scholarly journals Neutral N-donor ligand based flexible metal–organic frameworks

2016 ◽  
Vol 45 (10) ◽  
pp. 4060-4072 ◽  
Author(s):  
Biplab Manna ◽  
Aamod V. Desai ◽  
Sujit K. Ghosh
Keyword(s):  
Metal Organic Frameworks ◽  
Short Review ◽  
Donor Ligands ◽  
Donor Ligand ◽  
Metal Organic ◽  
Flexible Metal ◽  
Structural Aspects

This short review focuses on the flexibility aspect of MOFs based on neutral N-donor ligands with representative examples concerning the structural aspects and the subsequent properties induced by the reorganization of the frameworks.

ChemInform Abstract: Neutral N-Donor Ligand Based Flexible Metal-Organic Frameworks

ChemInform ◽  
2016 ◽  
Vol 47 (16) ◽  
Author(s):  
Biplab Manna ◽  
Aamod V. Desai ◽  
Sujit K. Ghosh
Keyword(s):  
Metal Organic Frameworks ◽  
Donor Ligand ◽  
Metal Organic ◽  
Flexible Metal

scholarly journals Highly sensitive detection of nitrobenzene by a series of fluorescent 2D zinc(ii) metal–organic frameworks with a flexible triangular ligand

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 23975-23984
Author(s):  
Xue Yang ◽  
Yixia Ren ◽  
Hongmei Chai ◽  
Xiufang Hou ◽  
Zhixiang Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
High Sensitivity ◽  
Fluorescent Sensors ◽  
Sensitive Detection ◽  
Donor Ligands ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

Four fluorescent 2D Zn-MOFs based on a flexible triangular ligand and linear N-donor ligands are hydrothermally prepared and used to detect nitrobenzene in aqueous solution with high sensitivity, demonstrating their potential as fluorescent sensors.

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

Intermediate states approach for adsorption studies in flexible metal–organic frameworks

2019 ◽  
Vol 21 (6) ◽  
pp. 3294-3303 ◽  
Author(s):  
Justyna Rogacka ◽  
Filip Formalik ◽  
Azahara L. Triguero ◽  
Lucyna Firlej ◽  
Bogdan Kuchta ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
P Adsorption ◽  
Adsorption Studies ◽  
Intermediate States ◽  
Metal Organic ◽  
Flexible Metal

Adsorption studies in flexible metal–organic frameworks are challenging and time-consuming.

scholarly journals Temperature dependence of adsorption hysteresis in flexible metal organic frameworks

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Shamsur Rahman ◽  
Arash Arami-Niya ◽  
Xiaoxian Yang ◽  
Gongkui Xiao ◽  
Gang (Kevin) Li ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Capillary Condensation ◽  
Metal Organic Frameworks ◽  
Sorption Isotherms ◽  
Separation Performance ◽  
Process Simulations ◽  
Metal Organic ◽  
Flexible Metal ◽  
Pressure Swing ◽  
External Stimuli

Abstract“Breathing” and “gating” are striking phenomena exhibited by flexible metal-organic frameworks (MOFs) in which their pore structures transform upon external stimuli. These effects are often associated with eminent steps and hysteresis in sorption isotherms. Despite significant mechanistic studies, the accurate description of stepped isotherms and hysteresis remains a barrier to the promised applications of flexible MOFs in molecular sieving, storage and sensing. Here, we investigate the temperature dependence of structural transformations in three flexible MOFs and present a new isotherm model to consistently analyse the transition pressures and step widths. The transition pressure reduces exponentially with decreasing temperature as does the degree of hysteresis (c.f. capillary condensation). The MOF structural transition enthalpies range from +6 to +31 kJ·mol−1 revealing that the adsorption-triggered transition is entropically driven. Pressure swing adsorption process simulations based on flexible MOFs that utilise the model reveal how isotherm hysteresis can affect separation performance.

scholarly journals Amino Acid Residues Determine the Response of Flexible Metal–Organic Frameworks to Guests

2020 ◽  
Vol 142 (35) ◽  
pp. 14903-14913 ◽  
Author(s):  
Yong Yan ◽  
Elliot J. Carrington ◽  
Rémi Pétuya ◽  
George F. S. Whitehead ◽  
Ajay Verma ◽  
...  
Keyword(s):  
Amino Acid ◽  
Metal Organic Frameworks ◽  
Amino Acid Residues ◽  
Metal Organic ◽  
Flexible Metal
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