Formation dynamics of mesocrystals composed of organically modified CeO2 nanoparticles: analogy to a particle formation model

CrystEngComm ◽  
2019 ◽  
Vol 21 (25) ◽  
pp. 3836-3843 ◽  
Author(s):  
Andrzej-Alexander Litwinowicz ◽  
Seiichi Takami ◽  
Shunsuke Asahina ◽  
Xiaodong Hao ◽  
Akira Yoko ◽  
...  

Mesocrystals, non-classical crystalline nanostructured materials composed of aligned nanoparticles, present analogous behavior to ordinary particle formation.

2014 ◽  
Vol 25 (04) ◽  
pp. 1450002 ◽  
Author(s):  
Lei Hou ◽  
Jianguo Liu ◽  
Xue Pan ◽  
Wen-Jun Song ◽  
Xu-Dong Li

In the consensus formation dynamics, the effect of leaders and interventions have been widely studied for it has many applications such as in politics and commerce. However, the problem is how to know if it is necessary for one to make an intervention. In this paper, we theoretically propose a method for predicting the tendency and final state of collective opinion. By giving each agent a conviction ci which measures the ability to insist on his opinion, we present an opinion formation model in which agents with high convictions naturally show up properties of the opinion leaders. Results reveal that, although each agent initially gets an opinion evenly distributed in the range [-1, 1], the collective opinion of the steady-state may deviate to the positive or negative direction because of the initial bias of the leaders' opinions. We further get the correlation coefficient of the linear relationship between the collective opinion and the initial bias according to both the experimental and theoretical analysis. Thus, we could predict the final state at the very beginning of the dynamic only if we get the opinions of a small portion of the population. The prediction would afford us more time and opportunities to make reactions and interventions.


Author(s):  
M. José-Yacamán

Electron microscopy is a fundamental tool in materials characterization. In the case of nanostructured materials we are looking for features with a size in the nanometer range. Therefore often the conventional TEM techniques are not enough for characterization of nanophases. High Resolution Electron Microscopy (HREM), is a key technique in order to characterize those materials with a resolution of ~ 1.7A. High resolution studies of metallic nanostructured materials has been also reported in the literature. It is concluded that boundaries in nanophase materials are similar in structure to the regular grain boundaries. That work therefore did not confirm the early hipothesis on the field that grain boundaries in nanostructured materials have a special behavior. We will show in this paper that by a combination of HREM image processing, and image calculations, it is possible to prove that small particles and coalesced grains have a significant surface roughness, as well as large internal strain.


Author(s):  
R. T. Chen ◽  
R.A. Norwood

Sol-gel processing has been used to control the structure of a material on a nanometer scale in preparing advanced ceramics and glasses. Film coating using the sol-gel process was also found to be a viable process technology in applications such as optical, porous, antireflection and hard coatings. In this study, organically modified silicate (Ormosil) coatings are applied to PET films for various industrial applications. Sol-gel materials are known to exhibit nanometer scale structures which havepreviously been characterized by small-angle X-ray scattering (SAXS), neutron scattering and light scattering. Imaging of the ultrafine sol-gel structures has also been performed using an ultrahigh resolution replica/TEM technique. The objective of this study was to evaluate the ultrafine structures inthe sol gel coatings using a direct imaging technique: atomic force microscopy (AFM). In addition, correlation of microstructures with processing parameters, coating density and other physical properties will be discussed.The materials evaluated are organically modified silicate coatings on PET film substrates. Refractive index measurement by the prism coupling method was used to assess density of the sol-gel coating.AFM imaging was performed on a Nanoscope III AFM (by Digital Instruments) using constant force mode. Solgel coating samples coated with a thin layer of Ft (by ion beam sputtering) were also examined by STM in order to confirm the structures observed in the contact type AFM. In addition, to compare the previous results, sol-gel powder samples were also prepared by ultrasonication followed by Pt/Au shadowing and examined using a JEOL 100CX TEM.


Polymer News ◽  
2005 ◽  
Vol 30 (7) ◽  
pp. 214-216
Author(s):  
G. Carotenuto

Polymer News ◽  
2004 ◽  
Vol 29 (3) ◽  
pp. 77-81
Author(s):  
G. Carotenuto

Polymer News ◽  
2004 ◽  
Vol 29 (1) ◽  
pp. 17-18
Author(s):  
G. Carotenuto

Tellus B ◽  
2001 ◽  
Vol 53 (4) ◽  
pp. 380-393 ◽  
Author(s):  
J. M. MÄKELÄ ◽  
S. YLI‐KOIVISTO ◽  
V. HILTUNEN ◽  
W. SEIDL ◽  
E. SWIETLICKI ◽  
...  

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