Ultrahigh hydrogen storage capacity of novel porous aromatic frameworks

2015 ◽  
Vol 3 (20) ◽  
pp. 10724-10729 ◽  
Author(s):  
Xuanjun Wu ◽  
Rui Wang ◽  
Hongjun Yang ◽  
Wenxuan Wang ◽  
Weiquan Cai ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Free Volume ◽  
Room Temperature ◽  
Storage Capacity ◽  
Volume Ratio ◽  
Hydrogen Uptake ◽  
Low Density ◽  
Hydrogen Storage Capacity ◽  
Gcmc Simulation ◽  
Porous Aromatic Frameworks

We proposed four novel PAF materials with extremely low density and unprecedented high free volume ratio, which were predicted to possess ultrahigh gravimetric hydrogen uptake reaching the DOE 2015 gravimetric targets at room temperature based on GCMC simulation calculations.

Pressure Isotherms of Hydrogen Adsorption in Carbon Nanostructures

2001 ◽  
Vol 706 ◽  
Author(s):  
Xiaohong Chen ◽  
Urszula Dettlaff-Weglikowska ◽  
Miroslav Haluska ◽  
Martin Hulman ◽  
Siegmar Roth ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Activated Carbon ◽  
Hydrogen Storage ◽  
Carbon Nanostructures ◽  
Room Temperature ◽  
Storage Capacity ◽  
Hydrogen Adsorption ◽  
Single Wall Carbon Nanotubes ◽  
Hydrogen Storage Capacity ◽  
Carbon And Graphite

AbstractThe hydrogen adsorption capacity of various carbon nanostructures including single-wall carbon nanotubes, graphitic nanofibers, activated carbon, and graphite has been measured as a function of pressure and temperature. Our results show that at room temperature and a pressure of 80 bar the hydrogen storage capacity is less than 1 wt.% for all samples. Upon cooling, the capacity of hydrogen adsorption increases with decreasing temperature and the highest value was observed to be 2.9 wt. % at 50 bar and 77 K. The correlation between hydrogen storage capacity and specific surface area is discussed.

Influence of hydrogen spillover on Pt-decorated carbon nanocones for enhancing hydrogen storage capacity: A DFT mechanistic study

2018 ◽  
Vol 20 (32) ◽  
pp. 21194-21203 ◽  
Author(s):  
Nuttapon Yodsin ◽  
Chompoonut Rungnim ◽  
Vinich Promarak ◽  
Supawadee Namuangruk ◽  
Nawee Kungwan ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Hydrogen Storage ◽  
Active Site ◽  
Storage Capacity ◽  
Hydrogen Adsorption ◽  
Hydrogen Uptake ◽  
Mechanistic Study ◽  
Hydrogen Storage Capacity ◽  
Carbon Nanocones ◽  
Hydrogen Migration

The hydrogen adsorption on platinum (Pt)-decorated carbon nanocenes (CNCs) are investigated by DFT calculations. The Pt is an active site for hydrogen adsorption while curvature of CNC enhances hydrogen uptake via hydrogen migration/diffusion on the C–C surface.

Enhanced room-temperature hydrogen storage capacity in Pt-loaded graphene oxide/HKUST-1 composites

2014 ◽  
Vol 39 (5) ◽  
pp. 2160-2167 ◽  
Author(s):  
Hu Zhou ◽  
Xiaoqing Liu ◽  
Jun Zhang ◽  
Xiufen Yan ◽  
Yuanjun Liu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Hydrogen Storage ◽  
Room Temperature ◽  
Storage Capacity ◽  
Hydrogen Storage Capacity

scholarly journals Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity

2016 ◽  
Vol 52 (50) ◽  
pp. 7826-7829 ◽  
Author(s):  
Ayesha Naeem ◽  
Valeska P. Ting ◽  
Ulrich Hintermair ◽  
Mi Tian ◽  
Richard Telford ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
High Selectivity ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Hydrogen Uptake ◽  
Hydrogen Storage Capacity ◽  
High Hydrogen ◽  
Metal Organic ◽  
Adsorption Of Co

New zirconium based metal–organic framework (UBMOF-31) synthesised using mixed-linker strategy showing permanent porosity, excellent hydrogen uptake, and high selectivity for adsorption of CO2 over N2.

