Self-healing protective coatings of polyvinyl butyral/polypyrrole-carbon black composite on carbon steel

RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43237-43249 ◽  
Author(s):  
Thanapoon Niratiwongkorn ◽  
Gisha Elizabeth Luckachan ◽  
Vikas Mittal

The self-healing nature of polyvinyl butyral (PVB) based organic coatings incorporated with a conducting pigment polypyrrole-carbon black (PPyCB) composite is discussed.

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2754 ◽  
Author(s):  
P ◽  
Al-Maadeed

The use of self-healing coatings to protect metal substrates, such as aluminum alloys, stainless steel, carbon steel, and Mg alloys from corrosion is an important aspect for protecting metals and for the economy. During the past decade, extensive transformations on self-healing strategies were introduced in protective coatings, including the use of green components. Scientists used extracts of henna leaves, aloe vera, tobacco, etc. as corrosion inhibitors, and cellulose nanofibers, hallyosite nanotubes, etc. as healing agent containers. This review gives a concise description on the need for self-healing protective coatings for metal parts, the latest extrinsic self-healing strategies, and the techniques used to follow-up the self-healing process to control the corrosion of metal substrates. Common techniques, such as accelerated salt immersion test and electrochemical impedance spectroscopy (EIS), for evaluating the self-healing process in protective coatings are explained. We also show recent advancements procedures, such as scanning vibrating electrode technique (SVET) and scanning electrochemical microscopy (SECM), as successful techniques in evaluating the self-healing process in protective coatings.


2021 ◽  
Vol 2129 (1) ◽  
pp. 012008
Author(s):  
J Alias ◽  
N A Johari ◽  
A Zanurin ◽  
N A Alang ◽  
M Z M Zain

Abstract The ability to self-heal is an important feature for the long-term durability of protective coatings on metal alloys. Microcapsules in the self-healing coating allowed for automatic recovery of any damages or cracks, extending the life of the coating. In this study, self-healing microcapsules containing linseed oil as the core material and polyurea-formaldehyde (PUF) as the shell material were manufactured to epoxy resin matrix. Coatings were applied to a bare magnesium (Mg) substrate and scratched to test the self-healing ability. Optical and scanning electron microscopy (SEM) were used to characterize the microcapsules formed by varied stirring rates of 300 and 800 rpm. By using potentiodynamic polarization in a 3.5 wt.% NaCl solution, the corrosion rate of embedded microcapsules and coatings on Mg was evaluated, and the corrosion rate was studied using the Tafel plot. As a consequence, the epoxy coating containing linseed oil and urea formaldehyde, stirred at 800 rpm, significantly resists corrosion attack on the magnesium sheet, with decreased corrosion current density, icorr (1.552 μA/cm2) as compared to the bare magnesium sheet (109.8 μA/cm2). During the microcapsule preparation, increasing the stirring rate from 300 to 800 rpm reduces the icorr value by roughly half. As a result, the self-healing coatings demonstrated adequate self-healing and corrosion resistance recovery on magnesium alloys.


AIP Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 075018
Author(s):  
Xi Wang ◽  
Hao Qiao ◽  
Ziwei Zhang ◽  
Shiying Tang ◽  
Shengjun Liu ◽  
...  

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