scholarly journals Excitation of higher levels of singly charged copper ions in argon and neon glow discharges

2014 ◽  
Vol 29 (12) ◽  
pp. 2256-2261 ◽  
Author(s):  
Zdeněk Weiss ◽  
Edward B. M. Steers ◽  
Juliet C. Pickering ◽  
Volker Hoffmann ◽  
Sohail Mushtaq

Transition rate diagrams of copper ions in argon and neon glow discharges are presented, using data from Cu ii emission spectra.

The electrical and optical characteristics of the overstressed nanosecond discharge in nitrogen at a pressure of 202 kPa, which was ignited between electrodes from chalcopyrite (CuInSe2 ), are presented. Upon sputtering of chalcopyrite electrodes, CuInSe2 compound vapors have been introduced into the discharge plasma. Chalcopyrite molecules were partially destroyed in the plasma and partially deposited in the form of thin films on a quartz substrate, which was placed near the system of discharge electrodes. The main decomposition products of a chalcopyrite molecule in an overstressed nanosecond discharge were found, which were in excited and ionized states and which, in the plasma emission spectra, were mainly represented by atoms and singly charged copper and indium ions. The spectral lines of copper and indium are proposed, which can be used to control the deposition of thin films of chalcopyrite in real time. On quartz substrates, gas-discharge method was used to synthesize thin films based on the CuInSe2 compound, which effectively absorbed light in a wide spectral range (200-800 nm), which opens up prospects for their use in photovoltaic devices.


2020 ◽  
Vol 21 (4) ◽  
pp. 669-679
Author(s):  
A.K. Shuaibov ◽  
A.I. Minya ◽  
R.V. Grytsak ◽  
A.A. Malinina ◽  
I.V. Shevera ◽  
...  

The characteristics of an overstressed bipolar discharge with a duration of 100-150 ns in argon and air, which was ignited between copper electrodes in argon, and also between an aluminum electrode and a chalcopyrite (CuInSe2) electrode in air, are presented. In the process of microexplosions of inhomogeneities on the working surfaces of the electrodes in a strong electric field, the vapor of copper, aluminum, and vapor of ternary chalcopyrite are introduced into the interelectrode gap. This creates the prerequisites for the synthesis of thin copper films and the synthesis of films based on quaternary chalcopyrite - CuAlInSe2, which can be deposited on a quartz plate installed near the center of the discharge gap. The optical characteristics of the plasma, as well as voltage pulses across the discharge gap of d = 1–2 mm, current pulses, and pulsed energy contributions to the discharge, have been investigated using emission spectroscopy with a high time resolution. The plasma emission spectra were thoroughly studied, which made it possible to establish the main decay products of the chalcopyrite molecule and the energy states of atoms and singly charged ions of aluminum, copper, and indium, which are formed in the discharge.


RSC Advances ◽  
2019 ◽  
Vol 9 (53) ◽  
pp. 30917-30924 ◽  
Author(s):  
Xiaoyan Liu ◽  
Nan Ding ◽  
Jun Wang ◽  
Honglan Chen ◽  
Xinwei Chen ◽  
...  

A novel solid-based up-conversion FRET sensor is convenient for the direct detection of Cu2+ based on color change and emission spectra.


2009 ◽  
Vol 6 (2) ◽  
pp. 101-107 ◽  
Author(s):  
Roberto K. Yamamoto ◽  
Mário R. Gongora-Rubio ◽  
Rodrigo S. Pessoa ◽  
Márcio R. Cunha ◽  
Homero S. Maciel

An issue of paramount importance for the fabrication of microplasma devices is internal structure flatness. To overcome this problem we devised a fabrication method using LTCC (Low Temperature Cofired Ceramic) and LTTT (Low Temperature Transfer Tape) technologies. The flexibility resulting from mixing these technologies could enable fabrication of certain microfluidic applications. In the present work, the fabrication of a microplasma generator using a mixed LTCC and LTTT technology is presented. Silver-palladium electrodes were screen printed on the green tapes and were cofired after machining of microchannels and other structures. Two electrode plates were obtained separately in this way using a setter powder sheet to ensure flatness. In the postfire process, transfer tapes were used to bind the two electrode plates and the electrode spacer together to make the final device structure. Uniform and stable glow discharges were obtained in argon, nitrogen, oxygen, and sulfur hexafluoride gases. Paschen's curves, V-I characteristics, and optical emission spectra were obtained in DC discharges. The fabrication method presented has been demonstrated to be very reproducible and produced very flat electrodes.


2015 ◽  
Vol 33 (2) ◽  
pp. 193-200 ◽  
Author(s):  
A. Bartnik ◽  
H. Fiedorowicz ◽  
T. Fok ◽  
R. Jarocki ◽  
M. Szczurek ◽  
...  

AbstractIn this work, two laser-produced plasma (LPP) sources – extreme ultraviolet (EUV) and a LPP soft X-ray (SXR) source were used to create Ne photoionized plasmas. A radiation beam was focused onto a gas stream, injected into a vacuum chamber synchronously with the radiation pulse. EUV radiation spanned a wide spectral range with pronounced maximum centered at λ≈11 nm, while in case of the SXR source spectral maximum was at λ≈1.4 nm. Emission spectra of photoionized plasmas created this way were measured in a wide spectral range λ = 10–100 nm. The dominating spectral lines originated from singly charged ions (Ne II) and neutral atoms (Ne I). For the highest radiation fluence, spectral lines originating from Ne III and even Ne IV species were detected. Differences between the experimental spectra, obtained for all irradiation conditions, were analyzed. They were attributed either to different fluence or spectral distribution of driving photons.


2008 ◽  
Vol 23 (9) ◽  
pp. 1223 ◽  
Author(s):  
Petr Šmíd ◽  
Edward Steers ◽  
Zdeněk Weiss ◽  
Juliet Pickering ◽  
Volker Hoffmann

2014 ◽  
Vol 29 (11) ◽  
pp. 2078-2090 ◽  
Author(s):  
Zdeněk Weiss ◽  
Edward B. M. Steers ◽  
Juliet C. Pickering ◽  
Sohail Mushtaq

Excitation and ionization processes of iron ions in argon-, neon- and argon–hydrogen glow discharges are described based on transition rate diagrams.


2000 ◽  
Vol 179 ◽  
pp. 193-196
Author(s):  
V. I. Makarov ◽  
A. G. Tlatov

AbstractA possible scenario of polar magnetic field reversal of the Sun during the Maunder Minimum (1645–1715) is discussed using data of magnetic field reversals of the Sun for 1880–1991 and the14Ccontent variations in the bi-annual rings of the pine-trees in 1600–1730 yrs.


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