Application of composition controlled nickel-alloyed iron sulfide pyrite nanocrystal thin films as the hole transport layer in cadmium telluride solar cells

2017 ◽  
Vol 5 (20) ◽  
pp. 4996-5004 ◽  
Author(s):  
Ebin Bastola ◽  
Khagendra P. Bhandari ◽  
Randy J. Ellingson

The solution-processed colloidal NixFe1−xS2 nanocrystal based thin films serve as the hole transport layers in cadmium telluride (CdTe) solar cells.

MRS Advances ◽  
2018 ◽  
Vol 3 (41) ◽  
pp. 2441-2447 ◽  
Author(s):  
Ebin Bastola ◽  
Kamala Khanal Subedi ◽  
Khagendra P. Bhandari ◽  
Randy J. Ellingson

ABSTRACTThe cadmium telluride (CdTe) photovoltaic (PV) comprise an efficient and cost-effective technology for harvesting solar energy. However, device efficiency remains limited in part by low-open circuit voltage (VOC) and fill factor (FF) due to inefficient transport of photo-generated charge carriers. Given the deep valence band of CdTe, the use of copper/gold (Cu/Au) as a back contact serves primarily to narrow the width of the inherent Schottky junction evident in CdTe solar cells (in our laboratory, Cu/Au has been used as a standard back contact). For efficient transport of carriers to and into the back contact, a hole transport layer (HTL) is desired with valence band edge comparable to that of CdTe (∼ -5.9 eV). Here, we report solution-processed nanocrystal (NCs) based thin films as HTLs in CdTe solar cells. The earth abundant materials we discuss include iron pyrite (FeS2), nickel-alloyed iron pyrite (NixFe1-xS2), zinc copper sulfide (ZnxCu1-xS) nanocomposites, and perovskite-based films. The FeS2 and NixFe1-xS2 NCs are synthesized by a hot-injection route, and thin films are fabricated by drop-casting, and spin-coating techniques using colloidal NCs. ZnxCu1-xS thin films are fabricated by chemical bath deposition. These NC-based thin films are applied and studied as the HTLs in CdTe devices. On using these materials, the device performance can be increased up to 10% compared to the standard Cu/Au back contact. Here, we discuss the benefits, challenges, and opportunities for these back contact materials in CdTe photovoltaics.


2016 ◽  
Vol 145 ◽  
pp. 193-199 ◽  
Author(s):  
Ashish Dubey ◽  
Nirmal Adhikari ◽  
Swaminathan Venkatesan ◽  
Shaopeng Gu ◽  
Devendra Khatiwada ◽  
...  

2016 ◽  
Vol 18 (5) ◽  
pp. 3463-3471 ◽  
Author(s):  
Leize Zhu ◽  
Beau J. Richardson ◽  
Qiuming Yu

A dual hole transport layer with PEDOT:PSS/MoO3 provides an effective way to enhance the performance of inverted hybrid CdSe–polymer solar cells.


Solar Energy ◽  
2018 ◽  
Vol 165 ◽  
pp. 131-135 ◽  
Author(s):  
Ranoo Bhargav ◽  
Asit Patra ◽  
S.K. Dhawan ◽  
S.P. Gairola

RSC Advances ◽  
2020 ◽  
Vol 10 (71) ◽  
pp. 43847-43852
Author(s):  
Su-Kyung Kim ◽  
Hae-Jun Seok ◽  
Do-Hyung Kim ◽  
Dong-Hyeok Choi ◽  
Seung-Ju Nam ◽  
...  

We compared nickel oxide (NiOx) deposited by thermal evaporation and that deposited by the spin-coating process, for use in the hole transport layers of inverted planar perovskite solar cells (PSCs).


APL Materials ◽  
2016 ◽  
Vol 4 (2) ◽  
pp. 026104 ◽  
Author(s):  
F. Anderson S. Lima ◽  
Michail J. Beliatis ◽  
Bérenger Roth ◽  
Thomas R. Andersen ◽  
Andressa Bortoti ◽  
...  

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