Greenfield ◽  
Michael R. Wasielewski ◽  
Deborah K. Hanson ◽  
Robert M. Pearlstein
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Primary Electron ◽  
Reaction Centers ◽  
Decay Kinetics ◽  
State Decay

Competitive Marcus-Type Electron Transfer and Energy Transfer from the Higher Triplet Excited State

2004 ◽  
Vol 108 (50) ◽  
pp. 10941-10948 ◽  
Author(s):  
Masanori Sakamoto ◽  
Xichen Cai ◽  
Michihiro Hara ◽  
Sachiko Tojo ◽  
Mamoru Fujitsuka ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Triplet Excited State

scholarly journals Tuning Excited-State Electron Transfer from an Adiabatic to Nonadiabatic Type in Donor−Bridge−Acceptor Systems and the Associated Energy-Transfer Process

2006 ◽  
Vol 110 (44) ◽  
pp. 12136-12144 ◽  
Author(s):  
Kew-Yu Chen ◽  
Cheng-Chih Hsieh ◽  
Yi-Ming Cheng ◽  
Chin-Hung Lai ◽  
Pi-Tai Chou ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Transfer Process ◽  
Energy Transfer Process ◽  
State Electron

scholarly journals Orthogonally Aligned Cyclic BODIPY Arrays with Long-lived Triplet Excited States as Efficient Heavy-Atom-Free Photosensitizers

2021 ◽  
Author(s):  
Zhaoyang Zhu ◽  
Xue Zhang ◽  
Xing Guo ◽  
Qing-Hua Wu ◽  
Zhongxin Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Excited States ◽  
Heavy Atom ◽  
Triplet Excited State ◽  
Transfer Processes ◽  
Excited State Lifetimes ◽  
Triplet Excited States

Photosensitizers with long triplet excited state lifetimes are key to their efficient electron transfer or energy transfer processes. Herein, we report a novel class of cyclic trimeric BODIPY arrays which...

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