scholarly journals Photocatalytic reduction of CO2 and H2O to CO and H2 with a cobalt chlorin complex adsorbed on multi-walled carbon nanotubes

2016 ◽  
Vol 6 (12) ◽  
pp. 4077-4080 ◽  
Author(s):  
Shoko Aoi ◽  
Kentaro Mase ◽  
Kei Ohkubo ◽  
Shunichi Fukuzumi

The photocatalytic reduction of CO2 and H2O with triethylamine occurred using a cobalt(ii) chlorin complex adsorbed on multi-walled carbon nanotubes as a catalyst to yield CO and H2 with a high turnover number of 710.

2015 ◽  
Vol 6 (1) ◽  
pp. 666-674 ◽  
Author(s):  
Kei Ohkubo ◽  
Naoki Kohno ◽  
Yusuke Yamada ◽  
Shunichi Fukuzumi

Metal-free photocatalytic hydrogen evolution occurred efficiently in benzene containing SWCNTs under laser irradiation with an extremely high turnover number of 2 000 000 and a high quantum yield of 130%.


2015 ◽  
Vol 51 (50) ◽  
pp. 10226-10228 ◽  
Author(s):  
Shoko Aoi ◽  
Kentaro Mase ◽  
Kei Ohkubo ◽  
Shunichi Fukuzumi

Selective electrocatalytic reduction of CO2 to CO occurred efficiently using a glassy carbon electrode modified with a cobalt(ii) chlorin complex adsorbed on multi-walled carbon nanotubes in water.


Acta Naturae ◽  
2011 ◽  
Vol 3 (1) ◽  
pp. 99-106 ◽  
Author(s):  
E A Smirnova ◽  
A A Gusev ◽  
O N Zaitseva ◽  
E M Lazareva ◽  
G E Onishchenko ◽  
...  

2003 ◽  
Vol 772 ◽  
Author(s):  
T. Seeger ◽  
G. de la Fuente ◽  
W.K. Maser ◽  
A.M. Benito ◽  
A. Righi ◽  
...  

AbstractCarbon nanotubes (CNT) are interesting candidates for the reinforcement in robust composites and for conducting fillers in polymers due to their fascinating electronic and mechanical properties. For the first time, we report the incorporation of multi walled carbon nanotubes (MWNTs) into silica-glass surfaces by means of partial surface-melting caused by a continuous wave Nd:YAG laser. MWNTs were detected being well incorporated in the silica-surface. The composites are characterized using scanning electron microscopy (SEM) and Raman-spectroscopy. A model for the composite-formation is proposed based on heatabsorption by MWNTs and a partial melting of the silica-surface.


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