In-Situ Ligand Formation-Driven Preparation of a Heterometallic Metal–Organic Framework for Highly Selective Separation of Light Hydrocarbons and Efficient Mercury Adsorption

2016 ◽  
Vol 8 (35) ◽  
pp. 23331-23337 ◽  
Author(s):  
Yi Han ◽  
Hao Zheng ◽  
Kang Liu ◽  
Hongli Wang ◽  
Hongliang Huang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Separation ◽  
Light Hydrocarbons ◽  
Mercury Adsorption ◽  
Metal Organic ◽  
Organic Framework

Chirality from substitution: enantiomer separation via a modified metal–organic framework

2015 ◽  
Vol 3 (23) ◽  
pp. 12145-12148 ◽  
Author(s):  
Jingshu Zhao ◽  
Haiwei Li ◽  
Yuzhen Han ◽  
Rui Li ◽  
Xuesong Ding ◽  
...  
Keyword(s):  
Amino Acids ◽  
Enantiomer Separation ◽  
Metal Organic Framework ◽  
Selective Separation ◽  
Metal Organic ◽  
Organic Framework

A microporous MOF structure, d-his–ZIF-8, with a chiral environment was synthesized via ligand in situ substitution (LIS), which shows exceptional selective separation capability for racemic amino acids.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)

2021 ◽  
Vol 316 ◽  
pp. 110957
Author(s):  
Mian Zahid Hussain ◽  
Mounib Bahri ◽  
Werner R. Heinz ◽  
Quanli Jia ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Metal Organic Framework ◽  
In Situ Investigation ◽  
Metal Organic ◽  
Organic Framework

In Situ Growth of Metal–Organic Framework Thin Films with Gas Sensing and Molecule Storage Properties

Langmuir ◽  
2013 ◽  
Vol 29 (27) ◽  
pp. 8657-8664 ◽  
Author(s):  
Wei-Jin Li ◽  
Shui-Ying Gao ◽  
Tian-Fu Liu ◽  
Li-Wei Han ◽  
Zu-Jin Lin ◽  
...  
Keyword(s):  
Thin Films ◽  
Gas Sensing ◽  
Metal Organic Framework ◽  
In Situ Growth ◽  
Metal Organic ◽  
Storage Properties ◽  
Organic Framework

In-situ one-step deposition of highly dispersed palladium nanoparticles into zirconium metal–organic framework for selective hydrogenation of furfural

2021 ◽  
Vol 514 ◽  
pp. 111859
Author(s):  
Samaneh Sohrabi ◽  
Reza Khaleghi Abasabadi ◽  
Abbas Ali Khodadadi ◽  
Yadollah Mortazavi ◽  
Ali Hoseinzadeh
Keyword(s):  
Selective Hydrogenation ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Highly Dispersed ◽  
Metal Organic ◽  
One Step ◽  
Zirconium Metal ◽  
Organic Framework

scholarly journals Mechanically Strong, Liquid-Resistant Photothermal Bioplastic Constructed from Cellulose and Metal-Organic Framework for Light-Driven Mechanical Motion

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4449
Author(s):  
Lijian Sun ◽  
Limei Li ◽  
Xianhui An ◽  
Xueren Qian
Keyword(s):  
Prussian Blue ◽  
Thermoelectric Generator ◽  
Metal Organic Framework ◽  
In Situ Synthesis ◽  
High Light ◽  
Hot Press ◽  
Mechanical Motion ◽  
Metal Organic ◽  
Organic Framework

The development of photothermal materials with a high light-to-heat conversion capability is essential for the utilization of clean solar energy. In this work, we demonstrate the use of a novel and sustainable concept involving cellulose liquefaction, rapid gelation, in situ synthesis and hot-press drying to convert cellulose and metal–organic framework (Prussian blue) into a stable photothermal bioplastic that can harvest sunlight and convert it into mechanical motion. As expected, the obtained Prussian blue@cellulose bioplastic (PCBP) can effectively absorb sunlight and the surface can be heated up to 70.3 °C under one sun irradiation (100 mW cm−2). As a demonstration of the practicality of PCBP, it was successfully used to drive a Stirling engine motion. Meanwhile, hot-pressing promotes the densification of the structure of PCBP and, therefore, improves the resistance to the penetration of water/non-aqueous liquids. Moreover, PCBP shows good mechanical properties and thermal stability. Given the excellent photothermal performance and environmentally friendly features of photothermal conversion bioplastic, we envisage this sustainable plastic film could play important roles toward diversified applications: a photothermal layer for thermoelectric generator, agricultural films for soil mulching and photothermal antibacterial activity, among others.

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