Tuning charge transport from unipolar (n-type) to ambipolar in bis(naphthalene diimide) derivatives by introducing π-conjugated heterocyclic bridging moieties

2016 ◽  
Vol 4 (30) ◽  
pp. 7230-7240 ◽  
Author(s):  
Zongrui Wang ◽  
Xiangguang Li ◽  
Ye Zou ◽  
Jiahui Tan ◽  
Xiaolong Fu ◽  
...  

The charge transport polarity of a series of acceptor–donor–acceptor (A–D–A) conjugated molecules can be tuned from unipolar (n-type) to ambipolar.

Author(s):  
Yan-Cheng Lin ◽  
Kosuke Terayama ◽  
Keita Yoshida ◽  
Ping-Jui Yu ◽  
Pin-Hsiang Chueh ◽  
...  

Diversified structure design is applied to donor−acceptor (D−A)-type conjugated polymers (CPs) to improve their mobility−stretchability properties. Most methods that are capable of improving mechanical durability without sacrificing charge transport performance...


2018 ◽  
Vol 5 (11) ◽  
pp. 1748-1755 ◽  
Author(s):  
Angela Benito-Hernández ◽  
Mardia T. El-Sayed ◽  
Juan T. López Navarrete ◽  
M. Carmen Ruiz Delgado ◽  
Berta Gómez-Lor

A promising candidate for ambipolar charge transport: a disk-like platform, diazatruxenone, as a novel, compact and planar donor–acceptor molecule.


2015 ◽  
Vol 51 (75) ◽  
pp. 14179-14182 ◽  
Author(s):  
Hung-Chin Wu ◽  
Jicheng Zhang ◽  
Zhishan Bo ◽  
Wen-Chang Chen

Solution processable star-shaped donor–acceptor conjugated molecules are explored for the first time as charge storage materials for resistor-type memory devices with a triphenylamine (donor) core, and three 1.8-naphthalimide (acceptors) end-groups.


2015 ◽  
Vol 1737 ◽  
Author(s):  
Cristiano F. Woellner ◽  
Leonardo D. Machado ◽  
Pedro A. S. Autreto ◽  
José A. Freire ◽  
Douglas S. Galvão

ABSTRACTIn this work we use a three-dimensional Pauli master equation to investigate the charge carrier mobility of a two-phase system, which can mimic donor-acceptor and amorphous-crystalline bulk heterojunctions. Our approach can be separated into two parts: the morphology generation and the charge transport modeling in the generated blend. The morphology part is based on a Monte Carlo simulation of binary mixtures (donor/acceptor). The second part is carried out by numerically solving the steady-state Pauli master equation. By taking the energetic disorder of each phase, their energy offset and domain morphology into consideration, we show that the carrier mobility can have a significant different behavior when compared to a one-phase system. When the energy offset is non-zero, we show that the mobility electric field dependence switches from negative to positive at a threshold field proportional to the energy offset. Additionally, the influence of morphology, through the domain size and the interfacial roughness parameters, on the transport was also investigated.


2019 ◽  
Vol 29 (5) ◽  
pp. 567-569 ◽  
Author(s):  
Sergey D. Tokarev ◽  
Yulia A. Sotnikova ◽  
Alexander V. Anisimov ◽  
Yurii V. Fedorov ◽  
Gediminas Jonusauskas ◽  
...  

2020 ◽  
Vol 8 (4) ◽  
pp. 1398-1404
Author(s):  
Guobing Zhang ◽  
Ruikun Chen ◽  
Yue Sun ◽  
Boseok Kang ◽  
Mingxiang Sun ◽  
...  

Two acceptor–donor–acceptor small molecules based on fused ring as donor, and hemi-isoindigo units as acceptors were synthesized and characterized for solution-processed organic field-effect transistors.


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