Preparation of Fe/activated carbon directly from rice husk pyrolytic carbon and its application in catalytic hydroxylation of phenol

RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 4984-4992 ◽  
Author(s):  
Xian Zhang ◽  
Yaxin Li ◽  
Guiying Li ◽  
Changwei Hu

The loading of iron and the formation of activated carbon were combined to one step and the thus-obtained Fe/activated carbon showed good catalytic performance for phenol hydroxylation.

2013 ◽  
Vol 662 ◽  
pp. 202-206
Author(s):  
Jia Feng Wu ◽  
Yu Mei Zhao ◽  
Peng Liang

A series of nano-sized iron oxide supported on 3D wormlike hierarchical mesoporous SiO2 catalysts were synthesized by one-step hydrothermal synthesis. The samples were characterized by XRD, N2 sorption, FT-IR, UV–Vis, TEM and ICP-AES. The catalysts were probed for the oxidation of phenol employing hydrogen peroxide. The results indicate that the materials exhibit high surface area and 3D wormlike hierarchical pore, iron ions exist as isolated framework species when the weight percentage content of iron is below 0.24 and nano-size iron oxide is dispersed in the surface (iron content above 0.24 wt%). Catalytic performance indicates that nano-size iron oxide supported on SiO2 is useful to enhance both the catalytic activity and the selectivity of target products compared with isolated iron species.


2015 ◽  
Vol 5 (4) ◽  
pp. 2486-2495 ◽  
Author(s):  
Ruiguang Yang ◽  
Guiying Li ◽  
Changwei Hu

Loading of Fe3+ and Fe2+ on wood-based activated carbon obtained Fe-based catalyst with good catalytic performance for phenol hydroxylation.


2011 ◽  
Vol 354 (2) ◽  
pp. 686-690 ◽  
Author(s):  
Shaoan Song ◽  
Wei Zhao ◽  
Lina Wang ◽  
Jinglong Chu ◽  
Jinkui Qu ◽  
...  

2021 ◽  
Vol 1034 (1) ◽  
pp. 012075
Author(s):  
Purnami ◽  
ING. Wardana ◽  
Sudjito ◽  
Denny Widhiyanuriyawan ◽  
Nurkholis Hamidi

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1259
Author(s):  
Ana Franco ◽  
Rafael Luque ◽  
Carolina Carrillo-Carrión

Biomass-derived materials are put forward as eco-friendly alternatives to design heterogeneous catalysts. To contribute in this field, we explored the potential of mesoporous biogenic silica (RH-Silica) obtained from lignocellulosic waste, in particular from rice husk, as an inorganic support to prepare heterogenized iron oxide-based catalysts. Mechanochemistry, considered as a green and sustainable technique, was employed to synthetize iron oxide nanoparticles in pure hematite phase onto the biosilica (α-Fe2O3/RH-Silica), making this material a good candidate to perform catalyzed organic reactions. The obtained material was characterized by different techniques, and its catalytic activity was tested in the selective oxidation of styrene under microwave irradiation. α-Fe2O3/RH-Silica displayed a good catalytic performance, achieving a conversion of 45% under optimized conditions, and more importantly, with a total selectivity to benzaldehyde. Furthermore, a good reusability was achieved without decreasing its activity after multiple catalytic cycles. This work represents a good example of using sustainable approaches and green materials as alternatives to conventional methods in the production of high-added value products.


1998 ◽  
Vol 15 (5) ◽  
pp. 505-509
Author(s):  
Tian-Cun Xiao ◽  
Hai-Tao Wang ◽  
Yu-Li Lu ◽  
Li-Dun An ◽  
Hong-Li Wang

RSC Advances ◽  
2015 ◽  
Vol 5 (41) ◽  
pp. 32626-32636 ◽  
Author(s):  
Yaxin Li ◽  
Xian Zhang ◽  
Ruiguang Yang ◽  
Guiying Li ◽  
Changwei Hu
Keyword(s):  

H3PO4promoted the decomposition of some species to form CO2and reacted with PBTRHR to form PH3.


Sign in / Sign up

Export Citation Format

Share Document