One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

2019 ◽  
Vol 55 (98) ◽  
pp. 14753-14756 ◽  
Author(s):  
Cayo Lee ◽  
Nicholas D. Ball ◽  
Glenn M. Sammis
Keyword(s):  
New Method ◽  
Grignard Reagents ◽  
One Pot ◽  
Sulfuryl Fluoride ◽  
The One

Herein, we report a new method for the one-pot syntheses of sulfonyl fluorides.

scholarly journals New sulfuryl fluoride-derived alkylating reagents for the 1,1-dihydrofluoroalkylation of thiols

2019 ◽  
Vol 10 (44) ◽  
pp. 10331-10335 ◽  
Author(s):  
Paul J. Foth ◽  
Frances Gu ◽  
Trevor G. Bolduc ◽  
Sahil S. Kanani ◽  
Glenn M. Sammis
Keyword(s):  
New Method ◽  
One Pot ◽  
Sulfuryl Fluoride ◽  
One Pot Synthesis ◽  
The One ◽  
Alkylating Reagents

Herein, we report a new method for the one-pot synthesis of 1,1-dihydrofluoroalkyl sulfides by bubbling sulfuryl fluoride (SO2F2) through a solution of the corresponding alcohol and thiol.

ChemInform Abstract: A New Method for the One-Pot Synthesis of α-Hydroxyaldehyde Ethyl Sulfates from Terminal Olefins.

ChemInform ◽  
2010 ◽  
Vol 27 (52) ◽  
pp. no-no
Author(s):  
N. V. ZYK ◽  
E. E. NESTEROV ◽  
A. N. KHLOBYSTOV ◽  
N. S. ZEFIROV
Keyword(s):  
New Method ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One ◽  
Terminal Olefins

scholarly journals Three-component synthesis, utilization and biological activity of phosphinoyl-functionalized isoindolinones

2021 ◽  
Author(s):  
Nóra Popovics-Tóth ◽  
Bettina Rávai ◽  
Ádám Tajti ◽  
Bence Varga ◽  
Péter Bagi ◽  
...  
Keyword(s):  
Biological Activity ◽  
Phosphorus Atom ◽  
New Method ◽  
Primary Amines ◽  
One Pot ◽  
Three Component Reaction ◽  
The One

A new method for the synthesis of 3-oxoisoindolin-1-ylphosphine oxides bearing same or different substituents on the phosphorus atom is described. The one-pot three-component reaction of 2-formylbenzoic acid, primary amines and...

scholarly journals Practical N-Hydroxyphthalimide-Mediated Oxidation of Sulfonamides to N-Sulfonylimines

Molecules ◽  
2019 ◽  
Vol 24 (20) ◽  
pp. 3771 ◽  
Author(s):  
Jian Wang ◽  
Wen-Jing Yi
Keyword(s):  
New Method ◽  
One Pot ◽  
Oxidation Method ◽  
Mild Conditions ◽  
The One ◽  
Mediated Oxidation

A new method to prepare sulfonylimines through the oxidation of sulfonamides mediated by N-hydroxyphthalimide under mild conditions has been developed. Compared to reported oxidation methods, broader substrates scope and milder conditions were achieved in our method. Importantly, this oxidation method can afford N-sulfonyl enaminones using Mannich products as starting materials. Additionally, the one-pot Friedel–Crafts arylation reaction of unseparated N-sulfonylimine formed in our system with 1,3,5-trimethoxybenzene was successful without any additional catalyst.

Intermolecular sp 3 C–H bond functionalization of alkyl amides as a new method for the one-pot synthesis of functional neo alkyl amides with remote functional groups

2015 ◽  
Vol 56 (3) ◽  
pp. 562-566 ◽  
Author(s):  
Irena S. Akhrem ◽  
Dzhul’etta V. Avetisyan ◽  
Lyudmila V. Afanas’eva ◽  
Oleg I. Artyushin ◽  
Nikolai D. Kagramanov
Keyword(s):  
Functional Groups ◽  
New Method ◽  
One Pot ◽  
Bond Functionalization ◽  
One Pot Synthesis ◽  
The One

A new method for α-specific glucosylation and its application to the one-pot synthesis of a branched α-glucan

2019 ◽  
Vol 6 (6) ◽  
pp. 762-772 ◽  
Author(s):  
Yanxin Zhang ◽  
Shihao Zhou ◽  
Xiaohan Wang ◽  
Han Zhang ◽  
Zhongwu Guo ◽  
...  
Keyword(s):  
New Method ◽  
Protecting Groups ◽  
One Pot ◽  
Highly Efficient ◽  
One Pot Synthesis ◽  
The One ◽  
Remote Participation ◽  
Promoter System

We have developed a new and highly efficient α-specific glucosylation method based on the synergistic α-directing effects of a TolSCl/AgOTf promoter system and the steric β-shielding or the remote participation of protecting groups at the donor 6-O-position.

