scholarly journals Surfactant-directed syntheses of mesostructured zinc imidazolates: formation mechanism and structural insights

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 463-470 ◽  
Author(s):  
E. A. Flügel ◽  
M. T. Aronson ◽  
S. C. Junggeburth ◽  
B. F. Chmelka ◽  
B. V. Lotsch

A detailed study on the formation mechanism, local and long-range structures of surfactant-directed lamellar zinc imidazolates is presented.


Cell Research ◽  
2016 ◽  
Vol 26 (9) ◽  
pp. 977-994 ◽  
Author(s):  
Risheng Wei ◽  
Xue Wang ◽  
Yan Zhang ◽  
Saptarshi Mukherjee ◽  
Lei Zhang ◽  
...  


2019 ◽  
Vol 36 (11) ◽  
pp. 1217-1234 ◽  
Author(s):  
Miaomiao Lu ◽  
Xiao Tang ◽  
Zifa Wang ◽  
Lin Wu ◽  
Xueshun Chen ◽  
...  

Abstract Severe haze pollution that occurred in January 2014 in Wuhan was investigated. The factors leading to Wuhan’s PM2.5 pollution and the characteristics and formation mechanism were found to be significantly different from other megacities, like Beijing. Both the growth rates and decline rates of PM2.5 concentrations in Wuhan were lower than those in Beijing, but the monthly PM2.5 value was approximately twice that in Beijing. Furthermore, the sharp increases of PM2.5 concentrations were often accompanied by strong winds. A high-precision modeling system with an online source-tagged method was established to explore the formation mechanism of five haze episodes. The long-range transport of the polluted air masses from the North China Plain (NCP) was the main factor leading to the sharp increases of PM2.5 concentrations in Wuhan, which contributed 53.4% of the monthly PM2.5 concentrations and 38.5% of polluted days. Furthermore, the change in meteorological conditions such as weakened winds and stable weather conditions led to the accumulation of air pollutants in Wuhan after the long-range transport. The contribution from Wuhan and surrounding cities to the PM2.5 concentrations was determined to be 67.4% during this period. Under the complex regional transport of pollutants from surrounding cities, the NCP, East China, and South China, the five episodes resulted in 30 haze days in Wuhan. The findings reveal important roles played by transregional and intercity transport in haze formation in Wuhan.



Molecules ◽  
2020 ◽  
Vol 25 (12) ◽  
pp. 2881 ◽  
Author(s):  
Charles Bou-Nader ◽  
Jinwei Zhang

In comparison with the pervasive use of protein dimers and multimers in all domains of life, functional RNA oligomers have so far rarely been observed in nature. Their diminished occurrence contrasts starkly with the robust intrinsic potential of RNA to multimerize through long-range base-pairing (“kissing”) interactions, self-annealing of palindromic or complementary sequences, and stable tertiary contact motifs, such as the GNRA tetraloop-receptors. To explore the general mechanics of RNA dimerization, we performed a meta-analysis of a collection of exemplary RNA homodimer structures consisting of viral genomic elements, ribozymes, riboswitches, etc., encompassing both functional and fortuitous dimers. Globally, we found that domain-swapped dimers and antiparallel, head-to-tail arrangements are predominant architectural themes. Locally, we observed that the same structural motifs, interfaces and forces that enable tertiary RNA folding also drive their higher-order assemblies. These feature prominently long-range kissing loops, pseudoknots, reciprocal base intercalations and A-minor interactions. We postulate that the scarcity of functional RNA multimers and limited diversity in multimerization motifs may reflect evolutionary constraints imposed by host antiviral immune surveillance and stress sensing. A deepening mechanistic understanding of RNA multimerization is expected to facilitate investigations into RNA and RNP assemblies, condensates, and granules and enable their potential therapeutical targeting.



1981 ◽  
Vol 117 (8) ◽  
pp. 521-522 ◽  
Author(s):  
R. J. Thomsen
Keyword(s):  




1997 ◽  
Vol 92 (6) ◽  
pp. 1039-1050 ◽  
Author(s):  
G. CELEBRE ◽  
G. DE LUCA ◽  
A. FERRARINI
Keyword(s):  


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