Hydrogen Storage in Carbon Nanotubes Prepared by Using Copper Nanoparticles as Catalyst

2012 ◽  
Vol 251 ◽  
pp. 342-345 ◽  
Author(s):  
Jin Chen ◽  
Xiao Gang Wang ◽  
Hai Yan Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Hydrogen Storage ◽  
Copper Nanoparticles ◽  
Room Temperature ◽  
Storage Capacity ◽  
Dissociative Adsorption ◽  
Electrochemical System ◽  
Hydrogen Storage Capacity ◽  
Structure Phase ◽  
Fundamental Understanding

carbon nanotubes were synthesized by pyroysis method using copper nanoparticles as catalyst. The structure, phase composition and hydrogen storage capacity were investigated by TEM, XRD spectra and Electrochemical System. The results show that the diameter of carbon nanotubes is 200-500nm, The P-C-T curve of adsorbing hydrogen of samples was measured in the pressure up to 12 MPa at room temperature. we show that a SWNT can strongly adsorb up to 8-wt% hydrogen. These results advance our fundamental understanding of dissociative adsorption of hydrogen in nanostructures and suggest new routes to better storage and catalyst materials.

Doping activated carbon incorporated composite MIL-101 using lithium: impact on hydrogen uptake

2015 ◽  
Vol 3 (13) ◽  
pp. 7014-7021 ◽  
Author(s):  
Prasanth Karikkethu Prabhakaran ◽  
Johnny Deschamps
Keyword(s):  
Activated Carbon ◽  
Hydrogen Storage ◽  
Storage Capacity ◽  
Lithium Ion ◽  
Hydrogen Uptake ◽  
Hydrogen Storage Capacity ◽  
Ion Doping

Enhancement of hydrogen storage capacity in composite MIL-101 by lithium ion doping.

The Capacity Enhancement of Room Temperature Hydrogen Storage in HiPco SWNT by Electrochemical deposition of Palladium Nanoparticles

2006 ◽  
Vol 927 ◽  
Author(s):  
Yong-Won Lee ◽  
Ranadeep Bhowmick ◽  
Bruce M. Clemens
Keyword(s):  
Hydrogen Storage ◽  
Palladium Nanoparticles ◽  
Hydrogen Pressure ◽  
Room Temperature ◽  
Storage Capacity ◽  
Hydrogen Uptake ◽  
Capacity Enhancement ◽  
Fe Catalyst ◽  
Co Conversion ◽  
Sample Chamber

ABSTRACTA Sieverts apparatus for small quantity samples has been implemented by employing a very small volume pressure reservoir and a sample chamber of less than 1 ml. The hydrogen storage capacity of a commercially available, HiPco (high pressure CO conversion) single-wall carbon nanotube (SWNT) was measured over a hydrogen pressure range of 0-35 Bar at room temperature. The sample contained approximately 5 wt% of residual Fe catalyst, and showed 0.17 wt% of hydrogen uptake capacity at 30 Bar of hydrogen pressure. Palladium nanoparticles were deposited on the SWNT via electrochemical method (EC) from H2PdCl4 solution. The storage capacity of the SWNT with EC-doped Pd was increased to 0.52 wt% at 30 Bar, which corresponds to the capacity enhancement by a factor between 2.8 and 3.1.

Easy synthesis of highly nitrogen-enriched graphitic carbon with a high hydrogen storage capacity at room temperature

Carbon ◽  
2009 ◽  
Vol 47 (6) ◽  
pp. 1585-1591 ◽  
Author(s):  
Seung Jae Yang ◽  
Jung Hyun Cho ◽  
Gyu Hwan Oh ◽  
Kee Suk Nahm ◽  
Chong Rae Park
Keyword(s):  
Hydrogen Storage ◽  
Room Temperature ◽  
Storage Capacity ◽  
Graphitic Carbon ◽  
Hydrogen Storage Capacity ◽  
High Hydrogen
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