Polymorphs of oxindole as the core structures in bioactive compounds

CrystEngComm ◽  
2018 ◽  
Vol 20 (12) ◽  
pp. 1739-1745 ◽  
Author(s):  
Barbara Hachuła ◽  
Maciej Zubko ◽  
Paweł Zajdel ◽  
Maria Książek ◽  
Joachim Kusz ◽  
...  
Keyword(s):  
Single Crystal ◽  
Bioactive Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Core

A new polymorph of oxindole (termed as “δ-form”) has been found and characterized by single-crystal X-ray diffraction.

An Organozinc Hydrazide-Thiolate Aggregate with a Zn3N4S2 Core

2009 ◽  
Vol 64 (3) ◽  
pp. 339-342 ◽  
Author(s):  
Surajit Jana ◽  
Norbert W. Mitzel
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Elemental Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Core ◽  
Alkane Elimination ◽  
Core Features

The first organometallic zinc hydrazide-thiolate cluster, [(MeZn)2(PhSZn)(HNNMe2)(H2N-NMe2)(SPh)2]2 (1) has been prepared by alkane elimination from dimethylzinc solutions upon treatment with N,N-dimethylhydrazine and thiophenol and characterised by NMR spectroscopy, elemental analysis and single crystal X-ray diffraction. Compound 1 forms asymmetric aggregates containing a Zn3N4S2 core. The core features rings with different connectivities. A seven-membered ZnSZnNNZnS ring comprises three fivemembered rings, two of a ZnSZnNN and one of a ZnNZnNN atom sequence. Intermolecular S···H bonding is observed in the crystal.

Zur strukturellen Verzerrung von Fe4S4I42- -Clustern durch Iod-Iod-Kon Die Kristallstrukturen von (Ph4P)2Fe4S4I4 und (Me3NCH2Ph)2Fe4S4I4 / Structural Distortion of Fe4S4I22- Clusters through Iodine-Iodine Contacts: Crystal Structures of (Ph4P)2Fe4S4I4 and (Me3NCH2Ph)2Fe4S4I4

1988 ◽  
Vol 43 (4) ◽  
pp. 457-462 ◽  
Author(s):  
Siegfried Pohl ◽  
Wolfgang Saak
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Diffraction Data ◽  
Core Structure ◽  
Structural Distortion ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
The Core

AbstractThe structures of (Ph4P)2Fe4S4I4 (1) and (Me3NCH2Ph)2Fe4S4I4 (2) were determined from single crystal X-ray diffraction data.1 crystallizes in the tetragonal space group I41/a with a = 1088.3(1) and c = 4540.3(2) pm. Z = 4.2: Monoclinic, space group Cc. a = 1332.0(2), b = 1513.8(3), c = 1755.1(3) pm, β = 96.69(1)°, Z = 4.In 1 the anion Fe4S4I42- has imposed S4 symmetry with four short (226.2 pm) and eight long (228.1 and 228.4 pm) Fe-S distances parallel and perpendicular, respectively, to the crystallo­graphic 4̃ axis. The Fe-Fe distances were found to be 274.3 and 275.5 pm (Fe-I 254.1 p0m).In (Me3NCH2Ph)2Fe4S4I4 the [Fe4S4]2+ cluster also exhibits a slightly compressed tetragonal core structure but the core distortions are larger and less regular than in 1 (Fe-S distances from 224.6 to 232.9 pm, Fe-Fe distances from 269.6 to 275.9 pm, Fe-I distances from 249.5 to 255.7 pm).In addition there are in 2 iodine-iodine interactions between the anions with an I-I distance of 391.7 pm. These weak attractive forces seem to be the reason for the rather large and hitherto in [Fe4S4] clusters with four identical ligands unobserved distortion of the Fe4S4 core.

