scholarly journals In situ monitoring of additives during CO2 gas hydrate formation

2016 ◽  
Vol 8 (30) ◽  
pp. 5897-5905 ◽  
Author(s):  
M. Schwenk ◽  
A. Katzir ◽  
B. Mizaikoff

The combination of pressure/temperature traces with in situ mid-infrared fiberoptic evanescent field spectroscopy as advanced sensing concept for CO2 gas hydrate analysis.

The Analyst ◽  
2017 ◽  
Vol 142 (5) ◽  
pp. 740-744 ◽  
Author(s):  
M. Schwenk ◽  
A. Katzir ◽  
B. Mizaikoff

Mid-infrared fiber-optic evanescent field spectroscopy (MIR-FEFS) has been applied as an in situ monitoring technique for THF containing clathrate hydrates.


ChemInform ◽  
2011 ◽  
Vol 42 (28) ◽  
pp. no-no
Author(s):  
Bettina Beeskow-Strauch ◽  
Judith M. Schicks ◽  
Erik Spangenberg ◽  
Joerg Erzinger

Fuel ◽  
2016 ◽  
Vol 185 ◽  
pp. 517-523 ◽  
Author(s):  
Ngoc N. Nguyen ◽  
Anh V. Nguyen ◽  
Khoi T. Nguyen ◽  
Llew Rintoul ◽  
Liem X. Dang

2011 ◽  
Vol 8 (3) ◽  
pp. 4529-4558 ◽  
Author(s):  
K. Heeschen ◽  
M. Haeckel ◽  
I. Klaucke ◽  
M. K. Ivanov ◽  
G. Bohrmann

Abstract. In the eastern Black Sea, we determined methane (CH4) concentrations, gas hydrate volumes and their vertical distribution from combined gas and chloride (Cl−) measurements within pressurized sediment cores. The total gas volume collected from the cores corresponds to concentrations of 1.2–1.4 mol of methane per kg porewater at in-situ pressure, which is equivalent to a gas hydrate saturation of 15–18% of pore volume and amongst the highest values detected in shallow seep sediments. At the central seep site, a high-resolution Cl− profile resolves the upper gas hydrate stability boundary and a continuous layer of hydrates in a sediment column of 120 cm thickness. Including this information, a more precise gas hydrate saturation of 22–24% pore volume can be calculated. This is higher in comparison to a saturation calculated from the Cl− profile alone, resulting in 14.4%. The likely explanation is an active gas hydrate formation from CH4 gas ebullition. The hydrocarbons at Batumi Seep are of shallow biogenic origin (CH4 > 99.6%), at Pechori Mound they originate from deeper thermocatalytic processes as indicated by the lower ratios of C1 to C2–C3 and the presence of C5.


2004 ◽  
Vol 2004 (0) ◽  
pp. 183-184
Author(s):  
Hajime Endou ◽  
Akiko Hirano ◽  
Masayuki Seko ◽  
Masahiro Ota

2004 ◽  
Vol 37 (8) ◽  
pp. 611-616 ◽  
Author(s):  
Masoud Ghandehari ◽  
Cristian S Vimer

1998 ◽  
Vol 12 (1) ◽  
pp. 183-188 ◽  
Author(s):  
Peter G. Brewer ◽  
Franklin M. Orr, ◽  
Gernot Friederich ◽  
Keith A. Kvenvolden ◽  
Daniel L. Orange

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