Controlled synthesis of high molecular weight poly(3-hexylthiophene)s via Kumada catalyst transfer polycondensation with Ni(IPr)(acac)2 as the catalyst

2015 ◽  
Vol 51 (11) ◽  
pp. 2138-2140 ◽  
Author(s):  
Xincui Shi ◽  
Aiguo Sui ◽  
Yongxia Wang ◽  
Yuesheng Li ◽  
Yanhou Geng ◽  
...  

Ni(IPr)(acac)2 is a great catalyst for the controlled synthesis of poly(3-hexylthiophene)s with Mns of 9.90–350 kg mol−1via Kumada catalyst transfer polycondensation.


2020 ◽  
Vol 11 (14) ◽  
pp. 2550-2558
Author(s):  
Dražen Pavlović ◽  
Shmuel Cohen

Palladium-catalysed Suzuki polycondensation in conjunction with thermal aromatization of cis- and trans-prepolymer precursors (1a and 1b) has been applied in polyphenylene chemistry, giving access to well-defined high-molecular weight PPP.



2016 ◽  
Vol 5 (3) ◽  
pp. 278-282 ◽  
Author(s):  
Titash Mondal ◽  
Rana Ashkar ◽  
Paul Butler ◽  
Anil K. Bhowmick ◽  
Ramanan Krishnamoorti


2021 ◽  
Author(s):  
Nan Zheng ◽  
Xiahui Li ◽  
Shangwei Huangfu ◽  
Kangkai Xia ◽  
Ruofei Yue ◽  
...  

A linear poly-porphyrin with high Mw and conjugated by PEG and acetazolamide was developed with enhanced singlet oxygen quantum yield, improved photo-toxicity and excellent in vivo photodynamic therapy.



1973 ◽  
Vol 6 (4) ◽  
pp. 498-502 ◽  
Author(s):  
B. G. Carr ◽  
J. F. Harrod ◽  
P. van Gheluwe






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