Mechanical and thermal properties of microcrystalline cellulose-reinforced soy protein isolate–gelatin eco-friendly films

RSC Advances ◽  
2015 ◽  
Vol 5 (70) ◽  
pp. 56518-56525 ◽  
Author(s):  
Chenchen Li ◽  
Jing Luo ◽  
Zhiyong Qin ◽  
Hui Chen ◽  
Qiang Gao ◽  
...  

SPI–gelatin films reinforced by MCC with hydrogen bond and interpenetrating network perform better mechanical and thermal properties.

Author(s):  
Kuang Li ◽  
Shicun Jin ◽  
Hui Chen ◽  
Jing He ◽  
Jianzhang Li

Soy protein isolate (SPI) based materials are abundant, biocompatible, renewable, and biodegradable. In order to improve the tensile strength (TS) of SPI films, we prepared a novel composite film modified with microcrystalline cellulose (MCC) and metal nanoclusters (NCs) in this research. The effects of the modification of MCC on the properties of SPI-Cu NCs and Zn NCs films were investigated. Attenuated total reflectance-Fourier transformed infrared spectroscopy analyses and X-ray diffraction patterns characterized the strong interactions and reduction of the crystalline structure of the composite films. Scanning electron microscope showed the enhanced cross-linked and entangled structure of modified films. Compared with untreated SPI film, the tensile strength of the SPI-MCC-Cu and SPI-MCC-Zn films increased from 2.91 MPa to 13.95 and 6.52 MPa, respectively. Moreover, the results also indicated their favorable water resistance with higher water contact angle. Meanwhile, the composite films exhibited increased initial degradation temperatures, demonstrating their higher thermostability. The results suggested that MCC could effectively improve the performance of SPI-NCs films, which would provide a novel preparation method for environmentally friendly SPI-based films in the applications of packaging materials.


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