Magnetic behavior of the metal organic framework [(CH3)2NH2]Co(HCOO)3

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37818-37822 ◽  
Author(s):  
K. Vinod ◽  
C. S. Deepak ◽  
Shilpam Sharma ◽  
D. Sornadurai ◽  
A. T. Satya ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Phase Transitions ◽  
Specific Heat ◽  
Single Crystals ◽  
Metal Organic Framework ◽  
Magnetic Behavior ◽  
Metal Organic ◽  
Organic Framework

In this study we examine the phase transitions in single crystals of [(CH3)2NH2]Co(HCOO)3, using magnetization and specific heat measurements as a function of temperature and magnetic field.

scholarly journals Millimeter-Scale Zn(3-ptz)2 Metal–Organic Framework Single Crystals: Self-Assembly Mechanism and Growth Kinetics

ACS Omega ◽  
2021 ◽  
Author(s):  
Juan M. Garcia-Garfido ◽  
Javier Enríquez ◽  
Ignacio Chi-Durán ◽  
Iván Jara ◽  
Leonardo Vivas ◽  
...  
Keyword(s):  
Single Crystals ◽  
Growth Kinetics ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Assembly Mechanism ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

2018 ◽  
Vol 19 (1) ◽  
pp. 506-512 ◽  
Author(s):  
Sylvia L. Hanna ◽  
Xuan Zhang ◽  
Ken-ichi Otake ◽  
Riki J. Drout ◽  
Peng Li ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

Ordered Macro–Microporous Metal–Organic Framework Single Crystals and Their Derivatives for Rechargeable Aluminum-Ion Batteries

2019 ◽  
Vol 141 (37) ◽  
pp. 14764-14771 ◽  
Author(s):  
Hu Hong ◽  
Jinlong Liu ◽  
Huawen Huang ◽  
Christian Atangana Etogo ◽  
Xianfeng Yang ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Organic Framework ◽  
Aluminum Ion ◽  
Metal Organic ◽  
Organic Framework

Ordered macro-microporous metal-organic framework single crystals

Science ◽  
2018 ◽  
Vol 359 (6372) ◽  
pp. 206-210 ◽  
Author(s):  
Kui Shen ◽  
Lei Zhang ◽  
Xiaodong Chen ◽  
Lingmei Liu ◽  
Daliang Zhang ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Single Crystalline ◽  
Metal Organic ◽  
Crystalline Nature ◽  
Opening Up ◽  
Diffusion Properties ◽  
Organic Framework

We constructed highly oriented and ordered macropores within metal-organic framework (MOF) single crystals, opening up the area of three-dimensional–ordered macro-microporous materials (that is, materials containing both macro- and micropores) in single-crystalline form. Our methodology relies on the strong shaping effects of a polystyrene nanosphere monolith template and a double-solvent–induced heterogeneous nucleation approach. This process synergistically enabled the in situ growth of MOFs within ordered voids, rendering a single crystal with oriented and ordered macro-microporous structure. The improved mass diffusion properties of such hierarchical frameworks, together with their robust single-crystalline nature, endow them with superior catalytic activity and recyclability for bulky-molecule reactions, as compared with conventional, polycrystalline hollow, and disordered macroporous ZIF-8.

Metal-Organic Framework Single Crystals as Photoactive Matrices for the Generation of Metallic Microstructures

2011 ◽  
Vol 23 (15) ◽  
pp. 1788-1791 ◽  
Author(s):  
Rob Ameloot ◽  
Maarten B. J. Roeffaers ◽  
Gert De Cremer ◽  
Frederik Vermoortele ◽  
Johan Hofkens ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework ◽  
Metallic Microstructures

An N,N′-diethylformamide solvent-induced conversion cascade within a metal–organic framework single crystal

2020 ◽  
Vol 56 (44) ◽  
pp. 5877-5880
Author(s):  
Jing Chen ◽  
Meng-Yao Chao ◽  
Yan Liu ◽  
Bo-Wei Xu ◽  
Wen-Hua Zhang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

A two-dimensional metal–organic framework undergoes four-step single-crystal to single-crystals conversions, including a three-step DEF-induced cascade conversion to shuttle back to its original connectivity.

Hierarchically Ordered Macro–Microporous Polyoxometalate-Based Metal–Organic Framework Single Crystals

ACS Nano ◽  
2021 ◽  
Author(s):  
Zhong Zhang ◽  
Yiwei Liu ◽  
Hongrui Tian ◽  
Xujiao Ma ◽  
Qian Yue ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Probing Time Dependent Phase Transformation in a Flexible Metal-Organic Framework with Nanoindentation

2021 ◽  
Author(s):  
Prakash Kanoo ◽  
Manish Kumar Mishra ◽  
Arpan Hazra
Keyword(s):  
Phase Transformation ◽  
Phase Transitions ◽  
Room Temperature ◽  
Metal Organic Framework ◽  
Time Dependent ◽  
Guest Molecules ◽  
Nanoindentation Technique ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Phase transformation in a flexible metal-organic framework, {[Zn4(1,4-NDC)4(1,2-BPE)2]•xSolvent}n, which loses guest molecules rapidly at room temperature, leading to several phase transitions, is examined using nanoindentation technique. Nanoindentation results reveal time...

scholarly journals Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields

RSC Advances ◽  
2018 ◽  
Vol 8 (25) ◽  
pp. 13675-13678 ◽  
Author(s):  
Lin Hu ◽  
Zhe Wang ◽  
Hui Wang ◽  
Zhe Qu ◽  
Qianwang Chen
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
High Magnetic Field ◽  
Metal Organic Framework ◽  
High Magnetic Fields ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework

High magnetic field-induced synthesis has been demonstrated to tune the structure and properties of the multiferroic metal–organic framework [(CH3)2NH2][Mn(HCOO)3].

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