Intermolecular sp3 C–H bond functionalization of alkyl alkanoates as a new method for the one-pot synthesis of functional neo alkyl alkanoates with remote functional groups

2013 ◽  
Vol 54 (45) ◽  
pp. 6037-6040 ◽  
Author(s):  
Irena S. Akhrem ◽  
Dzhul’etta V. Avetisyan ◽  
Irina M. Churilova ◽  
Lyudmila V. Afanas’eva ◽  
Oleg I. Artyushin ◽  
...  
Keyword(s):  
Functional Groups ◽  
New Method ◽  
One Pot ◽  
Bond Functionalization ◽  
One Pot Synthesis ◽  
The One

A Series of Metal-Organic Frameworks for Selective CO2 Capture and Catalytic Oxidative Carboxylation of Olefins

2018 ◽  
Author(s):  
Huong T. D. Nguyen ◽  
Y B. N. Tran ◽  
Hung N. Nguyen ◽  
Tranh C. Nguyen ◽  
Felipe Gándara ◽  
...  
Keyword(s):  
Room Temperature ◽  
Gas Adsorption ◽  
New Materials ◽  
One Pot ◽  
Acid Gas ◽  
Naphthalene Diimide ◽  
Styrene Carbonate ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
The One

<p>Three novel lanthanide metal˗organic frameworks (Ln-MOFs), namely MOF-590, -591, and -592 were constructed from a naphthalene diimide tetracarboxylic acid. Gas adsorption measurements of MOF-591 and -592 revealed good adsorption of CO<sub>2</sub> (low pressure, at room temperature) and moderate CO<sub>2</sub> selectivity over N<sub>2</sub> and CH<sub>4</sub>. Accordingly, breakthrough measurements were performed on a representative MOF-592, in which the separation of CO<sub>2</sub> from binary mixture containing N<sub>2</sub> and CO<sub>2</sub> was demonstrated without any loss in performance over three consecutive cycles. Moreover, MOF-590, MOF-591, and MOF-592 exhibited catalytic activity in the one-pot synthesis of styrene carbonate from styrene and CO<sub>2</sub> under mild conditions (1 atm CO<sub>2</sub>, 80 °C, and solvent-free). Among the new materials, MOF-590 revealed a remarkable efficiency with exceptional conversion (96%), selectivity (95%), and yield (91%). </p><br>

A Study on the Rearrangement of Dialkyl 1-Aryl-1-hydroxymethylphosphonates to Benzyl Phosphates

2020 ◽  
Vol 24 (4) ◽  
pp. 465-471 ◽  
Author(s):  
Zita Rádai ◽  
Réka Szabó ◽  
Áron Szigetvári ◽  
Nóra Zsuzsa Kiss ◽  
Zoltán Mucsi ◽  
...  
Keyword(s):  
Quantum Chemical ◽  
Room Temperature ◽  
Phase Transfer ◽  
One Pot ◽  
Substrate Dependence ◽  
Triethylbenzylammonium Chloride ◽  
One Step ◽  
The Pudovik Reaction ◽  
The One ◽  
Solid Liquid

The phospha-Brook rearrangement of dialkyl 1-aryl-1-hydroxymethylphosphonates (HPs) to the corresponding benzyl phosphates (BPs) has been elaborated under solid-liquid phase transfer catalytic conditions. The best procedure involved the use of triethylbenzylammonium chloride as the catalyst and Cs2CO3 as the base in acetonitrile as the solvent at room temperature. The substrate dependence of the rearrangement has been studied, and the mechanism of the transformation under discussion was explored by quantum chemical calculations. The key intermediate is an oxaphosphirane. The one-pot version starting with the Pudovik reaction has also been developed. The conditions of this tandem transformation were the same, as those for the one-step HP→BP conversion.

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