The effect of Si/Al ratio on the catalytic performance of hierarchical porous ZSM-5 for catalyzing benzene alkylation with methanol

2016 ◽  
Vol 6 (8) ◽  
pp. 2647-2652 ◽  
Author(s):  
Hualei Hu ◽  
Jinghui Lyu ◽  
Jiayao Rui ◽  
Jie Cen ◽  
Qunfeng Zhang ◽  
...  

High suppression of ethylbenzene formation could be successfully achieved by adjusting the Si/Al ratio of hierarchical porous ZSM-5.

2017 ◽  
Vol 28 (2) ◽  
pp. 482-486 ◽  
Author(s):  
Jing-Hui Lyu ◽  
Hua-Lei Hu ◽  
Jia-Yao Rui ◽  
Qun-Feng Zhang ◽  
Jie Cen ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63044-63049 ◽  
Author(s):  
Hualei Hu ◽  
Jinghui Lyu ◽  
Jie Cen ◽  
Qunfeng Zhang ◽  
Qingtao Wang ◽  
...  

The dual modification catalyst (MgO and Pd) could effectively combine the effect of MgO for suppressing the side reaction of methanol to olefins and the effect of Pd for inhibiting the formation of ethylbenzene and coke.


RSC Advances ◽  
2016 ◽  
Vol 6 (99) ◽  
pp. 97399-97403 ◽  
Author(s):  
Rui Kuang ◽  
Luyi Zheng ◽  
Ethan Cottrill ◽  
Ning Pan ◽  
Yanhui Chi ◽  
...  

A hierarchical porous MOF nanocrystal, hpCuL (L = 2,4,6-tris(3,5-dicarboxylatephenylamino)-1,3,5-triazine) was prepared via a facile gel-aging process. This nanocomposite exhibits high catalytic activity and stability for the reduction of 4-nitrophenol.


2019 ◽  
Vol 38 (6) ◽  
pp. 640-648 ◽  
Author(s):  
Athena Papadopoulou ◽  
Dimitra Zarafeta ◽  
Anastasia P. Galanopoulou ◽  
Haralambos Stamatis

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1098
Author(s):  
Ling Xu ◽  
Fan Wang ◽  
Zhi Xiu ◽  
Limei Duan ◽  
Zongrui Liu ◽  
...  

Hierarchical aluminum-silicon materials have been successfully prepared by mixing pre-crystallization of silica-alumina sol and citric acid under hydrothermal conditions. The influence of pre-crystallization time on the micro-mesoporous structure is studied using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), N2 physical adsorption, and high-resolution transmission electron microscopy (HRTEM). The catalytic performance of hierarchical silica-alumina material is evaluated by alkylation of phenol with tert-butanol. The results show that the silica-alumina materials with a pre-crystallization time of 16 h show micro-mesoporous structure and excellent catalytic activity.


ChemCatChem ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2415-2422 ◽  
Author(s):  
Fengwei Zhang ◽  
Zhihong Li ◽  
Chunlan Ma ◽  
Xu Han ◽  
Xue Dong ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 693 ◽  
Author(s):  
Jie Cen ◽  
Ning Zhang ◽  
Hualei Hu ◽  
Nan Yao ◽  
Zhengjia Li ◽  
...  

The major challenge in the production of xylene from benzene alkylation with methanol is to avoid the side reaction of methanol with olefins, and this leads to the low utilization efficiency of methanol and the generation of byproduct ethylbenzene. Hierarchical porous Ti-ZSM-5 with appropriate acidity was achieved by substituting part of Al by Ti in the synthesis process, which exhibited the high utilization efficiency of methanol and high suppression of the ethylbenzene formation by the efficient suppression of methanol to olefins.


2022 ◽  
Author(s):  
Baohe Wang ◽  
Yuan Zhu ◽  
Huanhuan Han ◽  
Qiaoyun Qin ◽  
Zhaobang Zhang ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Fei Xie ◽  
Mengyu Gan ◽  
Li Ma

Fabrication of hierarchical porous catalysts with large specific surface area and tunable architecture provides an effective strategy to promote the catalytic performance of Pt-based catalysts. Herein, we design and construct...


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