Si nanoflake-assembled blocks towards high initial coulombic efficiency anodes for lithium-ion batteries

2018 ◽  
Vol 54 (86) ◽  
pp. 12214-12217 ◽  
Author(s):  
Xiangyang Zhou ◽  
Yongpeng Ren ◽  
Juan Yang ◽  
Jing Ding ◽  
Jiaming Zhang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Si Anodes ◽  
Initial Coulombic Efficiency

The initial coulombic efficiency of Si anodes is effectively improved via a Cu assisted Mg reduction.

A Review on Recent Advances for Boosting Initial Coulombic Efficiency of Silicon Anodic Lithium Ion batteries

Small ◽  
2021 ◽  
pp. 2102894
Author(s):  
Lin Sun ◽  
Yanxiu Liu ◽  
Jun Wu ◽  
Rong Shao ◽  
Ruiyu Jiang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Recent Advances ◽  
Initial Coulombic Efficiency

scholarly journals A conductive self healing polymeric binder using hydrogen bonding for Si anodes in lithium ion batteries

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim
Keyword(s):  
Hydrogen Bonding ◽  
Acrylic Acid ◽  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Polymer Binder ◽  
Self Healing ◽  
Si Anodes ◽  
Ion Conducting ◽  
Poly Acrylic Acid

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.

Carbon coated porous silicon flakes with high initial coulombic efficiency and long-term cycling stability for lithium ion batteries

2019 ◽  
Vol 3 (9) ◽  
pp. 2361-2365 ◽  
Author(s):  
Xiaoyong Dou ◽  
Ming Chen ◽  
Jiantao Zai ◽  
Zhen De ◽  
Boxu Dong ◽  
...  
Keyword(s):  
Porous Silicon ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Next Generation ◽  
Carbon Coated ◽  
Initial Coulombic Efficiency

Silicon (Si) has been regarded as a promising next-generation anode material to replace carbon-based materials for lithium ion batteries (LIBs).

Pre-lithiation of onion-like carbon/MoS2nano-urchin anodes for high-performance rechargeable lithium ion batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (15) ◽  
pp. 8884-8890 ◽  
Author(s):  
Ye Wang ◽  
Guozhong Xing ◽  
Zhao Jun Han ◽  
Yumeng Shi ◽  
Jen It Wong ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Hybrid Structure ◽  
Initial Coulombic Efficiency

Pre-lithiation of a MoS2/OLC nano-urchin hybrid structure shows great potential in developing good performance lithium ion batteries with ultra-high initial coulombic efficiency.

Self-supported Zn3P2 nanowire arrays grafted on carbon fabrics as an advanced integrated anode for flexible lithium ion batteries

Nanoscale ◽  
2016 ◽  
Vol 8 (16) ◽  
pp. 8666-8672 ◽  
Author(s):  
Wenwu Li ◽  
Lin Gan ◽  
Kai Guo ◽  
Linbo Ke ◽  
Yaqing Wei ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Nanowire Arrays ◽  
Rate Performance ◽  
Reactive Metal ◽  
Metal Phosphide ◽  
Integrated Anode ◽  
Initial Coulombic Efficiency ◽  
Carbon Fabrics

The well-aligned binary lithium-reactive metal phosphide nanowire arrays were grafted on carbon fabrics. When served as integrated electrodes, they exhibit striking high initial coulombic efficiency, large capacity, excellent rate performance.

Saqima-like Co3O4/CNTs secondary microstructures with ultrahigh initial Coulombic efficiency as an anode for lithium ion batteries

2017 ◽  
Vol 22 (2) ◽  
pp. 417-427 ◽  
Author(s):  
Aiping Hu ◽  
Wen Cao ◽  
Dongning Liu ◽  
Qunli Tang ◽  
Weina Deng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Initial Coulombic Efficiency

SnSe/Cu2SnSe3 Heterojunction Structure with High Initial Coulombic Efficiency for Lithium-Ion Battery Anodes

2022 ◽  
Vol 905 ◽  
pp. 135-141
Author(s):  
Bao Juan Yang ◽  
Rui Xia ◽  
Su Bin Jiang ◽  
Mei Zhen Gao
Keyword(s):  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Specific Capacity ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Diffusion Path ◽  
Thermal Method ◽  
Tin Selenide ◽  
Ion Doping ◽  
Initial Coulombic Efficiency

Due to high theoretical specific capacity and abundant reserves, tin selenide-based materials have received tremendous attentions in the fields of lithium-ion batteries. Nevertheless, the huge volume changes during insertion/de-intercalation processes deteriorate the Coulombic Efficiency greatly. In order to solve it, the researchers have made great efforts by means of controlling nanoparticles granularity, carbon coating, ion doping et al. In this study, SnSe/Cu2SnSe3 heterojunction nanocomposites were synthesized by solvo-thermal method. The resulting SnSe/Cu2SnSe3 is a three-dimensional flower-like hierarchical nanostructure composed of nanoscale thin lamellae of a thickness of 8-12 nm. The unique nanostructure could shorten the diffusion path of lithium ions and expedite charge transfer, and therefore enhance the reaction kinetics. Compared with SnSe, the initial Coulombic efficiency of SnSe/Cu2SnSe3 is raised from 59% to 90% as the anode material of lithium-ion batteries.

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