Chloride Induced Corrosion and Carbonation in 3D Printed Concrete

The durability of reinforced concrete structures is dependent on the ability of the concrete cover to combat the ingress of chlorides and carbon dioxide in marine and urban environments. In recent years, interest in additive manufacturing), specifically referring to extrusion based three-dimensional concrete printing (3DCP), has been growing in the construction industry. Despite this being a promising technology that can save construction time, costs and resources, certain issues regarding the lack of fusion between subsequent printed layers have been brought to light. Research has shown that the lack of fusion at the interlayer regions can act as ingress pathways for corrosion contaminants, such as carbon dioxide and chloride aqueous solution, that can cause deterioration. This study investigates the interlayer bond strength (flexural strength) and durability performance of 3D printed concrete subjected to pass times between 0 and 30 min and compares the results to reference cast concrete of the same concrete mixture. The durability study includes Durability Index testing (oxygen permeability, water sorptivity and chloride conductivity index), accelerated concrete carbonation and chloride-induced corrosion. The results show that the cast samples outperform printed samples, yielding greater flexural strength and durability properties, and emphasize the importance of improving the 3DCP interfacial bond. Cast samples are shown to have randomly distributed, compact voids compared to the interconnected and elongated pores located at the interlayer regions of printed samples. In addition, printed samples yield lower interlayer bond strength and durability properties with an increase in pass time, which is attributed to surface moisture evaporation as well as the thixotropic behaviour of the concrete mixture. Good relationships between the mechanical strength and durability performance are also presented.

Analysis of Shear Stress and Rutting Performance of Semirigid Base Asphalt Pavement on Steep Longitudinal Slope

Rutting is the most common distress of the asphalt pavement with a semirigid base, mainly when located on a steep longitudinal slope. Previous studies have shown that shear stress is the leading cause of rutting. Therefore, it is essential to analyze the distribution characteristics of shear stress to evaluate pavement rutting performance. Firstly, the truck speed was measured at different locations on the steep longitudinal slope section. Then, the calculation method of shear stress was improved based on the method of “systematic clustering.” The distribution characteristics of shear stress were studied under the different gradients, slope lengths, horizontal forces, and interlayer bond conditions. Finally, the rutting prediction model was used to evaluate the rutting performance of the steep longitudinal slope section. The results show two critical parameters of a steep longitudinal slope: gradient and slope length can be quantified by establishing the relationship between truck speed and those parameters. The improved shear stress calculation method can correspond well with the layer where maximum rutting occurs. Gradients and slope lengths have little effect on shear stresses, while horizontal forces and interlayer bond conditions significantly change the shear stress distribution characteristics within the pavement. For the steep longitudinal slope sections, the rutting prediction model should consider the truck speed separately. With increasing gradient and slope length, the rutting increases the fastest in the middle layer. For sections with horizontal forces and poor interlayer bonding, the layers with the highest rutting accumulation are the upper layer and the lower layer, respectively.

Comparison of Properties of 3D-Printed Mortar in Air vs. Underwater

Research and technological advancements in 3D concrete printing (3DCP) have led to the idea of applying it to offshore construction. The effect of gravity is reduced underwater, which can have a positive effect on 3DCP. For basic verification of this idea, this study printed and additively manufactured specimens with the same mortar mixture in air and underwater and evaluated properties in the fresh state and the hardened state. The mechanical properties were evaluated using the specimens produced by direct casting to the mold and specimens produced by extracting from the additive part through coring and cutting. The results of the experiment show that underwater 3D printing required a greater amount of printing output than in-air 3D printing for a good print quality, and buildability was improved underwater compared to that in air. In the case of the specimen layered underwater, the density and compressive strength decreased compared to the specimen layered in air. Because there are almost no effects of moisture evaporation and bleeding in water, the interlayer bond strength of the specimen printed underwater was somewhat larger than that printed in air, while there was no effect of the deposition time interval underwater.

The Extent of Interlayer Bond Strength during Fused Filament Fabrication of Nylon Copolymers: An Interplay between Thermal History and Crystalline Morphology

One of the main drawbacks of Fused Filament Fabrication is the often-inadequate mechanical performance of printed parts due to a lack of sufficient interlayer bonding between successively deposited layers. The phenomenon of interlayer bonding becomes especially complex for semi-crystalline polymers, as, besides the extremely non-isothermal temperature history experienced by the extruded layers, the ongoing crystallization process will greatly complicate its analysis. This work attempts to elucidate a possible relation between the degree of crystallinity attained during printing by mimicking the experienced thermal history with Fast Scanning Chip Calorimetry, the extent of interlayer bonding by performing trouser tear fracture tests on printed specimens, and the resulting crystalline morphology at the weld interface through visualization with polarized light microscopy. Different printing conditions are defined, which all vary in terms of processing parameters or feedstock molecular weight. The concept of an equivalent isothermal weld time is utilized to validate whether an amorphous healing theory is capable of explaining the observed trends in weld strength. Interlayer bond strength was found to be positively impacted by an increased liquefier temperature and reduced feedstock molecular weight as predicted by the weld time. An increase in liquefier temperature of 40 °C brings about a tear energy value that is three to four times higher. The print speed was found to have a negligible effect. An elevated build plate temperature will lead to an increased degree of crystallinity, generally resulting in about a 1.5 times larger crystalline fraction compared to when printing occurs at a lower build plate temperature, as well as larger spherulites attained during printing, as it allows crystallization to occur at higher temperatures. Due to slower crystal growth, a lower tie chain density in the amorphous interlamellar regions is believed to be created, which will negatively impact interlayer bond strength.

A Concise Review on Interlayer Bond Strength in 3D Concrete Printing

Interlayer bond strength is one of the key aspects of 3D concrete printing. It is a well-established fact that, similar to other 3D printing process material designs, process parameters and printing environment can significantly affect the bond strength between layers of 3D printed concrete. The first section of this review paper highlights the importance of bond strength, which can affect the mechanical and durability properties of 3D printed structures. The next section summarizes all the testing and bond strength measurement methods adopted in the literature, including mechanical and microstructure characterization. Finally, the last two sections focus on the influence of critical parameters on bond strength and different strategies employed in the literature for improving the strength via strengthening mechanical interlocking in the layers and tailoring surface as well as interface reactions. This concise review work will provide a holistic perspective on the current state of the art of interlayer bond strength in 3D concrete printing process.