Precisely designed perylene bisimide-substituted polyethylene with a high glass transition temperature and an ordered architecture

RSC Advances ◽  
2015 ◽  
Vol 5 (84) ◽  
pp. 68765-68772 ◽  
Author(s):  
Wei Song ◽  
Jianhua Wu ◽  
Guangda Yang ◽  
Huijing Han ◽  
Meiran Xie ◽  
...  

A polyethylene with a precise repeat of perylene bisimide branches was synthesized by acyclic diene metathesis polymerization and hydrogenation of the as-synthesized polymer, and displayed good thermal stability and an ordered architecture.

2006 ◽  
Vol 937 ◽  
Author(s):  
Jiang Yu ◽  
Weijian Xu ◽  
Zhenghua Zhang ◽  
Yu Ni ◽  
Yanbing Lu ◽  
...  

ABSTRACTA novel σ-conjugated hyperbranched polysilane is presented, and it has good solubility in common organic solvents. The photoluminescence (PL) emission spectrum of it exhibits an emission maximum at 425nm, which indicates that the polymer emits blue light. The resulting polymer also has good thermal stability and high glass transition temperature. Therefore, it demonstrates a promising application in blue light emitting diodes.


2022 ◽  
Author(s):  
Francis Owusu ◽  
Martin Tress ◽  
Frank A. Nüesch ◽  
Sandro Lehner ◽  
Dorina M. Opris

Polar polynorbornenes prepared by ring-opening metathesis polymerization show thermally switchable dielectric permittivity. The polymers exhibit a large dielectric relaxation strength and high glass transition temperature.


2019 ◽  
Vol 10 (24) ◽  
pp. 3334-3341 ◽  
Author(s):  
Parijat Ray ◽  
Timothy Hughes ◽  
Craig Smith ◽  
Mena Hibbert ◽  
Kei Saito ◽  
...  

A bio-based methacrylic polymer derived from a green solvent, Cyrene™ through a green synthesis pathway with very high glass transition temperature, thermal stability and high reactivity.


2015 ◽  
Vol 3 (8) ◽  
pp. 1794-1798 ◽  
Author(s):  
Yao-Hsien Chung ◽  
Lei Sheng ◽  
Xing Xing ◽  
Lingling Zheng ◽  
Mengying Bian ◽  
...  

A chrysene derivative, BPCC (6,12-bis(9-phenyl-9H-carbazol-3-yl)chrysene), possessing high thermal stability with a high glass transition temperature (Tg = 181 °C) was synthesized.


RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 105038-105046 ◽  
Author(s):  
Jianbo Wang ◽  
Jianghuai Hu ◽  
Ke Zeng ◽  
Gang Yang

The in situ reaction of a hydroxy group with a phthalonitrile system was carried out in a one-pot reaction and the prepared polymers showed outstanding thermal stability, a high modulus and a high glass transition temperature.


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