The hydrolysis of ammonia borane catalyzed by NiCoP/OPC-300 nanocatalysts: high selectivity and efficiency, and mechanism

2019 ◽  
Vol 21 (4) ◽  
pp. 850-860 ◽  
Author(s):  
Xiaopeng Qu ◽  
Rui Jiang ◽  
Qian Li ◽  
Fanan Zeng ◽  
Xue Zheng ◽  
...  

The development of highly efficient and cheap catalysts for the release of hydrogen from chemical hydrogen-storage materials is indispensable for the coming clean energy economy.

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Zhang-Hui Lu ◽  
Qilu Yao ◽  
Zhujun Zhang ◽  
Yuwen Yang ◽  
Xiangshu Chen

Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3and N2H4BH3.


Author(s):  
Jun-Min Yan ◽  
Xia Kang ◽  
Jia-Xin Yao ◽  
Yan-Xin Duan ◽  
Ze-Yu Chen ◽  
...  

Chemical hydrogen storage materials such as hydrazine borane (HB) have aroused great interest when the tricky hydrogen storage is still a barrier on the way to sustainable hydrogen energy development....


Energies ◽  
2015 ◽  
Vol 8 (4) ◽  
pp. 3118-3141 ◽  
Author(s):  
Romain Moury ◽  
Umit Demirci

2010 ◽  
Vol 24 (4) ◽  
pp. 2596-2606 ◽  
Author(s):  
Scot D. Rassat ◽  
Christopher L. Aardahl ◽  
Tom Autrey ◽  
R. Scott Smith

2009 ◽  
Vol 34 (5) ◽  
pp. 2303-2311 ◽  
Author(s):  
Tetsuo Umegaki ◽  
Jun-Min Yan ◽  
Xin-Bo Zhang ◽  
Hiroshi Shioyama ◽  
Nobuhiro Kuriyama ◽  
...  

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