2,4-Diamino-5-(phenylthio)-5H-chromeno [2,3-b] pyridine-3-carbonitriles as green and effective corrosion inhibitors: gravimetric, electrochemical, surface morphology and theoretical studies

RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 53933-53948 ◽  
Author(s):  
Chandrabhan Verma ◽  
Lukman O. Olasunkanmi ◽  
I. B. Obot ◽  
Eno E. Ebenso ◽  
M. A. Quraishi

The inhibition of mild steel corrosion in 1 M HCl by three newly synthesized 2,4-diamino-5-(phenylthio)-5H-chromeno[2,3-b]pyridine-3-carbonitriles was studied using the weight loss method, electrochemical techniques, surface morphology studies and theoretical methods.

RSC Advances ◽  
2019 ◽  
Vol 9 (70) ◽  
pp. 40997-41009 ◽  
Author(s):  
Dongyi Li ◽  
Panpan Zhang ◽  
Xinyu Guo ◽  
Xiaowei Zhao ◽  
Ying Xu

The inhibitory effect of radish leaf extract (RLE) on mild steel corrosion in 0.5 M H2SO4 was studied by the weight loss method and the electrochemical method.


RSC Advances ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 4499-4511 ◽  
Author(s):  
Ifzan Arshad ◽  
Aamer Saeed ◽  
Pervaiz Ali Channar ◽  
Syeda Aaliya Shehzadi ◽  
Muhammad Naeem Ahmed ◽  
...  

The inhibitory effect of three new bis-Schiff bases on mild steel corrosion in 0.5 M HCl was studied by the weight loss method and the electrochemical method.


RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15639-15654 ◽  
Author(s):  
Chandrabhan Verma ◽  
L. O. Olasunkanmi ◽  
I. B. Obot ◽  
Eno E. Ebenso ◽  
M. A. Quraishi

The inhibition of mild steel corrosion in 1 M HCl by four 5-arylpyrimido-[4,5-b]-quinoline-diones has been investigated using weight loss, electrochemical, surface, and quantum chemical calculations and molecular dynamics simulation methods.


Author(s):  
Buraq T Sh AL-Mosawi ◽  
Mohammed M Sabri ◽  
Muhanad A Ahmed

Abstract In chemical manufactures, the corrosion inhibitors were added in order to reduce the corrosion of mild steel. Chemical molecules are often used on mild steel surfaces as portion of the latest finishing steps before painting and/or storage. Here, this work elucidated the utilization of an isatin derivative, namely, 3-((3-acetylphenyl)imino)indolin-2-one synergistic with zinc oxide nanoparticles for improving the impedance of mild steel (MS) against corrosion in 1.0 M hydrochloric acid using the weight loss method and scanning electron microscopy (SEM). Weight loss measurements demonstrated that the best 3-((3-acetylphenyl)imino)indolin-2-one concentration was 0.5 mM and the inhibition efficiency was 83% whereas the inhibition efficiency was 92% with addition of ZnO NPs. 3-((3-Acetylphenyl)imino)indolin-2-one retards the corrosion process at 300 K and demonstrates low inhibition efficiencies at 310, 320 and 330 K.


2014 ◽  
Vol 507 ◽  
pp. 245-248
Author(s):  
Yi Jiang ◽  
Chao Yi Zheng ◽  
Jun Zhe Liu

In this paper, the anticorrosive effects of two types of corrosion inhibitors (anodic inhibitors and cathodic inhibitors) on rebars immersed in the simulated concrete pore solution with 3.5%( wt) NaCl were studied by the static weight loss method . The results are as following: firstly, all of the inhibitors had an anticorrosive effect on the rebars and sodium nitrite performed best. Besides, the higher the concentration, the more obvious effect .Secondly, diethanolamine had the best performance in the cathodic inhibitors. Thirdly, sodium nitrite had a good coordination effect with diethanolamine instead of being used alone. In this way, it can exist synergy and reduce the activity of cathode and anode by the formation of consecutively protective film on the surface of the rebars.


2014 ◽  
Vol 670-671 ◽  
pp. 37-40 ◽  
Author(s):  
Shi Dong Wang ◽  
Qiang Wang ◽  
Jing Li ◽  
Shu Liang Zang

This paper uses a metal hung weight loss method, acidic ionic liquid desulfurizer as the media, by adding different inhibitor (Polyethylene Glycol, SDBS, Functional ionic liquids), contrast to carbon steel corrosion in the absence of inhibitor, understanding of their respective inhibition effect. In the experiment, the carbon steel material, different kinds and concentrations of the inhibitor in the medium, the corrosion rate measured by weight loss method. Contrast to the blank experiment the inhibition rate can be calculated. The experiment proved that the inhibition effect of several inhibitor at room temperature, and calculate their respective optimal concentration. The experiment also investigated the compound of several corrosion inhibition synergies, confirm the good corrosion inhibiting effect of polyethylene Glycol and SDBS complex, the inhibition rate reached 69.2%.Excellent inhibition effect of the ionic liquid corrosion inhibitor and the inhibition rate reached 88.3%, showing a clear advantage.


CORROSION ◽  
1959 ◽  
Vol 15 (6) ◽  
pp. 37-40
Author(s):  
DONALD W. SHANNON ◽  
JAMES E. BOGGS

Abstract A new method is proposed as a standard screening test for possible hydrogen sulfide corrosion inhibitors. This is a dynamic, weight-loss method which attempts to control conditions sufficiently well that substances which offer promise of being effective inhibitors under field conditions can be selected for further study. The test is cheap and simple, so that it can be run economically by a relatively untrained technician on large numbers of materials. The method is described and the reasons for choosing the particular conditions are explained. Then illustrations of the application of the procedure to a number of types of inhibiting substances are presented. 2.3.4


2012 ◽  
Vol 13 (2) ◽  
pp. 118
Author(s):  
Maria Erna ◽  
Emriadi Emriadi ◽  
Admin Alif ◽  
Syukri Arief

This research is intended to learn inhibition efficiency of mild steel corrosion in peat water using two type ofchitosan. First chitosan is without treatment and the second one is synthesized by ionotropic gelation method andthen is characterized by Fourier transform Infrared spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM).Diameter of chitosan porous is about 500 nm which is measured based on morphological photo using SEM withinhomogeneous porous shape and porous distribution is unsmooth . Effect of chitin and chitosan on the corrosionof mild steel in peat water is studied using weight loss method. It is found that corrosion inhibition efficiencydepends on peat water pH, inhibition technique and interaction time. The results show that inhibition efficiency ofchitosan without treatment and with treatment are 88.73% and 93.32% respectively. The inhibition is assumed tooccur via physicsorption of the chitin and chitosan molecules on the metal surface. The Langmuir adsorptionisotherm is tested for their fit to the experimental data.


2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Nisreen Faraj ◽  
Kareima A. Abdelghani ◽  
A.A. Idress ◽  
Dalal. M. Ibrahim

The chemical technique was used to investigate the inhibition and adsorption properties of L-proline for steel corrosion (weight loss method). As the concentration of L-proline increased, the inhibition efficiency increased, but decreased as the temperature increased, according to the findings. The inhibitor’s adsorption to the steel surface has been shown to be random, involving both electrostatic and chemisorptions. The Temkin adsorption isotherm governs the adsorption of L-proline to the steel surface. Thermodynamic parameters have been determined in some cases.


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