Electron Microscopy of Shock Loaded Polycrystalline Beryllium

1974 ◽  
Vol 32 ◽  
pp. 506-507 ◽  
Author(s):  
J. M. Galbraith ◽  
L. E. Murr ◽  
A. L. Stevens
Keyword(s):  
Electron Microscopy ◽  
Wave Propagation ◽  
Structural Change ◽  
Single Crystal ◽  
Diffraction Pattern ◽  
Shock Loading ◽  
Slip Systems ◽  
Compression Tests ◽  
X Ray Diffraction ◽  
X Ray

Uniaxial compression tests and hydrostatic tests at pressures up to 27 kbars have been performed to determine operating slip systems in single crystal and polycrystal1ine beryllium. A recent study has been made of wave propagation in single crystal beryllium by shock loading to selectively activate various slip systems, and this has been followed by a study of wave propagation and spallation in textured, polycrystal1ine beryllium. An alteration in the X-ray diffraction pattern has been noted after shock loading, but this alteration has not yet been correlated with any structural change occurring during shock loading of polycrystal1ine beryllium.This study is being conducted in an effort to characterize the effects of shock loading on textured, polycrystal1ine beryllium. Samples were fabricated from a billet of Kawecki-Berylco hot pressed HP-10 beryllium.

Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(–)-1-phenyl-ethyl ammonium percholorate

2003 ◽  
Vol 218 (5) ◽  
Author(s):  
Süheyla Özbey ◽  
F. B. Kaynak ◽  
M. Toğrul ◽  
N. Demirel ◽  
H. Hoşgören
Keyword(s):  
Crystal Structure ◽  
Inclusion Complex ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
New Type

AbstractA new type of inclusion complex, S(–)-1 phenyl ethyl ammonium percholorate complex of R-(–)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group

Unusual Rearrangement of Naphthalene in the Synthesis of a Novel B8-B8-Bridged Derivative in the [(1,2-C2B9H11)2-3-Co]- Series. X-Ray Structure and 11B NMR Spectra of [8,8'-μ-(CH2-C9H6)-(1,2-C2B9H10)2-3-Co]- (CH3)4N+

1997 ◽  
Vol 62 (5) ◽  
pp. 746-751 ◽  
Author(s):  
Andreas Franken ◽  
Jaromír Plešek ◽  
Christiane Nachtigal
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Nucleophilic Substitution ◽  
Nmr Spectra ◽  
X Ray Diffraction ◽  
X Ray ◽  
Unusual Rearrangement ◽  
Multinuclear Nmr Spectroscopy ◽  
11B Nmr ◽  
Isolated Compound

On treatment of the [(1,2-C2B9H11)2Co]- ion with naphthalene in presence of AlCl3 a remarkably bridged [8,8'-μ-(CH2-C9H6)-(1,2-C2B9H10)2-3-Co]- ion is obtained as a single isolated compound. The triatomic -CH2-C9H6- bridge is derived from the rearranged naphthalene nucleus. The mechanism of this reaction is obscure but it does resemble the "Electrophile-Induced Nucleophilic Substitution" reported earlier. The structure of the compound was established by multinuclear NMR spectroscopy and by single crystal X-ray diffraction.

scholarly journals An investigation of polyhedral deformation in two mixed-metal diarsenates: SrZnAs2O7and BaCuAs2O7

2015 ◽  
Vol 71 (4) ◽  
pp. 330-337 ◽  
Author(s):  
Sabina Kovač ◽  
Ljiljana Karanović ◽  
Tamara Đorđević
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
General Formula ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Open Framework ◽  
Geometrical Characteristics ◽  
Barium Copper

Two isostructural diarsenates, SrZnAs2O7(strontium zinc diarsenate), (I), and BaCuAs2O7[barium copper(II) diarsenate], (II), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The three-dimensional open-framework crystal structure consists of corner-sharingM2O5(M2 = Zn or Cu) square pyramids and diarsenate (As2O7) groups. Each As2O7group shares its five corners with five differentM2O5square pyramids. The resulting framework delimits two types of tunnels aligned parallel to the [010] and [100] directions where the large divalent nine-coordinatedM1 (M1 = Sr or Ba) cations are located. The geometrical characteristics of theM1O9,M2O5and As2O7groups of known isostructural diarsenates, adopting the general formulaM1IIM2IIAs2O7(M1II= Sr, Ba, Pb;M2II= Mg, Co, Cu, Zn) and crystallizing in the space groupP21/n, are presented and discussed.

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