scholarly journals Metal ‘turn-off’, anion ‘turn-on’ gelation cascade in pyridinylmethyl ureas

2017 ◽  
Vol 53 (12) ◽  
pp. 2024-2027 ◽  
Author(s):  
Caroline A. Offiler ◽  
Christopher D. Jones ◽  
Jonathan W. Steed

Pyridinylmethyl urea gels are weakened or destroyed by addition of transition metal ions but gelation is recovered by adding bromide giving rise to a gel–sol–gel chemically triggered cascade.

1997 ◽  
Vol 72-74 ◽  
pp. 417-418 ◽  
Author(s):  
Markus Herren ◽  
Kenji Yamanaka ◽  
Naoya Miyazaki ◽  
Makoto Morita

2011 ◽  
Vol 233-235 ◽  
pp. 2219-2222 ◽  
Author(s):  
Xue Chun Zhong ◽  
Zhan Chang Pan ◽  
Zhi Gang Wei ◽  
Shu Guang Xie ◽  
Zhen Jun Cheng ◽  
...  

In this paper, TiO2crystallines doped with transition metal ions have been prepared by sol-gel method. The UV-visible spectra indicated that the doping with transition metal ions (especially Cu2+, Mn2+and Cr3+ions) could effectively improve the absorption of TiO2crystals in the visible-light range. The XRD results showed that the doping does not affect the anatase phase of TiO2. The band structure and the UV-vis absorption spectrum of Mn2+ions doped-TiO2were also calculated by DFT (density function theory) method, which indicated that the doping with transition metal ion could make the band gap of TiO2smaller and a red shift in optical absorption.


Talanta ◽  
2009 ◽  
Vol 78 (3) ◽  
pp. 903-909 ◽  
Author(s):  
Bishnu Prasad Joshi ◽  
Junwon Park ◽  
Wan In Lee ◽  
Keun- Hyeung Lee

RSC Advances ◽  
2014 ◽  
Vol 4 (64) ◽  
pp. 33955 ◽  
Author(s):  
Pradip Kr. Dutta ◽  
Snigdha Panda ◽  
Debangshu Chaudhuri ◽  
Sanjio S. Zade

RSC Advances ◽  
2015 ◽  
Vol 5 (126) ◽  
pp. 104299-104313 ◽  
Author(s):  
Arpan Kool ◽  
Pradip Thakur ◽  
Biswajoy Bagchi ◽  
Nur Amin Hoque ◽  
Somtirtha Banerjee ◽  
...  

Mechanical, dielectric and photoluminescence properties of transition-metal ions doped mullite nanocomposite synthesized via alkoxide hydrolysis.


2012 ◽  
Vol 61 (3) ◽  
pp. 600-612 ◽  
Author(s):  
Alexandra Wittmar ◽  
Matthias Wittmar ◽  
Alfred Ulrich ◽  
Hinka Caparrotti ◽  
Michael Veith

2014 ◽  
Vol 2014 ◽  
pp. 1-4 ◽  
Author(s):  
K. S. Siddhapara ◽  
D. V. Shah

Transition metal (Mn, Fe, Co,) doped TiO2nanoparticles were synthesized by the sol-gel method. All the prepared samples were calcined at different temperatures like 200°C to 800°C and characterized by X-ray diffraction (XRD) and energy dispersive X-ray (EDX) analysis. The studies revealed that transition metal (TM) doped nanoparticles have smaller crystalline size and higher surface area than pure TiO2. Dopant ions in the TiO2structure caused significant absorption shift into the visible region. The results of photodegradation of formaldehyde in aqueous medium under UV light showed that photocatalytic activity of TiO2nanoparticles was significantly enhanced by the presence of some transition metal ions. Chemical oxygen demand (COD) of formaldehyde solutions done at regular intervals gave a good idea about mineralization of formaldehyde.


2012 ◽  
Vol 10 (13) ◽  
pp. 2542 ◽  
Author(s):  
Karimulla Mulla ◽  
Prateek Dongare ◽  
David W. Thompson ◽  
Yuming Zhao

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