Direct optical observations of vesicular self-assembly in large-scale polymeric structures during photocontrolled biphasic polymerization

2016 ◽  
Vol 7 (47) ◽  
pp. 7211-7215 ◽  
Author(s):  
Jan K. Szymański ◽  
Juan Pérez-Mercader

In this report, we employ a photo-controlled polymerization protocol featuring a fluorescent initiator to follow the evolution of the generated self-assembled microscopic structures in a phase-separating dispersion polymerization medium.

2017 ◽  
Vol 1 (6) ◽  
pp. 1200-1206 ◽  
Author(s):  
Jiemei Zhou ◽  
Chunyan Hong ◽  
Caiyuan Pan

A visible light mediated reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization of benzyl methacrylate (BzMA) is conducted in ethanol using poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) as a macro-chain transfer agent (macro-CTA), affording polymeric nanomaterials with various morphologies.


2019 ◽  
Vol 7 (27) ◽  
pp. 8471-8476 ◽  
Author(s):  
Yongqiang Ji ◽  
Minqiang Wang ◽  
Zhi Yang ◽  
Shangdong Ji ◽  
Hengwei Qiu

Ordered and self-assembled nanocrystal superstructures have attracted intense attention due to their ability to transfer unique nanoscale properties to large scale.


RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72519-72524 ◽  
Author(s):  
Yingjuan Sun ◽  
Hongyan Li ◽  
Yuan Lin ◽  
Li Niu ◽  
Qian Wang

P3HT was self-assembled into large-scale conductive stripe patterns based on confined evaporative self-assembly. These conductive stripe patterns could induce cell alignment and provide spatial electric signals to modulate cellular behaviors.


2012 ◽  
Vol 2012 ◽  
pp. 1-5
Author(s):  
Szymon Jasiecki ◽  
Jarosław Serafińczuk ◽  
Teodor Gotszalk ◽  
Grzegorz Schroeder

The self-assembly technique has been applied for the fabrication of thin films including macrocyclic molecules. These multilayered structures, grown by sequential deposition of oppositely charged molecules, were characterised with X-ray reflectometry. The data obtained indicate regular thickness of ion pair layers formed regardless of the number of depositions made as well as the number of ion groups occurring in the molecule. Savitzky-Golay algorithm was used for the calculation of the layer thickness. Formation of self-assembled multilayers (SAMs) occurs not only for polymeric structures but also for small ionic compound systems and results from the electrostatic interaction of many strongly dissipated charges on the whole structure of the molecule.


2014 ◽  
Vol 50 (61) ◽  
pp. 8306-8308 ◽  
Author(s):  
Xuejin Li ◽  
Yu-Hang Tang ◽  
Haojun Liang ◽  
George Em Karniadakis

GPU-accelerated dissipative particle dynamics has been explored to probe the self-assembly of amphiphilic molecules in a soft confined environment.


MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.


2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.


2021 ◽  
Vol 11 (7) ◽  
pp. 3254
Author(s):  
Marco Pisco ◽  
Francesco Galeotti

The realization of advanced optical fiber probes demands the integration of materials and structures on optical fibers with micro- and nanoscale definition. Although researchers often choose complex nanofabrication tools to implement their designs, the migration from proof-of-principle devices to mass production lab-on-fiber devices requires the development of sustainable and reliable technology for cost-effective production. To make it possible, continuous efforts are devoted to applying bottom-up nanofabrication based on self-assembly to decorate the optical fiber with highly ordered photonic structures. The main challenges still pertain to “order” attainment and the limited number of implementable geometries. In this review, we try to shed light on the importance of self-assembled ordered patterns for lab-on-fiber technology. After a brief presentation of the light manipulation possibilities concerned with ordered structures, and of the new prospects offered by aperiodically ordered structures, we briefly recall how the bottom-up approach can be applied to create ordered patterns on the optical fiber. Then, we present un-attempted methodologies, which can enlarge the set of achievable structures, and can potentially improve the yielding rate in finely ordered self-assembled optical fiber probes by eliminating undesired defects and increasing the order by post-processing treatments. Finally, we discuss the available tools to quantify the degree of order in the obtained photonic structures, by suggesting the use of key performance figures of merit in order to systematically evaluate to what extent the pattern is really “ordered”. We hope such a collection of articles and discussion herein could inspire new directions and hint at best practices to fully exploit the benefits inherent to self-organization phenomena leading to ordered systems.


Author(s):  
Zhengting Zhang ◽  
Guiyun Yi ◽  
Xiaodong Wang ◽  
Peng Li ◽  
Zhuoyan Wan ◽  
...  

2009 ◽  
Vol 143 ◽  
pp. 345 ◽  
Author(s):  
Aurelie M. Brizard ◽  
Marc C. A. Stuart ◽  
Jan H. van Esch

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