Liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen over a Mn-based metal–organic framework

2017 ◽  
Vol 46 (26) ◽  
pp. 8415-8421 ◽  
Author(s):  
Yasutaka Kuwahara ◽  
Yukihiro Yoshimura ◽  
Hiromi Yamashita

A microporous Mn-based metal–organic framework (Mn-MOF-74) acts as a heterogeneous catalyst active for liquid-phase oxidation of alkylaromatics with molecular O2.

2014 ◽  
Vol 4 (8) ◽  
pp. 2599-2607 ◽  
Author(s):  
Patricio Cancino ◽  
Verónica Paredes-García ◽  
Pedro Aguirre ◽  
Evgenia Spodine

The metal–organic framework [Cu2(bipy)2(btec)]∞ was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water–dichloroethane or n-decane medium.


2016 ◽  
Vol 6 (2) ◽  
pp. 442-448 ◽  
Author(s):  
Yasutaka Kuwahara ◽  
Yukihiro Yoshimura ◽  
Hiromi Yamashita

Mn(OH)x supported on oxides in situ transforms into a monomeric Mn(iii) species coordinated with the PhCOO− ligand, which efficiently oxidizes alkylaromatics with O2.


2020 ◽  
Vol 146 ◽  
pp. 106119
Author(s):  
Evgeniya S. Degtyareva ◽  
Kirill S. Erokhin ◽  
Valentine P. Ananikov

2006 ◽  
Vol 45 (22) ◽  
pp. 7444-7450 ◽  
Author(s):  
Shingo Sumimoto ◽  
Chiaki Tanaka ◽  
Sho-ta Yamaguchi ◽  
Yuichi Ichihashi ◽  
Satoru Nishiyama ◽  
...  

2018 ◽  
Vol 18 (12) ◽  
pp. 7451-7459 ◽  
Author(s):  
Zheng Wang ◽  
Katia Rodewald ◽  
Raghavender Medishetty ◽  
Bernhard Rieger ◽  
Roland A. Fischer

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.


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