Nanogold supported on manganese oxide doped alumina microspheres as a highly active and selective catalyst for CO oxidation in a H2-rich stream

2015 ◽  
Vol 51 (100) ◽  
pp. 17728-17731 ◽  
Author(s):  
Yu-Xin Miao ◽  
Wen-Cui Li ◽  
Qiang Sun ◽  
Lei Shi ◽  
Lei He ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Manganese Oxide ◽  
High Catalytic Activity ◽  
Selective Catalyst ◽  
Support Interaction ◽  
Highly Active

The exceptionally high catalytic activity for CO-PROX reaction is due to the Au–support interaction and the unique reducibility of the support.

scholarly journals CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Active Sites ◽  
Bond Activation ◽  
Dissociative Adsorption ◽  
High Catalytic Activity ◽  
Good Catalytic Activity ◽  
Pretreatment Conditions ◽  
Oxidation Efficiency

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2

2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
High Catalytic Activity

Towards highly active heterogeneous catalysts via a sequential noncovalent bonding strategy

2021 ◽  
Author(s):  
Ruixue Wang ◽  
Ying Yue ◽  
Huiying Wei ◽  
Jinxin Guo ◽  
Yanzhao Yang
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalysts ◽  
High Catalytic Activity ◽  
Synthetic Route ◽  
Surface Ligands ◽  
Highly Active ◽  
Noncovalent Bonding ◽  
Excellent Stability

Here, a novel synthetic route of ceria-based nanocatalysts with high catalytic activity and excellent stability was constructed by utilizing function groups from surface ligands. The surface of ceria nanorods were...

Synthesis and characterization of new isostructural series LnFe0.5Sb1.5O6 (Ln = La-Sm) exhibiting high catalytic activity in CO oxidation

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Synthesis And Characterization ◽  
High Catalytic Activity

High catalytic activity for CO oxidation on single Fe atom stabilized in graphene vacancies

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
High Catalytic Activity ◽  
First Principles Method

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.

Pt NPs immobilized on a N-doped graphene@Al2O3 hybrid support as robust catalysts for low temperature CO oxidation

2018 ◽  
Vol 54 (79) ◽  
pp. 11168-11171 ◽  
Author(s):  
Zhimin Jia ◽  
Fei Huang ◽  
Jiangyong Diao ◽  
Jiayun Zhang ◽  
Jia Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Co Oxidation ◽  
Platinum Nanoparticles ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Low Temperature Co Oxidation ◽  
Doped Graphene ◽  
Strong Metal Support Interaction

Platinum nanoparticles (Pt NPs) immobilized on a N-doped graphene@Al2O3 hybrid support (Al2O3@CNx) were synthesized and exhibit superior catalytic activity for low temperature CO oxidation, due to a strong metal–support interaction between Pt NPs and the N-doped.

Active phase of highly active Co3O4 catalyst for synthetic natural gas production

RSC Advances ◽  
2014 ◽  
Vol 4 (100) ◽  
pp. 57185-57191 ◽  
Author(s):  
Baowei Wang ◽  
Sihan Liu ◽  
Zongyuan Hu ◽  
Zhenhua Li ◽  
Xinbin Ma
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Natural Gas ◽  
Active Phase ◽  
Gas Production ◽  
High Catalytic Activity ◽  
Co Methanation ◽  
Synthetic Natural Gas ◽  
Highly Active ◽  
Catalytic Stability

Co3O4 nanoparticles showed high catalytic activity for low temperature CO methanation. CoO is the active phase of the catalyst. Pre-reduction treatment can improve catalytic stability.

Preparation of TiO2-supported twinned gold nanoparticles by CO treatment and their CO oxidation activity

2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Au Nanoparticles ◽  
High Catalytic Activity ◽  
Oxidation Activity

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.

A Composite Formation Route to Well-Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate-Alumina Nanocomposites

2011 ◽  
Vol 21 (12) ◽  
pp. 2301-2310 ◽  
Author(s):  
Tae Woo Kim ◽  
Hana Yoo ◽  
In Young Kim ◽  
Hyung-Wook Ha ◽  
Ah Reum Han ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Manganese Oxide ◽  
High Catalytic Activity ◽  
Composite Formation
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