Enhanced photocatalytic efficiency of C3N4/BiFeO3heterojunctions: the synergistic effects of band alignment and ferroelectricity

2018 ◽  
Vol 20 (5) ◽  
pp. 3648-3657 ◽  
Author(s):  
Xian-Zhu Deng ◽  
Chuang Song ◽  
Yin-Lin Tong ◽  
Guoliang Yuan ◽  
Feng Gao ◽  
...  

C3N4/BiFeO3heterojunction shows enhanced visible light photocatalytic efficiency.

RSC Advances ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 6114-6120 ◽  
Author(s):  
Junpeng Ren ◽  
Yongyong Zhu

Ag2O doped electrospun BiVO4 nanofibers with p–n junction heterogeneous structures show enhanced photocatalytic activity under visible light (photocatalytic efficiency: 98.47% within 100 min) and good cycling stability.


NANO ◽  
2017 ◽  
Vol 12 (06) ◽  
pp. 1750072 ◽  
Author(s):  
Tao Wang ◽  
Changchang Ma ◽  
Dan Wu ◽  
Xinlin Liu ◽  
Yang Liu ◽  
...  

In this paper, a novel heterostructure of 0D/3D-CdSe/Bi[Formula: see text]TiO[Formula: see text] pyramidal photocatalyst was synthesized and characterized. It exhibited significantly photocatalytic efficiency in photocatalytic degradation of the tetracycline than pure Bi[Formula: see text]TiO2 and CdSe and showed high stability. The enhanced photocatalytic activity might be attributed to the formation of heterostructure between CdSe QDs and 3D Bi[Formula: see text]TiO[Formula: see text], in which CdSe QDs served as electron trapper to improve the separation of photodegradation electron–hole pairs, and provided a number of active adsorption sites for the photogenerated of pollutants. The photocatalytic mechanism of 0D/3D-CdSe/Bi[Formula: see text]TiO[Formula: see text] pyramidal heterostructure was also proposed.


Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2233 ◽  
Author(s):  
Haocong Dong ◽  
Junzhu Li ◽  
Mingguang Chen ◽  
Hongwei Wang ◽  
Xiaochuan Jiang ◽  
...  

High-throughput production of highly efficient photocatalysts for hydrogen evolution remains a considerable challenge for materials scientists. Here, we produced extremely uniform high-quality graphene and molybdenum disulfide (MoS2) nanoplatelets through the electrochemical-assisted liquid-phase exfoliation, out of which we subsequently fabricated MoS2/graphene van der Waals heterostructures. Ultimately, zinc oxide (ZnO) nanoparticles were deposited into these two-dimensional heterostructures to produce an artificial ZnO/MoS2/graphene nanocomposite. This new composite experimentally exhibited an excellent photocatalytic efficiency in hydrogen evolution under the sunlight illumination ( λ > 400   n m ), owing to the extremely high electron mobilities in graphene nanoplatelets and the significant visible-light absorptions of MoS2. Moreover, due to the synergistic effects in MoS2 and graphene, the lifetime of excited carriers increased dramatically, which considerably improved the photocatalytic efficiency of the ZnO/MoS2/graphene heterostructure. We conclude that the novel artificial heterostructure presented here shows great potential for the high-efficient photocatalytic hydrogen generation and the high throughput production of visible-light photocatalysts for industrial applications.


2019 ◽  
Vol 43 (19) ◽  
pp. 7409-7418 ◽  
Author(s):  
Aizhong Jia ◽  
Xiao Zhang ◽  
Fang Li ◽  
Yanji Wang

Hierarchical pore-induced multiple internal reflections and/or scattering of light improves the capability of light trapping and thus photocatalytic efficiency.


2020 ◽  
Vol 213 ◽  
pp. 02037
Author(s):  
Chengli Tang ◽  
Limei Zhang

Bismuth oxide (Bi2O3) is one of the potential visible-light photocatalytic materials, however, due to low electron mobility and short minority carrier diffusion length, the photocatalytic activity of Bi2O3 is restricted. The GQD/Bi2O3 composites were synthesized stably depositing single-crystalline graphene quantum dots (GQDs) with absorption edge at ~10nm, prepared by using a top-down method. The GQDBi2O3 heterojunctions were successfully established, the photo-generated electrons transfer from the Bi2O3 to the GQDs at the interface of the GQD-Bi2O3 heterojunctions, result in efficient electron-hole pairs separation and higher photocatalytic efficiency. The optimum visible performance is achieved at GQD content of 1.0 wt %, the RhB dye was nearly completely decoloured after 90 min of visible-light irradiation, and then decrease at higher doping levels due to the thicker GQD layer will cover the active sites of Bi2O3, thus leading to the greatly reduced catalytic activity.


Sign in / Sign up

Export Citation Format

Share Document